Heavy Oil Fly Ash as an Adsorbent for Methylene Blue Removal from Aqueous Solution

The industry produces a large amount of solid waste that has very bad effects on the environment. The application of waste material adsorbents for waste materials treatment has become of greater interest. Heavy oil fly ash (HOFA) is hazardous industrial solid waste which produces from the combustio...

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Main Authors: Faten Hameed Kamil, Waleed Mohammed Abood, Yousra Mohammed, Zuhair Khedair
Format: Article
Language:English
Published: Corporation of Research and Industrial Development 2022-12-01
Series:Iraqi Journal of Industrial Research
Subjects:
Online Access:http://ijoir.gov.iq/ijoir/index.php/jou/article/view/262
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author Faten Hameed Kamil
Waleed Mohammed Abood
Yousra Mohammed
Zuhair Khedair
author_facet Faten Hameed Kamil
Waleed Mohammed Abood
Yousra Mohammed
Zuhair Khedair
author_sort Faten Hameed Kamil
collection DOAJ
description The industry produces a large amount of solid waste that has very bad effects on the environment. The application of waste material adsorbents for waste materials treatment has become of greater interest. Heavy oil fly ash (HOFA) is hazardous industrial solid waste which produces from the combustion of heavy fuel oil in power plants. The work aims to investigate using waste material heavy oil fly ash (HOFA) after modification to activated carbon (AC) as an adsorbent of methylene blue (MB) in an aqueous solution. Chemical and physical analyses were conducted to characterize the HOFA produced as a by-product of an electrical power station. BET analysis showed the surface area was 1.6 m2/g and the surface area was enhanced by the activation process to 63.7 m2/g and the pore width to 553.5A. SEM showed a change in the nature of the surface of the martial by increasing the porosity. Adsorption studies were performed by batch experiments as a function of process parameters. The removal percentage increased with the increase of the adsorbent to 1.5g, the amount was selected as the optimum dosage. The removal percentage decreased with an increase the entail dye concentration and limited difference in pH variables. The experimental adsorption data was represented with Langmuir, Freundlich, and Tempkin isotherms. The data fitted well to the Freundlich model as multilayer adsorption.
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spelling doaj.art-0a21738a129e477a9c84d40713a1bae22024-12-24T05:19:38ZengCorporation of Research and Industrial DevelopmentIraqi Journal of Industrial Research2788-712X2022-12-019310.53523/ijoirVol9I3ID262262Heavy Oil Fly Ash as an Adsorbent for Methylene Blue Removal from Aqueous SolutionFaten Hameed Kamil0Waleed Mohammed Abood1Yousra Mohammed2Zuhair Khedair3Chemical and Petrochemical Research Center/ Corporation of Research and Industrial Development – IraqChemical and Petrochemical Research Center/ Corporation of Research and Industrial Development – IraqChemical and Petrochemical Research Center/ Corporation of Research and Industrial Development – IraqChemical and Petrochemical Research Center/ Corporation of Research and Industrial Development – Iraq The industry produces a large amount of solid waste that has very bad effects on the environment. The application of waste material adsorbents for waste materials treatment has become of greater interest. Heavy oil fly ash (HOFA) is hazardous industrial solid waste which produces from the combustion of heavy fuel oil in power plants. The work aims to investigate using waste material heavy oil fly ash (HOFA) after modification to activated carbon (AC) as an adsorbent of methylene blue (MB) in an aqueous solution. Chemical and physical analyses were conducted to characterize the HOFA produced as a by-product of an electrical power station. BET analysis showed the surface area was 1.6 m2/g and the surface area was enhanced by the activation process to 63.7 m2/g and the pore width to 553.5A. SEM showed a change in the nature of the surface of the martial by increasing the porosity. Adsorption studies were performed by batch experiments as a function of process parameters. The removal percentage increased with the increase of the adsorbent to 1.5g, the amount was selected as the optimum dosage. The removal percentage decreased with an increase the entail dye concentration and limited difference in pH variables. The experimental adsorption data was represented with Langmuir, Freundlich, and Tempkin isotherms. The data fitted well to the Freundlich model as multilayer adsorption. http://ijoir.gov.iq/ijoir/index.php/jou/article/view/262Heavy oil fly ashActivated carbonAdsorption
spellingShingle Faten Hameed Kamil
Waleed Mohammed Abood
Yousra Mohammed
Zuhair Khedair
Heavy Oil Fly Ash as an Adsorbent for Methylene Blue Removal from Aqueous Solution
Iraqi Journal of Industrial Research
Heavy oil fly ash
Activated carbon
Adsorption
title Heavy Oil Fly Ash as an Adsorbent for Methylene Blue Removal from Aqueous Solution
title_full Heavy Oil Fly Ash as an Adsorbent for Methylene Blue Removal from Aqueous Solution
title_fullStr Heavy Oil Fly Ash as an Adsorbent for Methylene Blue Removal from Aqueous Solution
title_full_unstemmed Heavy Oil Fly Ash as an Adsorbent for Methylene Blue Removal from Aqueous Solution
title_short Heavy Oil Fly Ash as an Adsorbent for Methylene Blue Removal from Aqueous Solution
title_sort heavy oil fly ash as an adsorbent for methylene blue removal from aqueous solution
topic Heavy oil fly ash
Activated carbon
Adsorption
url http://ijoir.gov.iq/ijoir/index.php/jou/article/view/262
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AT waleedmohammedabood heavyoilflyashasanadsorbentformethyleneblueremovalfromaqueoussolution
AT yousramohammed heavyoilflyashasanadsorbentformethyleneblueremovalfromaqueoussolution
AT zuhairkhedair heavyoilflyashasanadsorbentformethyleneblueremovalfromaqueoussolution