Energy storage properties of P(VDF‐TrFE‐CTFE)‐based composite dielectrics with uniform and gradient‐doped boron nitride nanosheets
Abstract Dielectric capacitors play an important role in advanced electronic and power systems such as portable electronic devices, hybrid electric vehicles and electronic weapon systems, and the improvement of energy storage density will have a positive effect on reducing the volume and weight of e...
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Wiley
2022-03-01
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Series: | IET Nanodielectrics |
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Online Access: | https://doi.org/10.1049/nde2.12024 |
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author | Yanan Shang Yu Feng Changming Li Changhai Zhang Tiandong Zhang Yongquan Zhang Yue Zhang Chunhui Song Qingguo Chi |
author_facet | Yanan Shang Yu Feng Changming Li Changhai Zhang Tiandong Zhang Yongquan Zhang Yue Zhang Chunhui Song Qingguo Chi |
author_sort | Yanan Shang |
collection | DOAJ |
description | Abstract Dielectric capacitors play an important role in advanced electronic and power systems such as portable electronic devices, hybrid electric vehicles and electronic weapon systems, and the improvement of energy storage density will have a positive effect on reducing the volume and weight of equipment. Here, a series of single‐layer dielectrics with boron nitride nanosheets (BNNSs) uniformly dispersed and multilayer dielectrics with BNNSs showing a positive gradient distribution (PGD) and inverse gradient distribution (IGD) in the poly(vinylidene fluoride‐trifluoroethylene‐chlorotrifluoroethylene) (P[VDF‐TrFE‐CTFE]) matrix were prepared by high‐speed electrospinning and hot press technology. It is found that the best performance is observed inthe lowest interlayer gradient component in both PGD and IGD composite dielectrics. However, the performance of PGD is better than that of IGD, and the 3‐5‐3 multilayer dielectric in the positive gradient structure has the best electrical performance. Its maximum energy storage density of the 3‐5‐3 composite dielectrics is 12.93 J/cm3 at the applied electric field of 380 kV/mm. The above research results show that the gradient structure design plays an important role in optimising the breakdown strength and energy storage characteristics of composite dielectrics. |
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language | English |
last_indexed | 2024-04-13T06:43:31Z |
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spelling | doaj.art-0aa8500973834f82bfb647aab4c9da2d2022-12-22T02:57:40ZengWileyIET Nanodielectrics2514-32552022-03-0151506110.1049/nde2.12024Energy storage properties of P(VDF‐TrFE‐CTFE)‐based composite dielectrics with uniform and gradient‐doped boron nitride nanosheetsYanan Shang0Yu Feng1Changming Li2Changhai Zhang3Tiandong Zhang4Yongquan Zhang5Yue Zhang6Chunhui Song7Qingguo Chi8Key Laboratory of Engineering Dielectrics and Its Application Ministry of Education Harbin University of Science and Technology Harbin ChinaKey Laboratory of Engineering Dielectrics and Its Application Ministry of Education Harbin University of Science and Technology Harbin ChinaKey Laboratory of Engineering Dielectrics and Its Application Ministry of Education Harbin University of Science and Technology Harbin ChinaKey Laboratory of Engineering Dielectrics and Its Application Ministry of Education Harbin University of Science and Technology Harbin ChinaKey Laboratory of Engineering Dielectrics and Its Application Ministry of Education Harbin University of Science and Technology Harbin ChinaKey Laboratory of Engineering Dielectrics and Its Application Ministry of Education Harbin University of Science and Technology Harbin ChinaKey Laboratory of Engineering Dielectrics and Its Application Ministry of Education Harbin University of Science and Technology Harbin ChinaKey Laboratory of Engineering Dielectrics and Its Application Ministry of Education Harbin University of Science and Technology Harbin ChinaKey Laboratory of Engineering Dielectrics and Its Application Ministry of Education Harbin University of Science and Technology Harbin ChinaAbstract Dielectric capacitors play an important role in advanced electronic and power systems such as portable electronic devices, hybrid electric vehicles and electronic weapon systems, and the improvement of energy storage density will have a positive effect on reducing the volume and weight of equipment. Here, a series of single‐layer dielectrics with boron nitride nanosheets (BNNSs) uniformly dispersed and multilayer dielectrics with BNNSs showing a positive gradient distribution (PGD) and inverse gradient distribution (IGD) in the poly(vinylidene fluoride‐trifluoroethylene‐chlorotrifluoroethylene) (P[VDF‐TrFE‐CTFE]) matrix were prepared by high‐speed electrospinning and hot press technology. It is found that the best performance is observed inthe lowest interlayer gradient component in both PGD and IGD composite dielectrics. However, the performance of PGD is better than that of IGD, and the 3‐5‐3 multilayer dielectric in the positive gradient structure has the best electrical performance. Its maximum energy storage density of the 3‐5‐3 composite dielectrics is 12.93 J/cm3 at the applied electric field of 380 kV/mm. The above research results show that the gradient structure design plays an important role in optimising the breakdown strength and energy storage characteristics of composite dielectrics.https://doi.org/10.1049/nde2.12024filled polymersmultilayersdielectric hysteresisnanofabricationdielectric lossesnanocomposites |
spellingShingle | Yanan Shang Yu Feng Changming Li Changhai Zhang Tiandong Zhang Yongquan Zhang Yue Zhang Chunhui Song Qingguo Chi Energy storage properties of P(VDF‐TrFE‐CTFE)‐based composite dielectrics with uniform and gradient‐doped boron nitride nanosheets IET Nanodielectrics filled polymers multilayers dielectric hysteresis nanofabrication dielectric losses nanocomposites |
title | Energy storage properties of P(VDF‐TrFE‐CTFE)‐based composite dielectrics with uniform and gradient‐doped boron nitride nanosheets |
title_full | Energy storage properties of P(VDF‐TrFE‐CTFE)‐based composite dielectrics with uniform and gradient‐doped boron nitride nanosheets |
title_fullStr | Energy storage properties of P(VDF‐TrFE‐CTFE)‐based composite dielectrics with uniform and gradient‐doped boron nitride nanosheets |
title_full_unstemmed | Energy storage properties of P(VDF‐TrFE‐CTFE)‐based composite dielectrics with uniform and gradient‐doped boron nitride nanosheets |
title_short | Energy storage properties of P(VDF‐TrFE‐CTFE)‐based composite dielectrics with uniform and gradient‐doped boron nitride nanosheets |
title_sort | energy storage properties of p vdf trfe ctfe based composite dielectrics with uniform and gradient doped boron nitride nanosheets |
topic | filled polymers multilayers dielectric hysteresis nanofabrication dielectric losses nanocomposites |
url | https://doi.org/10.1049/nde2.12024 |
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