Diaquatetrakis(μ-3-methoxybenzoato-κ2O1:O1′)dicopper(II)
The asymmetric unit of the binuclear title compound, [Cu2(C8H7O3)4(H2O)2], comprises two halves of diaquatetrakis(μ-3-methoxybenzoato-κ2O1:O1′)dicopper(II) units. The paddle-wheel structure of each complex is completed by application of inversion symmetry, with the inversion centre situated at the m...
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2020-04-01
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| Series: | IUCrData |
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| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S2414314620004484 |
| _version_ | 1818912567510171648 |
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| author | Bikshandarkoil R. Srinivasan Pooja H. Bhargao P. K. Sudhadevi |
| author_facet | Bikshandarkoil R. Srinivasan Pooja H. Bhargao P. K. Sudhadevi |
| author_sort | Bikshandarkoil R. Srinivasan |
| collection | DOAJ |
| description | The asymmetric unit of the binuclear title compound, [Cu2(C8H7O3)4(H2O)2], comprises two halves of diaquatetrakis(μ-3-methoxybenzoato-κ2O1:O1′)dicopper(II) units. The paddle-wheel structure of each complex is completed by application of inversion symmetry, with the inversion centre situated at the midpoint between two CuII atoms in each dimer. The two CuII atoms of each centrosymmetric dimer are bridged by four 3-methoxybenzoate anions resulting in Cu...Cu separations of 2.5961 (11) and 2.6060 (12) Å, respectively. The square-pyramidal coordination sphere of each CuII atom is completed by an apical water molecule. Intermolecular O—H...O hydrogen bonds of weak nature link the complexes into layers parallel to (100). The three-dimensional network structure is accomplished by C—H...O hydrogen bonds interlinking adjacent layers. |
| first_indexed | 2024-12-19T23:16:39Z |
| format | Article |
| id | doaj.art-0ac290656a4042ed93bb2b0d498a9b6b |
| institution | Directory Open Access Journal |
| issn | 2414-3146 |
| language | English |
| last_indexed | 2024-12-19T23:16:39Z |
| publishDate | 2020-04-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | IUCrData |
| spelling | doaj.art-0ac290656a4042ed93bb2b0d498a9b6b2022-12-21T20:02:04ZengInternational Union of CrystallographyIUCrData2414-31462020-04-0154x20044810.1107/S2414314620004484wm4126Diaquatetrakis(μ-3-methoxybenzoato-κ2O1:O1′)dicopper(II)Bikshandarkoil R. Srinivasan0Pooja H. Bhargao1P. K. Sudhadevi2School of Chemical Sciences, Goa University, Goa 403206, IndiaSchool of Chemical Sciences, Goa University, Goa 403206, IndiaSophisticated Analytical Instruments Facility (SAIF), Indian Institute of Technology Madras, Chennai 600036, IndiaThe asymmetric unit of the binuclear title compound, [Cu2(C8H7O3)4(H2O)2], comprises two halves of diaquatetrakis(μ-3-methoxybenzoato-κ2O1:O1′)dicopper(II) units. The paddle-wheel structure of each complex is completed by application of inversion symmetry, with the inversion centre situated at the midpoint between two CuII atoms in each dimer. The two CuII atoms of each centrosymmetric dimer are bridged by four 3-methoxybenzoate anions resulting in Cu...Cu separations of 2.5961 (11) and 2.6060 (12) Å, respectively. The square-pyramidal coordination sphere of each CuII atom is completed by an apical water molecule. Intermolecular O—H...O hydrogen bonds of weak nature link the complexes into layers parallel to (100). The three-dimensional network structure is accomplished by C—H...O hydrogen bonds interlinking adjacent layers.http://scripts.iucr.org/cgi-bin/paper?S2414314620004484crystal structurepaddle-wheel structurebinuclear copper complexhydrogen bonding |
| spellingShingle | Bikshandarkoil R. Srinivasan Pooja H. Bhargao P. K. Sudhadevi Diaquatetrakis(μ-3-methoxybenzoato-κ2O1:O1′)dicopper(II) IUCrData crystal structure paddle-wheel structure binuclear copper complex hydrogen bonding |
| title | Diaquatetrakis(μ-3-methoxybenzoato-κ2O1:O1′)dicopper(II) |
| title_full | Diaquatetrakis(μ-3-methoxybenzoato-κ2O1:O1′)dicopper(II) |
| title_fullStr | Diaquatetrakis(μ-3-methoxybenzoato-κ2O1:O1′)dicopper(II) |
| title_full_unstemmed | Diaquatetrakis(μ-3-methoxybenzoato-κ2O1:O1′)dicopper(II) |
| title_short | Diaquatetrakis(μ-3-methoxybenzoato-κ2O1:O1′)dicopper(II) |
| title_sort | diaquatetrakis μ 3 methoxybenzoato κ2o1 o1 dicopper ii |
| topic | crystal structure paddle-wheel structure binuclear copper complex hydrogen bonding |
| url | http://scripts.iucr.org/cgi-bin/paper?S2414314620004484 |
| work_keys_str_mv | AT bikshandarkoilrsrinivasan diaquatetrakism3methoxybenzoatok2o1o1dicopperii AT poojahbhargao diaquatetrakism3methoxybenzoatok2o1o1dicopperii AT pksudhadevi diaquatetrakism3methoxybenzoatok2o1o1dicopperii |