The Chiral 1:2 Adduct (<i>S</i>)<sub>S</sub>(<i>S</i>)<sub>C</sub>(−)<sub>589</sub>-Ethyl 2-Phenylbutyl Sulphide-Mercury (II) Chloride:(−)<sub>589</sub>[(<i>S</i>)<sub>S</sub>(<i>S</i>)<sub>C</sub>-Et(2-PhBu)S.(HgCl<sub>2</sub>)<sub>2</sub>]. Stereoselective Synthesis, Asymmetric Oxidation, Crystal and Molecular Structure and Circular Dichroism Spectra

The Chiral 1:2 Adduct (<i>S</i>)<sub>S</sub>(<i>S</i>)<sub>C</sub>(−)<sub>589</sub>-Ethyl 2-Phenylbutyl Sulphide-Mercury (II) Chloride:(−)<sub>589</sub>[(<i>S</i>)<sub>S</sub>(<i>S</i>)<sub>C</sub>-Et(2-PhBu)S.(HgCl<sub>2</sub>)<sub>2</sub>]. Stereoselective Synthesis, Asymmetric Oxidation, Crystal and Molecular Structure and Circular Dichroism Spectra

Optically active (−)<sub>589</sub>ethyl (<i>S</i>)-2-phenylbutyl thioether, (−)(<i>S</i>)<sub>C</sub>-Et(PhBu)S (<b>I</b>), and its new diastereoisomeric mercury (II) chloride adduct, 1:2, (−)[(<i>S</i>)<sub>S</sub>(...

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Bibliographic Details
Main Authors:	Paolo Biscarini, Ivano Bilotti, Francesco Ferranti, Alessia Bacchi, Giancarlo Pelizzi, Marian Mikołajczyk, Jozef Drabowicz
Format:	Article
Language:	English
Published:	MDPI AG 2020-07-01
Series:	Molecules
Subjects:	sulphide mercury chloride complex chirality X-ray crystallography asymmetric oxidation circular dichroism absolute configuration
Online Access:	https://www.mdpi.com/1420-3049/25/15/3398

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