Development of aeronautical epoxy nanocomposites having an integrated selfhealing ability
Functionalized multi-wall carbon nanotubes (MWCNTs) have been embedded in a rubber-toughened epoxy formulation in order to explore the possibility to impart an auto-repair function to the epoxy matrix. The nanofiller has been covalently functionalized with hydrogen bonding moieties able to act as do...
| Main Authors: | , , , , , , , , , |
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| Format: | Article |
| Language: | English |
| Published: |
EDP Sciences
2018-01-01
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| Series: | MATEC Web of Conferences |
| Online Access: | https://doi.org/10.1051/matecconf/201823300021 |
| _version_ | 1818912704248676352 |
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| author | Guadagno Liberata Vertuccio Luigi Naddeo Carlo Calabrese Elisa Barra Giuseppina Raimondo Marialuigia Sorrentino Andrea Binder Wolfgang H. Michael Philipp Rana Sravendra |
| author_facet | Guadagno Liberata Vertuccio Luigi Naddeo Carlo Calabrese Elisa Barra Giuseppina Raimondo Marialuigia Sorrentino Andrea Binder Wolfgang H. Michael Philipp Rana Sravendra |
| author_sort | Guadagno Liberata |
| collection | DOAJ |
| description | Functionalized multi-wall carbon nanotubes (MWCNTs) have been embedded in a rubber-toughened epoxy formulation in order to explore the possibility to impart an auto-repair function to the epoxy matrix. The nanofiller has been covalently functionalized with hydrogen bonding moieties able to act as donor and acceptor of hydrogen bondings. Healing efficiencies have been evaluated for nano charged epoxy formulations at a loading of 0.5% wt/wt of functionalized MWCNTs bearing barbituric acid and thymine-based ligands. For both the performed functionalizations, a self-healing efficiency higher than 50% has been found. Dynamic Mechanical Analysis (DMA) highlights that the inclusion of nanofiller increases the storage moduli. Furthermore, DMA analysis evidences the presence of a phase characterized by a greater mobility of the epoxy chains, which promotes the activation of self-healing mechanisms. |
| first_indexed | 2024-12-19T23:18:49Z |
| format | Article |
| id | doaj.art-09b9b2ecd198472eb0c01a1b0ad6ec61 |
| institution | Directory Open Access Journal |
| issn | 2261-236X |
| language | English |
| last_indexed | 2024-12-19T23:18:49Z |
| publishDate | 2018-01-01 |
| publisher | EDP Sciences |
| record_format | Article |
| series | MATEC Web of Conferences |
| spelling | doaj.art-09b9b2ecd198472eb0c01a1b0ad6ec612022-12-21T20:02:01ZengEDP SciencesMATEC Web of Conferences2261-236X2018-01-012330002110.1051/matecconf/201823300021matecconf_easn_ceas2018_00021Development of aeronautical epoxy nanocomposites having an integrated selfhealing abilityGuadagno LiberataVertuccio LuigiNaddeo CarloCalabrese ElisaBarra GiuseppinaRaimondo MarialuigiaSorrentino AndreaBinder Wolfgang H.Michael PhilippRana SravendraFunctionalized multi-wall carbon nanotubes (MWCNTs) have been embedded in a rubber-toughened epoxy formulation in order to explore the possibility to impart an auto-repair function to the epoxy matrix. The nanofiller has been covalently functionalized with hydrogen bonding moieties able to act as donor and acceptor of hydrogen bondings. Healing efficiencies have been evaluated for nano charged epoxy formulations at a loading of 0.5% wt/wt of functionalized MWCNTs bearing barbituric acid and thymine-based ligands. For both the performed functionalizations, a self-healing efficiency higher than 50% has been found. Dynamic Mechanical Analysis (DMA) highlights that the inclusion of nanofiller increases the storage moduli. Furthermore, DMA analysis evidences the presence of a phase characterized by a greater mobility of the epoxy chains, which promotes the activation of self-healing mechanisms.https://doi.org/10.1051/matecconf/201823300021 |
| spellingShingle | Guadagno Liberata Vertuccio Luigi Naddeo Carlo Calabrese Elisa Barra Giuseppina Raimondo Marialuigia Sorrentino Andrea Binder Wolfgang H. Michael Philipp Rana Sravendra Development of aeronautical epoxy nanocomposites having an integrated selfhealing ability MATEC Web of Conferences |
| title | Development of aeronautical epoxy nanocomposites having an integrated selfhealing ability |
| title_full | Development of aeronautical epoxy nanocomposites having an integrated selfhealing ability |
| title_fullStr | Development of aeronautical epoxy nanocomposites having an integrated selfhealing ability |
| title_full_unstemmed | Development of aeronautical epoxy nanocomposites having an integrated selfhealing ability |
| title_short | Development of aeronautical epoxy nanocomposites having an integrated selfhealing ability |
| title_sort | development of aeronautical epoxy nanocomposites having an integrated selfhealing ability |
| url | https://doi.org/10.1051/matecconf/201823300021 |
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