(1R,4R,6S,7R)-5,5-Dibromo-1,4,8,8-tetramethyltricyclo[5.4.1.04,6]dodecan-12-one
The title compound, C16H24Br2O, was synthesized from the reaction of β-himachalene (3,5,5,9-tetramethyl-2,4a,5,6,7,8-hexahydro-1H-benzocycloheptene), which was isolated from Atlas cedar (Cedrus atlantica). The asymmetric unit contains two independent molecules with similar conformations. Each molecu...
| Main Authors: | , , , |
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2014-05-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536814007351 |
| _version_ | 1819105882240188416 |
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| author | Mohamed Zaki Ahmed Benharref Jean-Claude Daran Moha Berraho |
| author_facet | Mohamed Zaki Ahmed Benharref Jean-Claude Daran Moha Berraho |
| author_sort | Mohamed Zaki |
| collection | DOAJ |
| description | The title compound, C16H24Br2O, was synthesized from the reaction of β-himachalene (3,5,5,9-tetramethyl-2,4a,5,6,7,8-hexahydro-1H-benzocycloheptene), which was isolated from Atlas cedar (Cedrus atlantica). The asymmetric unit contains two independent molecules with similar conformations. Each molecule is built up from two fused seven-membered rings and an additional three-membered ring. In both molecules, one of the seven-membered rings has a chair conformation, whereas the other displays a screw-boat conformation. |
| first_indexed | 2024-12-22T02:29:18Z |
| format | Article |
| id | doaj.art-0afe3341f9f94dbaab74906d84ca4e2b |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-22T02:29:18Z |
| publishDate | 2014-05-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-0afe3341f9f94dbaab74906d84ca4e2b2022-12-21T18:41:55ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682014-05-01705o526o52610.1107/S1600536814007351bt6972(1R,4R,6S,7R)-5,5-Dibromo-1,4,8,8-tetramethyltricyclo[5.4.1.04,6]dodecan-12-oneMohamed Zaki0Ahmed Benharref1Jean-Claude Daran2Moha Berraho3Laboratoire de Chimie des Substances Naturelles, "Unité Associé au CNRST (URAC16)", Faculté des Sciences Semlalia, BP 2390 Bd My Abdellah, 40000 Marrakech, MoroccoLaboratoire de Chimie des Substances Naturelles, "Unité Associé au CNRST (URAC16)", Faculté des Sciences Semlalia, BP 2390 Bd My Abdellah, 40000 Marrakech, MoroccoLaboratoire de Chimie de Coordination, 205 Route de Narbone, 31077 Toulouse Cedex 04, FranceLaboratoire de Chimie des Substances Naturelles, "Unité Associé au CNRST (URAC16)", Faculté des Sciences Semlalia, BP 2390 Bd My Abdellah, 40000 Marrakech, MoroccoThe title compound, C16H24Br2O, was synthesized from the reaction of β-himachalene (3,5,5,9-tetramethyl-2,4a,5,6,7,8-hexahydro-1H-benzocycloheptene), which was isolated from Atlas cedar (Cedrus atlantica). The asymmetric unit contains two independent molecules with similar conformations. Each molecule is built up from two fused seven-membered rings and an additional three-membered ring. In both molecules, one of the seven-membered rings has a chair conformation, whereas the other displays a screw-boat conformation.http://scripts.iucr.org/cgi-bin/paper?S1600536814007351 |
| spellingShingle | Mohamed Zaki Ahmed Benharref Jean-Claude Daran Moha Berraho (1R,4R,6S,7R)-5,5-Dibromo-1,4,8,8-tetramethyltricyclo[5.4.1.04,6]dodecan-12-one Acta Crystallographica Section E |
| title | (1R,4R,6S,7R)-5,5-Dibromo-1,4,8,8-tetramethyltricyclo[5.4.1.04,6]dodecan-12-one |
| title_full | (1R,4R,6S,7R)-5,5-Dibromo-1,4,8,8-tetramethyltricyclo[5.4.1.04,6]dodecan-12-one |
| title_fullStr | (1R,4R,6S,7R)-5,5-Dibromo-1,4,8,8-tetramethyltricyclo[5.4.1.04,6]dodecan-12-one |
| title_full_unstemmed | (1R,4R,6S,7R)-5,5-Dibromo-1,4,8,8-tetramethyltricyclo[5.4.1.04,6]dodecan-12-one |
| title_short | (1R,4R,6S,7R)-5,5-Dibromo-1,4,8,8-tetramethyltricyclo[5.4.1.04,6]dodecan-12-one |
| title_sort | 1r 4r 6s 7r 5 5 dibromo 1 4 8 8 tetramethyltricyclo 5 4 1 04 6 dodecan 12 one |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536814007351 |
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