Aqua[4-(hydroxyiminomethyl)pyridine-κN1](iminodiacetato-κ3O,N,O′)copper(II)
In the title complex, [Cu(C4H5NO4)(C6H6N2O)(H2O)], conventionally abbreviated Cu(IDA)(4-OXPy)(H2O), where IDA is iminodiacetate and 4-OXPy is 4-(hydroxyiminomethyl)pyridine, the CuII atom exhibits a distorted square-pyramidal coordination geometry, which is constructed from two O atoms and one N ato...
| Main Authors: | , , , , |
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| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2011-09-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536811033459 |
| _version_ | 1818887128627544064 |
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| author | Yisheng Yang Wenxiang Chai Li Song Yunyun Yang Jiongke Chen |
| author_facet | Yisheng Yang Wenxiang Chai Li Song Yunyun Yang Jiongke Chen |
| author_sort | Yisheng Yang |
| collection | DOAJ |
| description | In the title complex, [Cu(C4H5NO4)(C6H6N2O)(H2O)], conventionally abbreviated Cu(IDA)(4-OXPy)(H2O), where IDA is iminodiacetate and 4-OXPy is 4-(hydroxyiminomethyl)pyridine, the CuII atom exhibits a distorted square-pyramidal coordination geometry, which is constructed from two O atoms and one N atom from a IDA ligand, one N atom from 4-OXPy ligand and one O atom from water. This molecule looks like a space shuttle, the IDA ligand is its empennage (tail), and the 4-OXPy ligand is its airframe. The complexes are linked into two-dimensional supramolecular layers parallel to (100) by three pairs of O—H...O hydrogen bonds. Two pairs of N—H...O hydrogen bonds further connect these supramolecular layers, forming a three-dimensional supramolecular network. |
| first_indexed | 2024-12-19T16:32:18Z |
| format | Article |
| id | doaj.art-0ad62702f7c74b19810fee0082921e0d |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-19T16:32:18Z |
| publishDate | 2011-09-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-0ad62702f7c74b19810fee0082921e0d2022-12-21T20:14:07ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682011-09-01679m1291m129210.1107/S1600536811033459Aqua[4-(hydroxyiminomethyl)pyridine-κN1](iminodiacetato-κ3O,N,O′)copper(II)Yisheng YangWenxiang ChaiLi SongYunyun YangJiongke ChenIn the title complex, [Cu(C4H5NO4)(C6H6N2O)(H2O)], conventionally abbreviated Cu(IDA)(4-OXPy)(H2O), where IDA is iminodiacetate and 4-OXPy is 4-(hydroxyiminomethyl)pyridine, the CuII atom exhibits a distorted square-pyramidal coordination geometry, which is constructed from two O atoms and one N atom from a IDA ligand, one N atom from 4-OXPy ligand and one O atom from water. This molecule looks like a space shuttle, the IDA ligand is its empennage (tail), and the 4-OXPy ligand is its airframe. The complexes are linked into two-dimensional supramolecular layers parallel to (100) by three pairs of O—H...O hydrogen bonds. Two pairs of N—H...O hydrogen bonds further connect these supramolecular layers, forming a three-dimensional supramolecular network.http://scripts.iucr.org/cgi-bin/paper?S1600536811033459 |
| spellingShingle | Yisheng Yang Wenxiang Chai Li Song Yunyun Yang Jiongke Chen Aqua[4-(hydroxyiminomethyl)pyridine-κN1](iminodiacetato-κ3O,N,O′)copper(II) Acta Crystallographica Section E |
| title | Aqua[4-(hydroxyiminomethyl)pyridine-κN1](iminodiacetato-κ3O,N,O′)copper(II) |
| title_full | Aqua[4-(hydroxyiminomethyl)pyridine-κN1](iminodiacetato-κ3O,N,O′)copper(II) |
| title_fullStr | Aqua[4-(hydroxyiminomethyl)pyridine-κN1](iminodiacetato-κ3O,N,O′)copper(II) |
| title_full_unstemmed | Aqua[4-(hydroxyiminomethyl)pyridine-κN1](iminodiacetato-κ3O,N,O′)copper(II) |
| title_short | Aqua[4-(hydroxyiminomethyl)pyridine-κN1](iminodiacetato-κ3O,N,O′)copper(II) |
| title_sort | aqua 4 hydroxyiminomethyl pyridine amp 954 n1 iminodiacetato amp 954 3o n o amp 8242 copper ii |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536811033459 |
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