Reduction of Furfural to Furfuryl Alcohol in Liquid Phase over a Biochar-Supported Platinum Catalyst

In this work, the liquid phase hydrogenation of furfural has been studied using a biochar-supported platinum catalyst in a batch reactor. Reactions were performed between 170 °C and 320 °C, using 3 wt % and 5 wt % of Pt supported on a maple-based biochar under hydrogen pressure varying from 500 psi...

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Bibliographic Details
Main Authors: Ariadna Fuente-Hernández, Roland Lee, Nicolas Béland, Ingrid Zamboni, Jean-Michel Lavoie
Format: Article
Language:English
Published: MDPI AG 2017-02-01
Series:Energies
Subjects:
Online Access:http://www.mdpi.com/1996-1073/10/3/286
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Summary:In this work, the liquid phase hydrogenation of furfural has been studied using a biochar-supported platinum catalyst in a batch reactor. Reactions were performed between 170 °C and 320 °C, using 3 wt % and 5 wt % of Pt supported on a maple-based biochar under hydrogen pressure varying from 500 psi to 1500 psi for reaction times between 1 h and 6 h in various solvents. Under all reactive conditions, furfural conversion was significant, whilst under specific conditions furfuryl alcohol (FA) was obtained in most cases as the main product showing a selectivity around 80%. Other products as methylfuran (MF), furan, and trace of tetrahydrofuran (THF) were detected. Results showed that the most efficient reaction conditions involved a 3% Pt load on biochar and operations for 2 h at 210 °C and 1500 psi using toluene as solvent. When used repetitively, the catalyst showed deactivation although only a slight variation in selectivity toward FA at the optimal experimental conditions was observed.
ISSN:1996-1073