Kinetics of photocatalytic removal of 2-amino-5-chloropyridine from water
Titanium dioxide sensitized photocatalytic degradation of a pyridine pesticide analogue, 2-amino-5-chloropyridine, was investigated by monitoring the pyridine moiety degradation, as well as by monitoring the chloride generated in the process. Effect of the initial substrate concentration on the rate...
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| Format: | Article |
| Language: | English |
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Faculty of Technology, Novi Sad
2004-01-01
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| Series: | Acta Periodica Technologica |
| Subjects: | |
| Online Access: | http://www.doiserbia.nb.rs/img/doi/1450-7188/2004/1450-71880435079A.pdf |
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| author | Abramović Biljana F. Anderluh Vesna B. Topalov Anđelka S. Gaal Ferenc F. |
| author_facet | Abramović Biljana F. Anderluh Vesna B. Topalov Anđelka S. Gaal Ferenc F. |
| author_sort | Abramović Biljana F. |
| collection | DOAJ |
| description | Titanium dioxide sensitized photocatalytic degradation of a pyridine pesticide analogue, 2-amino-5-chloropyridine, was investigated by monitoring the pyridine moiety degradation, as well as by monitoring the chloride generated in the process. Effect of the initial substrate concentration on the rate of its degradation is reported. Here we show that the kinetics of both reactions are of the zero-order in the entire investigated concentration range. The Langmuir-Hinshelwood kinetic model successfully described the influence of the initial substrate concentration on the rate of the pyridine moiety degradation. It was found that dechlorination of the substrate takes place by direct photolysis. The differences in the kinetics of pyridine moiety degradation and dechlorination were explained on the basis of the electrostatic potential for the investigated compound. |
| first_indexed | 2024-12-10T15:55:04Z |
| format | Article |
| id | doaj.art-097771b2b497413284f2b38f10b74930 |
| institution | Directory Open Access Journal |
| issn | 1450-7188 |
| language | English |
| last_indexed | 2024-12-10T15:55:04Z |
| publishDate | 2004-01-01 |
| publisher | Faculty of Technology, Novi Sad |
| record_format | Article |
| series | Acta Periodica Technologica |
| spelling | doaj.art-097771b2b497413284f2b38f10b749302022-12-22T01:42:40ZengFaculty of Technology, Novi SadActa Periodica Technologica1450-71882004-01-01200435798610.2298/APT0435079AKinetics of photocatalytic removal of 2-amino-5-chloropyridine from waterAbramović Biljana F.Anderluh Vesna B.Topalov Anđelka S.Gaal Ferenc F.Titanium dioxide sensitized photocatalytic degradation of a pyridine pesticide analogue, 2-amino-5-chloropyridine, was investigated by monitoring the pyridine moiety degradation, as well as by monitoring the chloride generated in the process. Effect of the initial substrate concentration on the rate of its degradation is reported. Here we show that the kinetics of both reactions are of the zero-order in the entire investigated concentration range. The Langmuir-Hinshelwood kinetic model successfully described the influence of the initial substrate concentration on the rate of the pyridine moiety degradation. It was found that dechlorination of the substrate takes place by direct photolysis. The differences in the kinetics of pyridine moiety degradation and dechlorination were explained on the basis of the electrostatic potential for the investigated compound.http://www.doiserbia.nb.rs/img/doi/1450-7188/2004/1450-71880435079A.pdfPhotocatalytic degradationwater treatmentTiO22-amino-5-chloropyridine |
| spellingShingle | Abramović Biljana F. Anderluh Vesna B. Topalov Anđelka S. Gaal Ferenc F. Kinetics of photocatalytic removal of 2-amino-5-chloropyridine from water Acta Periodica Technologica Photocatalytic degradation water treatment TiO2 2-amino-5-chloropyridine |
| title | Kinetics of photocatalytic removal of 2-amino-5-chloropyridine from water |
| title_full | Kinetics of photocatalytic removal of 2-amino-5-chloropyridine from water |
| title_fullStr | Kinetics of photocatalytic removal of 2-amino-5-chloropyridine from water |
| title_full_unstemmed | Kinetics of photocatalytic removal of 2-amino-5-chloropyridine from water |
| title_short | Kinetics of photocatalytic removal of 2-amino-5-chloropyridine from water |
| title_sort | kinetics of photocatalytic removal of 2 amino 5 chloropyridine from water |
| topic | Photocatalytic degradation water treatment TiO2 2-amino-5-chloropyridine |
| url | http://www.doiserbia.nb.rs/img/doi/1450-7188/2004/1450-71880435079A.pdf |
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