High-Temperature Properties and Applications of Si-Based Polymer-Derived Ceramics: A Review

Ceramics derived from organic polymer precursors, which have exceptional mechanical and chemical properties that are stable up to temperatures slightly below 2000 °C, are referred to as polymer-derived ceramics (PDCs). These molecularly designed amorphous ceramics have the same high mechanical and c...

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Main Authors: Zhongkan Ren, Shakir Bin Mujib, Gurpreet Singh
Format: Article
Language:English
Published: MDPI AG 2021-01-01
Series:Materials
Subjects:
Online Access:https://www.mdpi.com/1996-1944/14/3/614
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author Zhongkan Ren
Shakir Bin Mujib
Gurpreet Singh
author_facet Zhongkan Ren
Shakir Bin Mujib
Gurpreet Singh
author_sort Zhongkan Ren
collection DOAJ
description Ceramics derived from organic polymer precursors, which have exceptional mechanical and chemical properties that are stable up to temperatures slightly below 2000 °C, are referred to as polymer-derived ceramics (PDCs). These molecularly designed amorphous ceramics have the same high mechanical and chemical properties as conventional powder-based ceramics, but they also demonstrate improved oxidation resistance and creep resistance and low pyrolysis temperature. Since the early 1970s, PDCs have attracted widespread attention due to their unique microstructures, and the benefits of polymeric precursors for advanced manufacturing techniques. Depending on various doping elements, molecular configurations, and microstructures, PDCs may also be beneficial for electrochemical applications at elevated temperatures that exceed the applicability of other materials. However, the microstructural evolution, or the conversion, segregation, and decomposition of amorphous nanodomain structures, decreases the reliability of PDC products at temperatures above 1400 °C. This review investigates structure-related properties of PDC products at elevated temperatures close to or higher than 1000 °C, including manufacturing production, and challenges of high-temperature PDCs. Analysis and future outlook of high-temperature structural and electrical applications, such as fibers, ceramic matrix composites (CMCs), microelectromechanical systems (MEMSs), and sensors, within high-temperature regimes are also discussed.
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spelling doaj.art-09824018309847d4b8b24de30d295c392023-12-03T15:10:04ZengMDPI AGMaterials1996-19442021-01-0114361410.3390/ma14030614High-Temperature Properties and Applications of Si-Based Polymer-Derived Ceramics: A ReviewZhongkan Ren0Shakir Bin Mujib1Gurpreet Singh2Department of Mechanical and Nuclear Engineering, Kansas State University, Manhattan, KS 66506, USADepartment of Mechanical and Nuclear Engineering, Kansas State University, Manhattan, KS 66506, USADepartment of Mechanical and Nuclear Engineering, Kansas State University, Manhattan, KS 66506, USACeramics derived from organic polymer precursors, which have exceptional mechanical and chemical properties that are stable up to temperatures slightly below 2000 °C, are referred to as polymer-derived ceramics (PDCs). These molecularly designed amorphous ceramics have the same high mechanical and chemical properties as conventional powder-based ceramics, but they also demonstrate improved oxidation resistance and creep resistance and low pyrolysis temperature. Since the early 1970s, PDCs have attracted widespread attention due to their unique microstructures, and the benefits of polymeric precursors for advanced manufacturing techniques. Depending on various doping elements, molecular configurations, and microstructures, PDCs may also be beneficial for electrochemical applications at elevated temperatures that exceed the applicability of other materials. However, the microstructural evolution, or the conversion, segregation, and decomposition of amorphous nanodomain structures, decreases the reliability of PDC products at temperatures above 1400 °C. This review investigates structure-related properties of PDC products at elevated temperatures close to or higher than 1000 °C, including manufacturing production, and challenges of high-temperature PDCs. Analysis and future outlook of high-temperature structural and electrical applications, such as fibers, ceramic matrix composites (CMCs), microelectromechanical systems (MEMSs), and sensors, within high-temperature regimes are also discussed.https://www.mdpi.com/1996-1944/14/3/614high-temperaturepolymer-derived ceramicfibersceramic matrix compositesmicroelectromechanical systems sensors
spellingShingle Zhongkan Ren
Shakir Bin Mujib
Gurpreet Singh
High-Temperature Properties and Applications of Si-Based Polymer-Derived Ceramics: A Review
Materials
high-temperature
polymer-derived ceramic
fibers
ceramic matrix composites
microelectromechanical systems sensors
title High-Temperature Properties and Applications of Si-Based Polymer-Derived Ceramics: A Review
title_full High-Temperature Properties and Applications of Si-Based Polymer-Derived Ceramics: A Review
title_fullStr High-Temperature Properties and Applications of Si-Based Polymer-Derived Ceramics: A Review
title_full_unstemmed High-Temperature Properties and Applications of Si-Based Polymer-Derived Ceramics: A Review
title_short High-Temperature Properties and Applications of Si-Based Polymer-Derived Ceramics: A Review
title_sort high temperature properties and applications of si based polymer derived ceramics a review
topic high-temperature
polymer-derived ceramic
fibers
ceramic matrix composites
microelectromechanical systems sensors
url https://www.mdpi.com/1996-1944/14/3/614
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AT shakirbinmujib hightemperaturepropertiesandapplicationsofsibasedpolymerderivedceramicsareview
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