Thermal and Rheological Performances Evaluation of a Modified Biopolymer for Fracturing Fluid System
Developing an efficient fracturing fluid system is an enduring hot topic in the petrochemical industries, especially regarding the exploitation of limited oil. Biopolymers, especially polysaccharides (e.g., konjac gum, guar gum), are widely applied as fracturing fluids in fracturing as a result of t...
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MDPI AG
2022-11-01
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| Series: | Molecules |
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| Online Access: | https://www.mdpi.com/1420-3049/27/22/7776 |
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| author | Guoyan Ma Le Wang Chao Hao Chunbao Du Hongfei Ma |
| author_facet | Guoyan Ma Le Wang Chao Hao Chunbao Du Hongfei Ma |
| author_sort | Guoyan Ma |
| collection | DOAJ |
| description | Developing an efficient fracturing fluid system is an enduring hot topic in the petrochemical industries, especially regarding the exploitation of limited oil. Biopolymers, especially polysaccharides (e.g., konjac gum, guar gum), are widely applied as fracturing fluids in fracturing as a result of their advantages. Herein, we propose an easy method of modifying konjac gum (KGM) using isopropanol, sodium hydroxide, and chloroacetic acid to obtain modified konjac glum (MKGM). The MKGM and KGM gels were also obtained by using the self-prepared organic titanium high-temperature stabilizer and organic borate cross-linker. The prepared MKGM was characterized by multiscale techniques, including attenuated total reflection Fourier transform infrared (ATR-FTIR), X-ray diffraction (XRD), thermal gravimetric analysis (TGA), differential scanning calorimetry (DSC), and rheology properties. The ATR-FTIR results showed that the etherification modification reaction occurred as designed. The XRD results showed that the regularity of KGM was destroyed after modification. The TGA and DSC results showed that the thermal stability improved. Rheology measurements illustrated that the temperature and shear resistance of MKGM were better than those of KGM. The MKGM gel could be applied in fracturing fluid systems at a lower frequency through viscoelastic measurements. |
| first_indexed | 2024-03-09T18:07:35Z |
| format | Article |
| id | doaj.art-0a5f620fe63d48bcbf25cc2bb1c54802 |
| institution | Directory Open Access Journal |
| issn | 1420-3049 |
| language | English |
| last_indexed | 2024-03-09T18:07:35Z |
| publishDate | 2022-11-01 |
| publisher | MDPI AG |
| record_format | Article |
| series | Molecules |
| spelling | doaj.art-0a5f620fe63d48bcbf25cc2bb1c548022023-11-24T09:20:58ZengMDPI AGMolecules1420-30492022-11-012722777610.3390/molecules27227776Thermal and Rheological Performances Evaluation of a Modified Biopolymer for Fracturing Fluid SystemGuoyan Ma0Le Wang1Chao Hao2Chunbao Du3Hongfei Ma4College of Chemistry and Chemical Engineering, Xi’an Shiyou University, Xi’an 710065, ChinaCollege of Chemistry and Chemical Engineering, Xi’an Shiyou University, Xi’an 710065, ChinaCCDC Drilling & Production Engineering Technology Research Institute, Xi’an 710018, ChinaCollege of Chemistry and Chemical Engineering, Xi’an Shiyou University, Xi’an 710065, ChinaDepartment of Chemical Engineering, Norwegian University of Science and Technology, Sem Sælands vei 4, 7034 Trondheim, NorwayDeveloping an efficient fracturing fluid system is an enduring hot topic in the petrochemical industries, especially regarding the exploitation of limited oil. Biopolymers, especially polysaccharides (e.g., konjac gum, guar gum), are widely applied as fracturing fluids in fracturing as a result of their advantages. Herein, we propose an easy method of modifying konjac gum (KGM) using isopropanol, sodium hydroxide, and chloroacetic acid to obtain modified konjac glum (MKGM). The MKGM and KGM gels were also obtained by using the self-prepared organic titanium high-temperature stabilizer and organic borate cross-linker. The prepared MKGM was characterized by multiscale techniques, including attenuated total reflection Fourier transform infrared (ATR-FTIR), X-ray diffraction (XRD), thermal gravimetric analysis (TGA), differential scanning calorimetry (DSC), and rheology properties. The ATR-FTIR results showed that the etherification modification reaction occurred as designed. The XRD results showed that the regularity of KGM was destroyed after modification. The TGA and DSC results showed that the thermal stability improved. Rheology measurements illustrated that the temperature and shear resistance of MKGM were better than those of KGM. The MKGM gel could be applied in fracturing fluid systems at a lower frequency through viscoelastic measurements.https://www.mdpi.com/1420-3049/27/22/7776biopolymersmodified konjac glumthermal stabilityshear resistanceviscoelastic property |
| spellingShingle | Guoyan Ma Le Wang Chao Hao Chunbao Du Hongfei Ma Thermal and Rheological Performances Evaluation of a Modified Biopolymer for Fracturing Fluid System Molecules biopolymers modified konjac glum thermal stability shear resistance viscoelastic property |
| title | Thermal and Rheological Performances Evaluation of a Modified Biopolymer for Fracturing Fluid System |
| title_full | Thermal and Rheological Performances Evaluation of a Modified Biopolymer for Fracturing Fluid System |
| title_fullStr | Thermal and Rheological Performances Evaluation of a Modified Biopolymer for Fracturing Fluid System |
| title_full_unstemmed | Thermal and Rheological Performances Evaluation of a Modified Biopolymer for Fracturing Fluid System |
| title_short | Thermal and Rheological Performances Evaluation of a Modified Biopolymer for Fracturing Fluid System |
| title_sort | thermal and rheological performances evaluation of a modified biopolymer for fracturing fluid system |
| topic | biopolymers modified konjac glum thermal stability shear resistance viscoelastic property |
| url | https://www.mdpi.com/1420-3049/27/22/7776 |
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