The structure of 9-(3-bromo-6-chloro-2-hydroxyphenyl)-10-(2-hydroxyethyl)-3,6-diphenyl-3,4,5,6,7,9-hexahydro-2H-acridine-1,8-dione
In the structure of the title compound C33H29BrClNO4, (I), the hexahydro-2H-acridine ring system has a hydroxyethyl substituent on the N atom and a 3-bromo-6-chloro-2-hydroxyphenyl substituent on the central C atom at the 9-position. An unusual feature of the molecule is that the substituents at the...
| Main Authors: | , , , , |
|---|---|
| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2018-09-01
|
| Series: | Acta Crystallographica Section E: Crystallographic Communications |
| Subjects: | |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S2056989018010873 |
| Summary: | In the structure of the title compound C33H29BrClNO4, (I), the hexahydro-2H-acridine ring system has a hydroxyethyl substituent on the N atom and a 3-bromo-6-chloro-2-hydroxyphenyl substituent on the central C atom at the 9-position. An unusual feature of the molecule is that the substituents at the 3- and 5-positions of the outer cyclohexenone rings are phenyl rings rather than the more common dimethyl substituents. C atoms on both of the cyclohexenone rings are disordered over two sites. In the crystal structure, O—H...O, C—H...O and C—H...π(ring) hydrogen bonds combine with an Br—O and unusual C—Br...π(ring) halogen bonds to generate a three dimensional network with molecules stacked along the a-axis direction. |
|---|---|
| ISSN: | 2056-9890 |