Conductive Composites Based on Polyurethane and Nanostructured Conductive Filler of Montmorillonite/Polypyrrole for Electromagnetic Shielding Applications

Conductive Composites Based on Polyurethane and Nanostructured Conductive Filler of Montmorillonite/Polypyrrole for Electromagnetic Shielding Applications

In this study, composites based on polyurethane (PU) derived from castor oil and montmorillonite/polypyrrole doped with dodecylbenzenesulfonic acid (MMt-PPy.DBSA) were developed. In order to investigate the potential use of these materials for electromagnetic shielding applications, the electrical a...

Full description

Bibliographic Details
Main Authors: Patricia Cristine Vargas, Claudia Merlini, Sílvia Daniela Araújo da Silva Ramôa, Rafael Arenhart, Guilherme Mariz de Oliveira Barra, Bluma Guenther Soares
Format: Article
Language:English
Published: Associação Brasileira de Metalurgia e Materiais (ABM); Associação Brasileira de Cerâmica (ABC); Associação Brasileira de Polímeros (ABPol) 2018-07-01
Series:Materials Research
Subjects:
Polypyrrole
montmorillonite
polyurethane derived from castor oil
electromagnetic interference shielding application
Online Access:http://www.scielo.br/pdf/mr/v21n5/1516-1439-mr-21-05-e20180014.pdf
Description
Summary:In this study, composites based on polyurethane (PU) derived from castor oil and montmorillonite/polypyrrole doped with dodecylbenzenesulfonic acid (MMt-PPy.DBSA) were developed. In order to investigate the potential use of these materials for electromagnetic shielding applications, the electrical and mechanical properties of PU/MMt-PPy.DBSA composites were determined and compared with composites containing neat PPy.DBSA. The electrical conductivity of PU/MMt-PPy.DBSA composites was found to be higher than those for PU/PPy.DBSA with a similar filler content. Additionally, with a higher conductive additive content, significant increases in the tensile stress (σ) and elastic modulus (E) were observed, suggesting that MMt-PPy.DBSA acts as reinforcing agent for the PU matrix. The electromagnetic interference shielding effectiveness (EMI SE) of composites is mainly dependent on the morphology and filler content. The PU/MMt-PPy.DBSA composite containing 25 wt % of MMt-PPy.DBSA showed a maximum EMI SE of -21 dB, which is similar to the value required for commercial applications (-20 dB). The results revealed that PU/MMt-PPy.DBSA composites are promising materials for electromagnetic shielding applications.
ISSN:1516-1439

Similar Items