μ3-Oxido-hexa-μ2-pivalato-tris[(methanol-κO)cobalt(III)] chloride
The crystal structure of the title compound, [Co3(C5H9O2)6O(CH4O)3]Cl, consists of trinuclear CoIII complex cations and chloride anions. The CoIII cation has site symmetry m, and is coordinated by four oxygen atoms from four bridging pivalate groups, one central O anion and a methanol oxygen atom, f...
| Main Authors: | , , |
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| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2009-11-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536809041907 |
| _version_ | 1819105809726963712 |
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| author | Yu Sun Li-Li Zhu Huai-Hong Zhang |
| author_facet | Yu Sun Li-Li Zhu Huai-Hong Zhang |
| author_sort | Yu Sun |
| collection | DOAJ |
| description | The crystal structure of the title compound, [Co3(C5H9O2)6O(CH4O)3]Cl, consists of trinuclear CoIII complex cations and chloride anions. The CoIII cation has site symmetry m, and is coordinated by four oxygen atoms from four bridging pivalate groups, one central O anion and a methanol oxygen atom, forming a distorted octahedral geometry. The coordinated methanol molecule is located on a crystallographic special position, the C and O atoms being located on the mirror plane. The central O anion lies in the crystallographic overline6 position, and acts as a μ3-O bridge, linking three equivalent CoIII cations and generating the oxo-centered trinuclear CoIII complex. The chloride anion, which acts as the counter-ion, is located on crystallographic overline6 position. O—H...Cl hydrogen bonding between the Cl anion and hydroxyl group of the coordinated methanol molecule links the molecules into a supramolecular network. |
| first_indexed | 2024-12-22T02:28:09Z |
| format | Article |
| id | doaj.art-0a0365cb971f4e21874d76c9c6f1a88c |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-22T02:28:09Z |
| publishDate | 2009-11-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-0a0365cb971f4e21874d76c9c6f1a88c2022-12-21T18:41:56ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682009-11-016511m1402m140310.1107/S1600536809041907μ3-Oxido-hexa-μ2-pivalato-tris[(methanol-κO)cobalt(III)] chlorideYu SunLi-Li ZhuHuai-Hong ZhangThe crystal structure of the title compound, [Co3(C5H9O2)6O(CH4O)3]Cl, consists of trinuclear CoIII complex cations and chloride anions. The CoIII cation has site symmetry m, and is coordinated by four oxygen atoms from four bridging pivalate groups, one central O anion and a methanol oxygen atom, forming a distorted octahedral geometry. The coordinated methanol molecule is located on a crystallographic special position, the C and O atoms being located on the mirror plane. The central O anion lies in the crystallographic overline6 position, and acts as a μ3-O bridge, linking three equivalent CoIII cations and generating the oxo-centered trinuclear CoIII complex. The chloride anion, which acts as the counter-ion, is located on crystallographic overline6 position. O—H...Cl hydrogen bonding between the Cl anion and hydroxyl group of the coordinated methanol molecule links the molecules into a supramolecular network.http://scripts.iucr.org/cgi-bin/paper?S1600536809041907 |
| spellingShingle | Yu Sun Li-Li Zhu Huai-Hong Zhang μ3-Oxido-hexa-μ2-pivalato-tris[(methanol-κO)cobalt(III)] chloride Acta Crystallographica Section E |
| title | μ3-Oxido-hexa-μ2-pivalato-tris[(methanol-κO)cobalt(III)] chloride |
| title_full | μ3-Oxido-hexa-μ2-pivalato-tris[(methanol-κO)cobalt(III)] chloride |
| title_fullStr | μ3-Oxido-hexa-μ2-pivalato-tris[(methanol-κO)cobalt(III)] chloride |
| title_full_unstemmed | μ3-Oxido-hexa-μ2-pivalato-tris[(methanol-κO)cobalt(III)] chloride |
| title_short | μ3-Oxido-hexa-μ2-pivalato-tris[(methanol-κO)cobalt(III)] chloride |
| title_sort | amp 956 3 oxido hexa amp 956 2 pivalato tris methanol amp 954 o cobalt iii chloride |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536809041907 |
| work_keys_str_mv | AT yusun amp9563oxidohexaamp9562pivalatotrismethanolamp954ocobaltiiichloride AT lilizhu amp9563oxidohexaamp9562pivalatotrismethanolamp954ocobaltiiichloride AT huaihongzhang amp9563oxidohexaamp9562pivalatotrismethanolamp954ocobaltiiichloride |