Electrochemical promotion of propane oxidation on Pt deposited on a dense β"-Al2O3 ceramic Ag+ conductor

A new kind of electrochemical catalyst based on a Pt porous catalyst film deposited on a β"-Al2O3 ceramic Ag+ conductor was developed and evaluated during propane oxidation. It was observed that upon anodic polarization, the rate of propane combustion was significantly electropromoted up to...

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Main Authors: Michail eTsampas, Anastasios eKambolis, Emil eObeid, Leonardo eLizarraga, Foteini eSapountzi, Philippe eVernoux
Format: Article
Language:English
Published: Frontiers Media S.A. 2013-08-01
Series:Frontiers in Chemistry
Subjects:
Online Access:http://journal.frontiersin.org/Journal/10.3389/fchem.2013.00013/full
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author Michail eTsampas
Anastasios eKambolis
Emil eObeid
Leonardo eLizarraga
Foteini eSapountzi
Philippe eVernoux
author_facet Michail eTsampas
Anastasios eKambolis
Emil eObeid
Leonardo eLizarraga
Foteini eSapountzi
Philippe eVernoux
author_sort Michail eTsampas
collection DOAJ
description A new kind of electrochemical catalyst based on a Pt porous catalyst film deposited on a β"-Al2O3 ceramic Ag+ conductor was developed and evaluated during propane oxidation. It was observed that upon anodic polarization, the rate of propane combustion was significantly electropromoted up to 400%. Moreover, for the first time, exponential increase of the catalytic rate was evidenced during galvanostatic transient experiment in excellent agreement with EPOC equation.
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spelling doaj.art-0a0bd19c0fbd4e11992aaf8a5de2768d2022-12-21T19:09:55ZengFrontiers Media S.A.Frontiers in Chemistry2296-26462013-08-01110.3389/fchem.2013.0001356557Electrochemical promotion of propane oxidation on Pt deposited on a dense β"-Al2O3 ceramic Ag+ conductorMichail eTsampas0Anastasios eKambolis1Emil eObeid2Leonardo eLizarraga3Foteini eSapountzi4Philippe eVernoux5University Lyon 1University Lyon 1University Lyon 1University Lyon 1Centre National de la Recherche ScientifiqueCentre National de la Recherche ScientifiqueA new kind of electrochemical catalyst based on a Pt porous catalyst film deposited on a β"-Al2O3 ceramic Ag+ conductor was developed and evaluated during propane oxidation. It was observed that upon anodic polarization, the rate of propane combustion was significantly electropromoted up to 400%. Moreover, for the first time, exponential increase of the catalytic rate was evidenced during galvanostatic transient experiment in excellent agreement with EPOC equation.http://journal.frontiersin.org/Journal/10.3389/fchem.2013.00013/fullEPOCNEMCA effectPropane combustionβ-Al2O3 (Ag+) electrochemical catalystsAg+ cations
spellingShingle Michail eTsampas
Anastasios eKambolis
Emil eObeid
Leonardo eLizarraga
Foteini eSapountzi
Philippe eVernoux
Electrochemical promotion of propane oxidation on Pt deposited on a dense β"-Al2O3 ceramic Ag+ conductor
Frontiers in Chemistry
EPOC
NEMCA effect
Propane combustion
β-Al2O3 (Ag+) electrochemical catalysts
Ag+ cations
title Electrochemical promotion of propane oxidation on Pt deposited on a dense β"-Al2O3 ceramic Ag+ conductor
title_full Electrochemical promotion of propane oxidation on Pt deposited on a dense β"-Al2O3 ceramic Ag+ conductor
title_fullStr Electrochemical promotion of propane oxidation on Pt deposited on a dense β"-Al2O3 ceramic Ag+ conductor
title_full_unstemmed Electrochemical promotion of propane oxidation on Pt deposited on a dense β"-Al2O3 ceramic Ag+ conductor
title_short Electrochemical promotion of propane oxidation on Pt deposited on a dense β"-Al2O3 ceramic Ag+ conductor
title_sort electrochemical promotion of propane oxidation on pt deposited on a dense β quot al2o3 ceramic ag conductor
topic EPOC
NEMCA effect
Propane combustion
β-Al2O3 (Ag+) electrochemical catalysts
Ag+ cations
url http://journal.frontiersin.org/Journal/10.3389/fchem.2013.00013/full
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