Zr-Based Metal−Organic Frameworks with Phosphoric Acids for the Photo-Oxidation of Sulfides
Heterogeneous Brønsted acidic catalysts such as phosphoric acids are the conventional activators for organic transformations. However, the photocatalytic performance of these catalysts is still rarely explored. Herein, a novel Zr-based metal−organic framework <b>Zr-MOF-P</b> with phospho...
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MDPI AG
2022-12-01
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| Series: | International Journal of Molecular Sciences |
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| Online Access: | https://www.mdpi.com/1422-0067/23/24/16121 |
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| author | Zhenghua Zhao Mingjie Liu Kai Zhou Hantao Gong Yajing Shen Zongbi Bao Qiwei Yang Qilong Ren Zhiguo Zhang |
| author_facet | Zhenghua Zhao Mingjie Liu Kai Zhou Hantao Gong Yajing Shen Zongbi Bao Qiwei Yang Qilong Ren Zhiguo Zhang |
| author_sort | Zhenghua Zhao |
| collection | DOAJ |
| description | Heterogeneous Brønsted acidic catalysts such as phosphoric acids are the conventional activators for organic transformations. However, the photocatalytic performance of these catalysts is still rarely explored. Herein, a novel Zr-based metal−organic framework <b>Zr-MOF-P</b> with phosphoric acids as a heterogeneous photocatalyst has been fabricated, which shows high selectivity and reactivity towards the photo-oxidation of sulfides under white light illumination. A mechanism study indicates that the selective oxygenation of sulfides occurs with triplet oxygen rather than common reactive oxygen species (ROS). When <b>Zr-MOF-P</b> is irradiated, the hydroxyl group of phosphoric acid is converted into oxygen radical, which takes an electron from the sulfides, and then the activated substrates react with the triplet oxygen to form sulfoxides, avoiding the destruction of the catalysts and endowing the reaction with high substrate compatibility and fine recyclability. |
| first_indexed | 2024-03-09T16:18:25Z |
| format | Article |
| id | doaj.art-09cf21039a1e436cb8ee1de90f9284a2 |
| institution | Directory Open Access Journal |
| issn | 1661-6596 1422-0067 |
| language | English |
| last_indexed | 2024-03-09T16:18:25Z |
| publishDate | 2022-12-01 |
| publisher | MDPI AG |
| record_format | Article |
| series | International Journal of Molecular Sciences |
| spelling | doaj.art-09cf21039a1e436cb8ee1de90f9284a22023-11-24T15:33:21ZengMDPI AGInternational Journal of Molecular Sciences1661-65961422-00672022-12-0123241612110.3390/ijms232416121Zr-Based Metal−Organic Frameworks with Phosphoric Acids for the Photo-Oxidation of SulfidesZhenghua Zhao0Mingjie Liu1Kai Zhou2Hantao Gong3Yajing Shen4Zongbi Bao5Qiwei Yang6Qilong Ren7Zhiguo Zhang8Key Laboratory of Biomass Chemical Engineering of Ministry of Education, College of Chemical and Biological Engineering, Zhejiang University, Hangzhou 310058, ChinaKey Laboratory of Biomass Chemical Engineering of Ministry of Education, College of Chemical and Biological Engineering, Zhejiang University, Hangzhou 310058, ChinaKey Laboratory of Biomass Chemical Engineering of Ministry of Education, College of Chemical and Biological Engineering, Zhejiang University, Hangzhou 310058, ChinaKey Laboratory of Biomass Chemical Engineering of Ministry of Education, College of Chemical and Biological Engineering, Zhejiang University, Hangzhou 310058, ChinaInstitute of Zhejiang University—Quzhou, Quzhou 324000, ChinaKey Laboratory of Biomass Chemical Engineering of Ministry of Education, College of Chemical and Biological Engineering, Zhejiang University, Hangzhou 310058, ChinaKey Laboratory of Biomass Chemical Engineering of Ministry of Education, College of Chemical and Biological Engineering, Zhejiang University, Hangzhou 310058, ChinaKey Laboratory of Biomass Chemical Engineering of Ministry of Education, College of Chemical and Biological Engineering, Zhejiang University, Hangzhou 310058, ChinaKey Laboratory of Biomass Chemical Engineering of Ministry of Education, College of Chemical and Biological Engineering, Zhejiang University, Hangzhou 310058, ChinaHeterogeneous Brønsted acidic catalysts such as phosphoric acids are the conventional activators for organic transformations. However, the photocatalytic performance of these catalysts is still rarely explored. Herein, a novel Zr-based metal−organic framework <b>Zr-MOF-P</b> with phosphoric acids as a heterogeneous photocatalyst has been fabricated, which shows high selectivity and reactivity towards the photo-oxidation of sulfides under white light illumination. A mechanism study indicates that the selective oxygenation of sulfides occurs with triplet oxygen rather than common reactive oxygen species (ROS). When <b>Zr-MOF-P</b> is irradiated, the hydroxyl group of phosphoric acid is converted into oxygen radical, which takes an electron from the sulfides, and then the activated substrates react with the triplet oxygen to form sulfoxides, avoiding the destruction of the catalysts and endowing the reaction with high substrate compatibility and fine recyclability.https://www.mdpi.com/1422-0067/23/24/16121metal−organic frameworksphosphoric acidphoto-oxidationoxygen radical |
| spellingShingle | Zhenghua Zhao Mingjie Liu Kai Zhou Hantao Gong Yajing Shen Zongbi Bao Qiwei Yang Qilong Ren Zhiguo Zhang Zr-Based Metal−Organic Frameworks with Phosphoric Acids for the Photo-Oxidation of Sulfides International Journal of Molecular Sciences metal−organic frameworks phosphoric acid photo-oxidation oxygen radical |
| title | Zr-Based Metal−Organic Frameworks with Phosphoric Acids for the Photo-Oxidation of Sulfides |
| title_full | Zr-Based Metal−Organic Frameworks with Phosphoric Acids for the Photo-Oxidation of Sulfides |
| title_fullStr | Zr-Based Metal−Organic Frameworks with Phosphoric Acids for the Photo-Oxidation of Sulfides |
| title_full_unstemmed | Zr-Based Metal−Organic Frameworks with Phosphoric Acids for the Photo-Oxidation of Sulfides |
| title_short | Zr-Based Metal−Organic Frameworks with Phosphoric Acids for the Photo-Oxidation of Sulfides |
| title_sort | zr based metal organic frameworks with phosphoric acids for the photo oxidation of sulfides |
| topic | metal−organic frameworks phosphoric acid photo-oxidation oxygen radical |
| url | https://www.mdpi.com/1422-0067/23/24/16121 |
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