Sensing Capacity in Dysprosium Metal–Organic Frameworks Based on 5-Aminoisophthalic Acid Ligand

Two novel metal-organic frameworks (MOFs), based on dysprosium as the metal and the 5-aminoisophthalic acid (5aip) ligand, have been solvothermally synthesized, with the aim of studying and modulating their luminescence properties according to the variation of solvent in the structure. These materia...

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Main Authors: Javier Cepeda, Isabel Blasco-Pascual, Sara Rojas, Duane Choquesillo-Lazarte, Francisco J. Guerrero-Arroyo, Diego P. Morales, Jose Ángel García, Antonio Rodríguez-Diéguez, Alfonso Salinas-Castillo
Format: Article
Language:English
Published: MDPI AG 2022-04-01
Series:Sensors
Subjects:
Online Access:https://www.mdpi.com/1424-8220/22/9/3392
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author Javier Cepeda
Isabel Blasco-Pascual
Sara Rojas
Duane Choquesillo-Lazarte
Francisco J. Guerrero-Arroyo
Diego P. Morales
Jose Ángel García
Antonio Rodríguez-Diéguez
Alfonso Salinas-Castillo
author_facet Javier Cepeda
Isabel Blasco-Pascual
Sara Rojas
Duane Choquesillo-Lazarte
Francisco J. Guerrero-Arroyo
Diego P. Morales
Jose Ángel García
Antonio Rodríguez-Diéguez
Alfonso Salinas-Castillo
author_sort Javier Cepeda
collection DOAJ
description Two novel metal-organic frameworks (MOFs), based on dysprosium as the metal and the 5-aminoisophthalic acid (5aip) ligand, have been solvothermally synthesized, with the aim of studying and modulating their luminescence properties according to the variation of solvent in the structure. These materials display intense photo-luminescence properties in the solid state at room temperature. Interestingly, one fascinating sensory capacity of compound <b>2</b> regards obtaining a variation of the signal, depending on the solvent to which it is exposed. These results pave the way for a new generation of sensitive chemical sensors.
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spelling doaj.art-0ac60e946ffb456aba0f895266ac39f02023-11-23T09:17:49ZengMDPI AGSensors1424-82202022-04-01229339210.3390/s22093392Sensing Capacity in Dysprosium Metal–Organic Frameworks Based on 5-Aminoisophthalic Acid LigandJavier Cepeda0Isabel Blasco-Pascual1Sara Rojas2Duane Choquesillo-Lazarte3Francisco J. Guerrero-Arroyo4Diego P. Morales5Jose Ángel García6Antonio Rodríguez-Diéguez7Alfonso Salinas-Castillo8Department of Applied Chemistry, Faculty of Chemistry, University of the Basque Country (UPV/EHU), 20018 Donostia-San Sebastián, SpainDepartment of Analytical Chemistry, Faculty of Science, University of Granada, 18071 Granada, SpainDepartment of Inorganic Chemistry, Faculty of Science, University of Granada, 18071 Granada, SpainLaboratorio de Estudios Cristalográficos, IACT, CSIC-UGR, Av. Las Palmeras nº4, 18100 Granada, SpainDepartment of Inorganic Chemistry, Faculty of Science, University of Granada, 18071 Granada, SpainPervasive Electronics Advanced Research Laboratory (PEARL), Department Electronics and Computer Technology, University of Granada, 18071 Granada, SpainDepartamento de Física Aplicada II, Facultad de Ciencia y Tecnología, Universidad del País Vasco/Euskal Herriko Unibertsitatea (UPV/EHU), 48940 Leioa, SpainDepartment of Inorganic Chemistry, Faculty of Science, University of Granada, 18071 Granada, SpainDepartment of Analytical Chemistry, Faculty of Science, University of Granada, 18071 Granada, SpainTwo novel metal-organic frameworks (MOFs), based on dysprosium as the metal and the 5-aminoisophthalic acid (5aip) ligand, have been solvothermally synthesized, with the aim of studying and modulating their luminescence properties according to the variation of solvent in the structure. These materials display intense photo-luminescence properties in the solid state at room temperature. Interestingly, one fascinating sensory capacity of compound <b>2</b> regards obtaining a variation of the signal, depending on the solvent to which it is exposed. These results pave the way for a new generation of sensitive chemical sensors.https://www.mdpi.com/1424-8220/22/9/3392MOFdysprosium5-aminoisophthalicsensingluminescence
spellingShingle Javier Cepeda
Isabel Blasco-Pascual
Sara Rojas
Duane Choquesillo-Lazarte
Francisco J. Guerrero-Arroyo
Diego P. Morales
Jose Ángel García
Antonio Rodríguez-Diéguez
Alfonso Salinas-Castillo
Sensing Capacity in Dysprosium Metal–Organic Frameworks Based on 5-Aminoisophthalic Acid Ligand
Sensors
MOF
dysprosium
5-aminoisophthalic
sensing
luminescence
title Sensing Capacity in Dysprosium Metal–Organic Frameworks Based on 5-Aminoisophthalic Acid Ligand
title_full Sensing Capacity in Dysprosium Metal–Organic Frameworks Based on 5-Aminoisophthalic Acid Ligand
title_fullStr Sensing Capacity in Dysprosium Metal–Organic Frameworks Based on 5-Aminoisophthalic Acid Ligand
title_full_unstemmed Sensing Capacity in Dysprosium Metal–Organic Frameworks Based on 5-Aminoisophthalic Acid Ligand
title_short Sensing Capacity in Dysprosium Metal–Organic Frameworks Based on 5-Aminoisophthalic Acid Ligand
title_sort sensing capacity in dysprosium metal organic frameworks based on 5 aminoisophthalic acid ligand
topic MOF
dysprosium
5-aminoisophthalic
sensing
luminescence
url https://www.mdpi.com/1424-8220/22/9/3392
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