Structural, electrical and optical properties of hetrostructured MoS2/ZnO thin films for potential perovskite solar cells application

ZnO, MoS2, MoS2/ZnO/glass, and ZnO/MoS2/glass thin films have been deposited on glass substrates by chemical bath deposition techniques (CBD). XRD results confirmed the formation of MoS2, ZnO, MoS2/ZnO/glass, and ZnO/MoS2/glass films. All the films have a hexagonal structure. The grain size of heter...

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Main Authors: M.I. Khan, Sabir Ali, Norah Alwadai, Ikram-ul-Haq, Muhammad Irfan, Hind Albalawi, Aljawhara H. Almuqrin, Maha M. Almoneef, Munawar Iqbal
Format: Article
Language:English
Published: Elsevier 2022-09-01
Series:Journal of Materials Research and Technology
Subjects:
Online Access:http://www.sciencedirect.com/science/article/pii/S2238785422011218
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author M.I. Khan
Sabir Ali
Norah Alwadai
Ikram-ul-Haq
Muhammad Irfan
Hind Albalawi
Aljawhara H. Almuqrin
Maha M. Almoneef
Munawar Iqbal
author_facet M.I. Khan
Sabir Ali
Norah Alwadai
Ikram-ul-Haq
Muhammad Irfan
Hind Albalawi
Aljawhara H. Almuqrin
Maha M. Almoneef
Munawar Iqbal
author_sort M.I. Khan
collection DOAJ
description ZnO, MoS2, MoS2/ZnO/glass, and ZnO/MoS2/glass thin films have been deposited on glass substrates by chemical bath deposition techniques (CBD). XRD results confirmed the formation of MoS2, ZnO, MoS2/ZnO/glass, and ZnO/MoS2/glass films. All the films have a hexagonal structure. The grain size of heterostructured (MoS2/ZnO/glass and ZnO/MoS2/glass) films is larger than pure (ZnO and MoS2) films. The band gap energy of ZnO, MoS2, MoS2/ZnO/glass and ZnO/MoS2/glass is 3.14 eV, 1.52 eV, 1.62 eV and 2.67 eV, respectively. Photoluminescence (PL) emission peaks of ZnO are observed in the visible region. When ZnO film is deposited on MoS2 film, PL peaks are shifted to smaller wavelengths. A very high PL intensity peak of MoS2 is observed. When MoS2 film was deposited on ZnO film the peak intensity was reduced. The average sheet resistivity of glass/MoS2, glass/ZnO, MoS2/ZnO/glass and ZnO/MoS2/glass films is 6.44 × 104, 7.89 × 103, 5.65 × 104, and 2.45 × 103 (ohm-m), respectively. These materials have potential applications in perovskite solar cells.
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spelling doaj.art-0b30349e57fb46c29132d5a7a0ff802d2022-12-22T04:32:36ZengElsevierJournal of Materials Research and Technology2238-78542022-09-012016161623Structural, electrical and optical properties of hetrostructured MoS2/ZnO thin films for potential perovskite solar cells applicationM.I. Khan0Sabir Ali1Norah Alwadai2 Ikram-ul-Haq3Muhammad Irfan4Hind Albalawi5Aljawhara H. Almuqrin6Maha M. Almoneef7Munawar Iqbal8Department of Physics, The University of Lahore, Lahore 53700, PakistanDepartment of Physics, The University of Lahore, Lahore 53700, PakistanDepartment of Physics, College of Science, Princess Nourah bint Abdulrahman University (PNU), Riyadh 11671, Saudi Arabia; Corresponding author.Department of Physics, The University of Lahore, Lahore 53700, PakistanDepartment of Physics, The University of Lahore, Lahore 53700, PakistanDepartment of Physics, College of Science, Princess Nourah bint Abdulrahman University (PNU), Riyadh 11671, Saudi ArabiaDepartment of Physics, College of Science, Princess Nourah bint Abdulrahman University (PNU), Riyadh 11671, Saudi ArabiaDepartment of Physics, College of Science, Princess Nourah bint Abdulrahman University (PNU), Riyadh 11671, Saudi ArabiaDepartment of Chemistry, The University of Lahore, Lahore 53700, Pakistan; Corresponding author.ZnO, MoS2, MoS2/ZnO/glass, and ZnO/MoS2/glass thin films have been deposited on glass substrates by chemical bath deposition techniques (CBD). XRD results confirmed the formation of MoS2, ZnO, MoS2/ZnO/glass, and ZnO/MoS2/glass films. All the films have a hexagonal structure. The grain size of heterostructured (MoS2/ZnO/glass and ZnO/MoS2/glass) films is larger than pure (ZnO and MoS2) films. The band gap energy of ZnO, MoS2, MoS2/ZnO/glass and ZnO/MoS2/glass is 3.14 eV, 1.52 eV, 1.62 eV and 2.67 eV, respectively. Photoluminescence (PL) emission peaks of ZnO are observed in the visible region. When ZnO film is deposited on MoS2 film, PL peaks are shifted to smaller wavelengths. A very high PL intensity peak of MoS2 is observed. When MoS2 film was deposited on ZnO film the peak intensity was reduced. The average sheet resistivity of glass/MoS2, glass/ZnO, MoS2/ZnO/glass and ZnO/MoS2/glass films is 6.44 × 104, 7.89 × 103, 5.65 × 104, and 2.45 × 103 (ohm-m), respectively. These materials have potential applications in perovskite solar cells.http://www.sciencedirect.com/science/article/pii/S2238785422011218ZnOMoS2Thin filmsOptical propertiesElectrical propertiesSolar energy
spellingShingle M.I. Khan
Sabir Ali
Norah Alwadai
Ikram-ul-Haq
Muhammad Irfan
Hind Albalawi
Aljawhara H. Almuqrin
Maha M. Almoneef
Munawar Iqbal
Structural, electrical and optical properties of hetrostructured MoS2/ZnO thin films for potential perovskite solar cells application
Journal of Materials Research and Technology
ZnO
MoS2
Thin films
Optical properties
Electrical properties
Solar energy
title Structural, electrical and optical properties of hetrostructured MoS2/ZnO thin films for potential perovskite solar cells application
title_full Structural, electrical and optical properties of hetrostructured MoS2/ZnO thin films for potential perovskite solar cells application
title_fullStr Structural, electrical and optical properties of hetrostructured MoS2/ZnO thin films for potential perovskite solar cells application
title_full_unstemmed Structural, electrical and optical properties of hetrostructured MoS2/ZnO thin films for potential perovskite solar cells application
title_short Structural, electrical and optical properties of hetrostructured MoS2/ZnO thin films for potential perovskite solar cells application
title_sort structural electrical and optical properties of hetrostructured mos2 zno thin films for potential perovskite solar cells application
topic ZnO
MoS2
Thin films
Optical properties
Electrical properties
Solar energy
url http://www.sciencedirect.com/science/article/pii/S2238785422011218
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