Phase composition and phase equilibrium diagrams as the Evidence of the Colloidal State of melts
One of the most extensively studied silicate systems with complete miscibility in the solid and liquid state – albite (Ab)-anorthite (An) system – has been analyzed in detail. It has been established that the commonly accepted system and interpretation rules for these diagrams do not match their gra...
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| Format: | Article |
| Language: | English |
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EDP Sciences
2023-01-01
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| Series: | E3S Web of Conferences |
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| Online Access: | https://www.e3s-conferences.org/articles/e3sconf/pdf/2023/26/e3sconf_uesf2023_01027.pdf |
| _version_ | 1827930085949177856 |
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| author | Pankov Vladimir |
| author_facet | Pankov Vladimir |
| author_sort | Pankov Vladimir |
| collection | DOAJ |
| description | One of the most extensively studied silicate systems with complete miscibility in the solid and liquid state – albite (Ab)-anorthite (An) system – has been analyzed in detail. It has been established that the commonly accepted system and interpretation rules for these diagrams do not match their graphic representation. Calculations have proved the colloidal state of the “solid” phase on the solidus. Actual data support the colloidal (liquid) state of the solidus phase below the solidus and eutectic point. Crystallization in multicomponent systems, at least in silicate melts, has been shown to be based on the sol coagulation mechanism. Thus, silicate solid phases, even those of fixed composition, have no particular melting point. They consolidate and melt within a temperature band. The bandwidth is subject to the system composition that predetermines the micelle structure and directly affects coagulation and peptization processes. |
| first_indexed | 2024-03-13T06:30:33Z |
| format | Article |
| id | doaj.art-0b1225a91e2b48c1b719ce1e3cb7bb25 |
| institution | Directory Open Access Journal |
| issn | 2267-1242 |
| language | English |
| last_indexed | 2024-03-13T06:30:33Z |
| publishDate | 2023-01-01 |
| publisher | EDP Sciences |
| record_format | Article |
| series | E3S Web of Conferences |
| spelling | doaj.art-0b1225a91e2b48c1b719ce1e3cb7bb252023-06-09T09:07:30ZengEDP SciencesE3S Web of Conferences2267-12422023-01-013890102710.1051/e3sconf/202338901027e3sconf_uesf2023_01027Phase composition and phase equilibrium diagrams as the Evidence of the Colloidal State of meltsPankov Vladimir0North-Eastern Federal University named after M.K. Ammosov (NEFU)One of the most extensively studied silicate systems with complete miscibility in the solid and liquid state – albite (Ab)-anorthite (An) system – has been analyzed in detail. It has been established that the commonly accepted system and interpretation rules for these diagrams do not match their graphic representation. Calculations have proved the colloidal state of the “solid” phase on the solidus. Actual data support the colloidal (liquid) state of the solidus phase below the solidus and eutectic point. Crystallization in multicomponent systems, at least in silicate melts, has been shown to be based on the sol coagulation mechanism. Thus, silicate solid phases, even those of fixed composition, have no particular melting point. They consolidate and melt within a temperature band. The bandwidth is subject to the system composition that predetermines the micelle structure and directly affects coagulation and peptization processes.https://www.e3s-conferences.org/articles/e3sconf/pdf/2023/26/e3sconf_uesf2023_01027.pdfcrystallizationmeltingsolcoagulationpeptizationcoacervation |
| spellingShingle | Pankov Vladimir Phase composition and phase equilibrium diagrams as the Evidence of the Colloidal State of melts E3S Web of Conferences crystallization melting sol coagulation peptization coacervation |
| title | Phase composition and phase equilibrium diagrams as the Evidence of the Colloidal State of melts |
| title_full | Phase composition and phase equilibrium diagrams as the Evidence of the Colloidal State of melts |
| title_fullStr | Phase composition and phase equilibrium diagrams as the Evidence of the Colloidal State of melts |
| title_full_unstemmed | Phase composition and phase equilibrium diagrams as the Evidence of the Colloidal State of melts |
| title_short | Phase composition and phase equilibrium diagrams as the Evidence of the Colloidal State of melts |
| title_sort | phase composition and phase equilibrium diagrams as the evidence of the colloidal state of melts |
| topic | crystallization melting sol coagulation peptization coacervation |
| url | https://www.e3s-conferences.org/articles/e3sconf/pdf/2023/26/e3sconf_uesf2023_01027.pdf |
| work_keys_str_mv | AT pankovvladimir phasecompositionandphaseequilibriumdiagramsastheevidenceofthecolloidalstateofmelts |