Multi-Walled Carbon Nanotubes Solid-Phase Extraction and Capillary Electrophoresis Methods for the Analysis of 4-Cyanophenol and 3-Nitrophenol in Water
Analysis of 4-cyanophenol and 3-nitrophenol was carried out using multi-walled carbon nanotubes-based solid-phase extraction (SPE) and capillary electrophoresis (CE) methods. Capillary electrophoresis was carried out with 18 kV voltage, 214 nm detection, and phosphate buffer (pH 7.0, 15 mM) as backg...
| Main Authors: | , , , |
|---|---|
| Format: | Article |
| Language: | English |
| Published: |
MDPI AG
2020-08-01
|
| Series: | Molecules |
| Subjects: | |
| Online Access: | https://www.mdpi.com/1420-3049/25/17/3893 |
| _version_ | 1827707427945971712 |
|---|---|
| author | Zeid A. ALOthman Ahmad Yacine Badjah Marcello Locatelli Imran Ali |
| author_facet | Zeid A. ALOthman Ahmad Yacine Badjah Marcello Locatelli Imran Ali |
| author_sort | Zeid A. ALOthman |
| collection | DOAJ |
| description | Analysis of 4-cyanophenol and 3-nitrophenol was carried out using multi-walled carbon nanotubes-based solid-phase extraction (SPE) and capillary electrophoresis (CE) methods. Capillary electrophoresis was carried out with 18 kV voltage, 214 nm detection, and phosphate buffer (pH 7.0, 15 mM) as background electrolyte at 25 ± 1 °C temperature with 15.05 and 16.5 min migration times of 4-cyanophenol and 3-nitrophenol. The separation and resolution factors were 1.10 and 2.90. The optimized experimental conditions were 40 mg/L concentration, 1.0 g multi-walled carbon nanotubes (MWCNTs) per SPE cartridge, 5.0 mL/min flow rate of water, 0.1 mL flow rate of eluting solvent. The maximum recoveries were 91% and 98% at 0.1 mL/min flow rate of 4-cyanophenol and 3-nitrophenol. These methods were applied successfully for extraction and estimation of 4-cyanophenol and 3-nitrophenol in the municipal wastewater. The reported methods are reproducible, efficient, and practical for the estimation of these phenols in water. |
| first_indexed | 2024-03-10T16:47:26Z |
| format | Article |
| id | doaj.art-096e578bfe4f4846981cf30e99dc00f3 |
| institution | Directory Open Access Journal |
| issn | 1420-3049 |
| language | English |
| last_indexed | 2024-03-10T16:47:26Z |
| publishDate | 2020-08-01 |
| publisher | MDPI AG |
| record_format | Article |
| series | Molecules |
| spelling | doaj.art-096e578bfe4f4846981cf30e99dc00f32023-11-20T11:27:22ZengMDPI AGMolecules1420-30492020-08-012517389310.3390/molecules25173893Multi-Walled Carbon Nanotubes Solid-Phase Extraction and Capillary Electrophoresis Methods for the Analysis of 4-Cyanophenol and 3-Nitrophenol in WaterZeid A. ALOthman0Ahmad Yacine Badjah1Marcello Locatelli2Imran Ali3Advanced Materials Research Chair, Chemistry Department, College of Science, King Saud University, P. O. Box 2455, Riyadh 11451, Saudi ArabiaAdvanced Materials Research Chair, Chemistry Department, College of Science, King Saud University, P. O. Box 2455, Riyadh 11451, Saudi ArabiaDepartment of Pharmacy, University “G. d’Annunzio” of Chieti-Pescara, Build B, level 2, 66100 Chieti, ItalyDepartment of Chemistry, College of Sciences, Taibah University, Al-Medina Al-Munawara 41477, Saudi ArabiaAnalysis of 4-cyanophenol and 3-nitrophenol was carried out using multi-walled carbon nanotubes-based solid-phase extraction (SPE) and capillary electrophoresis (CE) methods. Capillary electrophoresis was carried out with 18 kV voltage, 214 nm detection, and phosphate buffer (pH 7.0, 15 mM) as background electrolyte at 25 ± 1 °C temperature with 15.05 and 16.5 min migration times of 4-cyanophenol and 3-nitrophenol. The separation and resolution factors were 1.10 and 2.90. The optimized experimental conditions were 40 mg/L concentration, 1.0 g multi-walled carbon nanotubes (MWCNTs) per SPE cartridge, 5.0 mL/min flow rate of water, 0.1 mL flow rate of eluting solvent. The maximum recoveries were 91% and 98% at 0.1 mL/min flow rate of 4-cyanophenol and 3-nitrophenol. These methods were applied successfully for extraction and estimation of 4-cyanophenol and 3-nitrophenol in the municipal wastewater. The reported methods are reproducible, efficient, and practical for the estimation of these phenols in water.https://www.mdpi.com/1420-3049/25/17/38934-cyanophenol3-nitrophenolmulti-walled carbon nanotubeswatercapillary electrophoresissolid-phase extraction |
| spellingShingle | Zeid A. ALOthman Ahmad Yacine Badjah Marcello Locatelli Imran Ali Multi-Walled Carbon Nanotubes Solid-Phase Extraction and Capillary Electrophoresis Methods for the Analysis of 4-Cyanophenol and 3-Nitrophenol in Water Molecules 4-cyanophenol 3-nitrophenol multi-walled carbon nanotubes water capillary electrophoresis solid-phase extraction |
| title | Multi-Walled Carbon Nanotubes Solid-Phase Extraction and Capillary Electrophoresis Methods for the Analysis of 4-Cyanophenol and 3-Nitrophenol in Water |
| title_full | Multi-Walled Carbon Nanotubes Solid-Phase Extraction and Capillary Electrophoresis Methods for the Analysis of 4-Cyanophenol and 3-Nitrophenol in Water |
| title_fullStr | Multi-Walled Carbon Nanotubes Solid-Phase Extraction and Capillary Electrophoresis Methods for the Analysis of 4-Cyanophenol and 3-Nitrophenol in Water |
| title_full_unstemmed | Multi-Walled Carbon Nanotubes Solid-Phase Extraction and Capillary Electrophoresis Methods for the Analysis of 4-Cyanophenol and 3-Nitrophenol in Water |
| title_short | Multi-Walled Carbon Nanotubes Solid-Phase Extraction and Capillary Electrophoresis Methods for the Analysis of 4-Cyanophenol and 3-Nitrophenol in Water |
| title_sort | multi walled carbon nanotubes solid phase extraction and capillary electrophoresis methods for the analysis of 4 cyanophenol and 3 nitrophenol in water |
| topic | 4-cyanophenol 3-nitrophenol multi-walled carbon nanotubes water capillary electrophoresis solid-phase extraction |
| url | https://www.mdpi.com/1420-3049/25/17/3893 |
| work_keys_str_mv | AT zeidaalothman multiwalledcarbonnanotubessolidphaseextractionandcapillaryelectrophoresismethodsfortheanalysisof4cyanophenoland3nitrophenolinwater AT ahmadyacinebadjah multiwalledcarbonnanotubessolidphaseextractionandcapillaryelectrophoresismethodsfortheanalysisof4cyanophenoland3nitrophenolinwater AT marcellolocatelli multiwalledcarbonnanotubessolidphaseextractionandcapillaryelectrophoresismethodsfortheanalysisof4cyanophenoland3nitrophenolinwater AT imranali multiwalledcarbonnanotubessolidphaseextractionandcapillaryelectrophoresismethodsfortheanalysisof4cyanophenoland3nitrophenolinwater |