Environmental-Friendly and Facile Synthesis of Co3O4 Nanowires and Their Promising Application with Graphene in Lithium-Ion Batteries
Abstract In this work, we developed an eco-friendly strategy for preparing Co3O4 nanowires. The process consisted of two steps: controllable synthesis of metal cobalt nanowires followed by a facile air-oxidization step. The 1D nanowire structure with a high aspect ratio was easily achieved via a mag...
| Main Authors: | , , , , , |
|---|---|
| Format: | Article |
| Language: | English |
| Published: |
SpringerOpen
2017-12-01
|
| Series: | Nanoscale Research Letters |
| Subjects: | |
| Online Access: | http://link.springer.com/article/10.1186/s11671-017-2382-4 |
| Summary: | Abstract In this work, we developed an eco-friendly strategy for preparing Co3O4 nanowires. The process consisted of two steps: controllable synthesis of metal cobalt nanowires followed by a facile air-oxidization step. The 1D nanowire structure with a high aspect ratio was easily achieved via a magnetic-field-assisted self-assembly of cobalt ion complexes during reduction. After air-calcinations, the Co3O4 nanowires were prepared in large scale and ready to be used as the anode material for lithium-ion batteries. The Co3O4 nanowires, which possessed a length ranging from 3 to 8 μm with the aspect ratio more than 15, exhibited a reversible lithium storage capacity up to ~ 790 mAh/g when using a small amount of defect-free graphene flakes as conductive additives. The superior electrochemical performances were ascribable to the synergistic “flat-on” effect between the 1D nanowires and the 2D graphene. Therefore, the Co3O4 nanowire/graphene composite holds promising application for lithium-ion batteries. |
|---|---|
| ISSN: | 1931-7573 1556-276X |