Catalytic Enantioselective Addition of Alkylzirconium Reagents to Aliphatic Aldehydes

Catalytic Enantioselective Addition of Alkylzirconium Reagents to Aliphatic Aldehydes

A catalytic methodology for the enantioselective addition of alkylzirconium reagents to aliphatic aldehydes is reported here. The versatile and readily accessible chiral Ph-BINMOL ligand, in the presence of Ti(O<i><sup>i</sup></i>Pr)<sub>4</sub> and a zinc salt, f...

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Bibliographic Details
Main Authors: Jade Vaccari, María José González-Soria, Nicholas Carter, Beatriz Maciá
Format: Article
Language:English
Published: MDPI AG 2021-07-01
Series:Molecules
Subjects:
alkenes
Schwartz reagent
enantioselective catalysis
titanium-diol complex
aliphatic aldehydes
Online Access:https://www.mdpi.com/1420-3049/26/15/4471

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