Microstructure, Pitting Corrosion Resistance and Impact Toughness of Duplex Stainless Steel Underwater Dry Hyperbaric Flux-Cored Arc Welds

Duplex stainless steel multi-pass welds were made at 0.15 MPa, 0.45 MPa, and 0.75 MPa pressure, simulating underwater dry hyperbaric welding by the flux-cored arc welding (FCAW) method, with welds of normal pressure as a benchmark. The purpose of this work was to estimate the effect of ambient press...

Full description

Bibliographic Details
Main Authors: Yu Hu, Yong-Hua Shi, Xiao-Qin Shen, Zhong-Min Wang
Format: Article
Language:English
Published: MDPI AG 2017-12-01
Series:Materials
Subjects:
Online Access:https://www.mdpi.com/1996-1944/10/12/1443
_version_ 1811238697260023808
author Yu Hu
Yong-Hua Shi
Xiao-Qin Shen
Zhong-Min Wang
author_facet Yu Hu
Yong-Hua Shi
Xiao-Qin Shen
Zhong-Min Wang
author_sort Yu Hu
collection DOAJ
description Duplex stainless steel multi-pass welds were made at 0.15 MPa, 0.45 MPa, and 0.75 MPa pressure, simulating underwater dry hyperbaric welding by the flux-cored arc welding (FCAW) method, with welds of normal pressure as a benchmark. The purpose of this work was to estimate the effect of ambient pressure on the microstructure, pitting corrosion resistance and impact toughness of the weld metal. The microstructure measurement revealed that the ferrite content in the weld metal made at 0.45 MPa is the lowest, followed by that of 0.75 MPa and 0.15 MPa. The analysis of potentiodynamic polarization tests at 30 °C and 50 °C demonstrated that the pitting corrosion resistance depends on the phases of the lower pitting resistance equivalent numbers (PREN), secondary austenite and ferrite. The weld metal made at 0.45 MPa had the best resistance to pitting corrosion at 30 °C and 50 °C with the highest PRENs of secondary austenite and ferrite. The weld metal made at 0.15 MPa displayed the lowest pitting corrosion resistance at 30 °C with the lowest PREN of secondary austenite, while the weld metal made at 0.75 MPa was the most seriously eroded after being tested at 50 °C for the lowest PREN of ferrite, with large cluster pits seen in ferrite at 50 °C. The impact tests displayed a typical ductile-brittle transition because of the body-centered cubic (BCC) structure of the ferrite when the test temperature was lowered. All the weld metals met the required value of 34 J at −40 °C according to the ASTM A923. The highest ferrite content corresponded to the worst impact toughness, but the highest toughness value did not correspond to the greatest austenite content. With the decreasing of the test temperature, the drop value of absorbed energy was correlated to the ferrite content. Additionally, in this work, the weld metal made at 0.45 MPa had the best combined properties of pitting resistance and impact toughness.
first_indexed 2024-04-12T12:46:46Z
format Article
id doaj.art-0af14f0d88bc4761b201fabce9aea4a6
institution Directory Open Access Journal
issn 1996-1944
language English
last_indexed 2024-04-12T12:46:46Z
publishDate 2017-12-01
publisher MDPI AG
record_format Article
series Materials
spelling doaj.art-0af14f0d88bc4761b201fabce9aea4a62022-12-22T03:32:36ZengMDPI AGMaterials1996-19442017-12-011012144310.3390/ma10121443ma10121443Microstructure, Pitting Corrosion Resistance and Impact Toughness of Duplex Stainless Steel Underwater Dry Hyperbaric Flux-Cored Arc WeldsYu Hu0Yong-Hua Shi1Xiao-Qin Shen2Zhong-Min Wang3School of Mechanical and Automotive Engineering, South China University of Technology, Guangzhou 510640, ChinaSchool of Mechanical and Automotive Engineering, South China University of Technology, Guangzhou 510640, ChinaSchool of Mechanical and Automotive Engineering, South China University of Technology, Guangzhou 510640, ChinaGuangxi Key Laboratory of Information Materials, Guilin University of Electronic Technology, Guilin 541004, ChinaDuplex stainless steel multi-pass welds were made at 0.15 MPa, 0.45 MPa, and 0.75 MPa pressure, simulating underwater dry hyperbaric welding by the flux-cored arc welding (FCAW) method, with welds of normal pressure as a benchmark. The purpose of this work was to estimate the effect of ambient pressure on the microstructure, pitting corrosion resistance and impact toughness of the weld metal. The microstructure measurement revealed that the ferrite content in the weld metal made at 0.45 MPa is the lowest, followed by that of 0.75 MPa and 0.15 MPa. The analysis of potentiodynamic polarization tests at 30 °C and 50 °C demonstrated that the pitting corrosion resistance depends on the phases of the lower pitting resistance equivalent numbers (PREN), secondary austenite and ferrite. The weld metal made at 0.45 MPa had the best resistance to pitting corrosion at 30 °C and 50 °C with the highest PRENs of secondary austenite and ferrite. The weld metal made at 0.15 MPa displayed the lowest pitting corrosion resistance at 30 °C with the lowest PREN of secondary austenite, while the weld metal made at 0.75 MPa was the most seriously eroded after being tested at 50 °C for the lowest PREN of ferrite, with large cluster pits seen in ferrite at 50 °C. The impact tests displayed a typical ductile-brittle transition because of the body-centered cubic (BCC) structure of the ferrite when the test temperature was lowered. All the weld metals met the required value of 34 J at −40 °C according to the ASTM A923. The highest ferrite content corresponded to the worst impact toughness, but the highest toughness value did not correspond to the greatest austenite content. With the decreasing of the test temperature, the drop value of absorbed energy was correlated to the ferrite content. Additionally, in this work, the weld metal made at 0.45 MPa had the best combined properties of pitting resistance and impact toughness.https://www.mdpi.com/1996-1944/10/12/1443underwater FCAWpitting corrosionimpact toughnessduplex stainless steelmicrostructuresecondary phasesTEM
spellingShingle Yu Hu
Yong-Hua Shi
Xiao-Qin Shen
Zhong-Min Wang
Microstructure, Pitting Corrosion Resistance and Impact Toughness of Duplex Stainless Steel Underwater Dry Hyperbaric Flux-Cored Arc Welds
Materials
underwater FCAW
pitting corrosion
impact toughness
duplex stainless steel
microstructure
secondary phases
TEM
title Microstructure, Pitting Corrosion Resistance and Impact Toughness of Duplex Stainless Steel Underwater Dry Hyperbaric Flux-Cored Arc Welds
title_full Microstructure, Pitting Corrosion Resistance and Impact Toughness of Duplex Stainless Steel Underwater Dry Hyperbaric Flux-Cored Arc Welds
title_fullStr Microstructure, Pitting Corrosion Resistance and Impact Toughness of Duplex Stainless Steel Underwater Dry Hyperbaric Flux-Cored Arc Welds
title_full_unstemmed Microstructure, Pitting Corrosion Resistance and Impact Toughness of Duplex Stainless Steel Underwater Dry Hyperbaric Flux-Cored Arc Welds
title_short Microstructure, Pitting Corrosion Resistance and Impact Toughness of Duplex Stainless Steel Underwater Dry Hyperbaric Flux-Cored Arc Welds
title_sort microstructure pitting corrosion resistance and impact toughness of duplex stainless steel underwater dry hyperbaric flux cored arc welds
topic underwater FCAW
pitting corrosion
impact toughness
duplex stainless steel
microstructure
secondary phases
TEM
url https://www.mdpi.com/1996-1944/10/12/1443
work_keys_str_mv AT yuhu microstructurepittingcorrosionresistanceandimpacttoughnessofduplexstainlesssteelunderwaterdryhyperbaricfluxcoredarcwelds
AT yonghuashi microstructurepittingcorrosionresistanceandimpacttoughnessofduplexstainlesssteelunderwaterdryhyperbaricfluxcoredarcwelds
AT xiaoqinshen microstructurepittingcorrosionresistanceandimpacttoughnessofduplexstainlesssteelunderwaterdryhyperbaricfluxcoredarcwelds
AT zhongminwang microstructurepittingcorrosionresistanceandimpacttoughnessofduplexstainlesssteelunderwaterdryhyperbaricfluxcoredarcwelds