X-photon laser direct write 3D nanolithography
Multiphoton photopolymerisation (MPP), also known as 3D nanoprinting, was studied using a wavelength-tunable femtosecond laser. The possibility of using any colour of the spectrum from 500 to 1200 nm with a fixed pulse width of 100 fs revealed an interplay of photophysical mechanisms more delicate t...
Main Authors: | , , , , , , , , , , |
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Format: | Article |
Language: | English |
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Taylor & Francis Group
2023-12-01
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Series: | Virtual and Physical Prototyping |
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Online Access: | http://dx.doi.org/10.1080/17452759.2023.2228324 |
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author | Edvinas Skliutas Danielius Samsonas Arūnas Čiburys Lukas Kontenis Darius Gailevičius Jonas Berzinš Donatas Narbutis Vytautas Jukna Mikas Vengris Saulius Juodkazis Mangirdas Malinauskas |
author_facet | Edvinas Skliutas Danielius Samsonas Arūnas Čiburys Lukas Kontenis Darius Gailevičius Jonas Berzinš Donatas Narbutis Vytautas Jukna Mikas Vengris Saulius Juodkazis Mangirdas Malinauskas |
author_sort | Edvinas Skliutas |
collection | DOAJ |
description | Multiphoton photopolymerisation (MPP), also known as 3D nanoprinting, was studied using a wavelength-tunable femtosecond laser. The possibility of using any colour of the spectrum from 500 to 1200 nm with a fixed pulse width of 100 fs revealed an interplay of photophysical mechanisms more delicate than just two-photon photopolymerisation. An effective order of absorption, i.e. the X-photon absorption, as well as optimal exposure conditions were assessed for photosensitised and pure SZ2080$^{{\rm TM}}$ pre-polymer. The tunability of wavelength greatly influenced the dynamic fabrication window (DFW), optimised conditions resulting in a 10-fold increase. Furthermore, a non-trivial energy deposition by X-photon absorption was noted with an onset of a strong lateral size increase at longer wavelengths and can be understood as due to reaching epsilon-near-zero conditions. Such a control over the voxel aspect ratio and, consequently, the photopolymerised volume, may boost 3D nanoprinting efficiency. Overall, the results reveal wavelength being an important degree of freedom to tailor the MPP process and, if optimised, benefiting broad applications in areas of micro-optics, nanophotonic devices, metamaterials and tissue engineering. |
first_indexed | 2024-03-11T23:02:13Z |
format | Article |
id | doaj.art-09d1033a2cac46d4b2028c9d92316b6a |
institution | Directory Open Access Journal |
issn | 1745-2759 1745-2767 |
language | English |
last_indexed | 2024-03-11T23:02:13Z |
publishDate | 2023-12-01 |
publisher | Taylor & Francis Group |
record_format | Article |
series | Virtual and Physical Prototyping |
spelling | doaj.art-09d1033a2cac46d4b2028c9d92316b6a2023-09-21T14:38:04ZengTaylor & Francis GroupVirtual and Physical Prototyping1745-27591745-27672023-12-0118110.1080/17452759.2023.22283242228324X-photon laser direct write 3D nanolithographyEdvinas Skliutas0Danielius Samsonas1Arūnas Čiburys2Lukas Kontenis3Darius Gailevičius4Jonas Berzinš5Donatas Narbutis6Vytautas Jukna7Mikas Vengris8Saulius Juodkazis9Mangirdas Malinauskas10Vilnius UniversityVilnius UniversityVilnius UniversityLight ConversionVilnius UniversityLight ConversionVilnius UniversityVilnius UniversityVilnius UniversitySwinburne University of TechnologyVilnius UniversityMultiphoton photopolymerisation (MPP), also known as 3D nanoprinting, was studied using a wavelength-tunable femtosecond laser. The possibility of using any colour of the spectrum from 500 to 1200 nm with a fixed pulse width of 100 fs revealed an interplay of photophysical mechanisms more delicate than just two-photon photopolymerisation. An effective order of absorption, i.e. the X-photon absorption, as well as optimal exposure conditions were assessed for photosensitised and pure SZ2080$^{{\rm TM}}$ pre-polymer. The tunability of wavelength greatly influenced the dynamic fabrication window (DFW), optimised conditions resulting in a 10-fold increase. Furthermore, a non-trivial energy deposition by X-photon absorption was noted with an onset of a strong lateral size increase at longer wavelengths and can be understood as due to reaching epsilon-near-zero conditions. Such a control over the voxel aspect ratio and, consequently, the photopolymerised volume, may boost 3D nanoprinting efficiency. Overall, the results reveal wavelength being an important degree of freedom to tailor the MPP process and, if optimised, benefiting broad applications in areas of micro-optics, nanophotonic devices, metamaterials and tissue engineering.http://dx.doi.org/10.1080/17452759.2023.2228324multi-photon photopolymerisationlaser direct writingorder of absorptiontunable wavelengthgroup delay dispersionresolution bridges |
spellingShingle | Edvinas Skliutas Danielius Samsonas Arūnas Čiburys Lukas Kontenis Darius Gailevičius Jonas Berzinš Donatas Narbutis Vytautas Jukna Mikas Vengris Saulius Juodkazis Mangirdas Malinauskas X-photon laser direct write 3D nanolithography Virtual and Physical Prototyping multi-photon photopolymerisation laser direct writing order of absorption tunable wavelength group delay dispersion resolution bridges |
title | X-photon laser direct write 3D nanolithography |
title_full | X-photon laser direct write 3D nanolithography |
title_fullStr | X-photon laser direct write 3D nanolithography |
title_full_unstemmed | X-photon laser direct write 3D nanolithography |
title_short | X-photon laser direct write 3D nanolithography |
title_sort | x photon laser direct write 3d nanolithography |
topic | multi-photon photopolymerisation laser direct writing order of absorption tunable wavelength group delay dispersion resolution bridges |
url | http://dx.doi.org/10.1080/17452759.2023.2228324 |
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