Structure and Properties of High-Entropy Nitride Coatings

The interest in nitride coatings based on high-entropy alloys (HEAs) has increased rapidly in the last decade. According to a number of papers, such high-entropy nitride (HEN) coatings have a single-phase structure and properties that significantly exceed those of simpler nitride systems. These prop...

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Main Authors: Vseslav Novikov, Nikita Stepanov, Sergey Zherebtsov, Gennady Salishchev
Format: Article
Language:English
Published: MDPI AG 2022-05-01
Series:Metals
Subjects:
Online Access:https://www.mdpi.com/2075-4701/12/5/847
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author Vseslav Novikov
Nikita Stepanov
Sergey Zherebtsov
Gennady Salishchev
author_facet Vseslav Novikov
Nikita Stepanov
Sergey Zherebtsov
Gennady Salishchev
author_sort Vseslav Novikov
collection DOAJ
description The interest in nitride coatings based on high-entropy alloys (HEAs) has increased rapidly in the last decade. According to a number of papers, such high-entropy nitride (HEN) coatings have a single-phase structure and properties that significantly exceed those of simpler nitride systems. These properties include high hardness, wear resistance, oxidation resistance and thermal stability. It is believed that these distinctive properties are due to the high entropy of mixing, which increases with an increase in the number of elements in the composition. However, comparison with various binary and ternary systems shows that better properties are not typical of each HEA-based coating, and the effect of the number of elements competes with other factors that can make even more pronounced contributions to the structure and properties of the coating. Because of fragmentation of data on the structure and properties of high-entropy coatings, a unified concept of alloying is needed. This review compares the methods for obtaining HEN coatings, describes their structural features and analyzes the main properties, such as hardness, wear resistance and oxidation resistance, in order to establish an understanding of the influence of the number of elements and their role in the composition of coatings.
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spelling doaj.art-0b5ced7e63044fc8848548c18aafe5132023-11-23T12:10:17ZengMDPI AGMetals2075-47012022-05-0112584710.3390/met12050847Structure and Properties of High-Entropy Nitride CoatingsVseslav Novikov0Nikita Stepanov1Sergey Zherebtsov2Gennady Salishchev3Joint Research Center “Technology and Materials”, Belgorod State University, 308015 Belgorod, RussiaLaboratory of Bulk Nanostructured Materials, Belgorod State University, 308015 Belgorod, RussiaLaboratory of Bulk Nanostructured Materials, Belgorod State University, 308015 Belgorod, RussiaLaboratory of Bulk Nanostructured Materials, Belgorod State University, 308015 Belgorod, RussiaThe interest in nitride coatings based on high-entropy alloys (HEAs) has increased rapidly in the last decade. According to a number of papers, such high-entropy nitride (HEN) coatings have a single-phase structure and properties that significantly exceed those of simpler nitride systems. These properties include high hardness, wear resistance, oxidation resistance and thermal stability. It is believed that these distinctive properties are due to the high entropy of mixing, which increases with an increase in the number of elements in the composition. However, comparison with various binary and ternary systems shows that better properties are not typical of each HEA-based coating, and the effect of the number of elements competes with other factors that can make even more pronounced contributions to the structure and properties of the coating. Because of fragmentation of data on the structure and properties of high-entropy coatings, a unified concept of alloying is needed. This review compares the methods for obtaining HEN coatings, describes their structural features and analyzes the main properties, such as hardness, wear resistance and oxidation resistance, in order to establish an understanding of the influence of the number of elements and their role in the composition of coatings.https://www.mdpi.com/2075-4701/12/5/847high-entropy alloyscoatingsthin filmsnitridesPVDstructure
spellingShingle Vseslav Novikov
Nikita Stepanov
Sergey Zherebtsov
Gennady Salishchev
Structure and Properties of High-Entropy Nitride Coatings
Metals
high-entropy alloys
coatings
thin films
nitrides
PVD
structure
title Structure and Properties of High-Entropy Nitride Coatings
title_full Structure and Properties of High-Entropy Nitride Coatings
title_fullStr Structure and Properties of High-Entropy Nitride Coatings
title_full_unstemmed Structure and Properties of High-Entropy Nitride Coatings
title_short Structure and Properties of High-Entropy Nitride Coatings
title_sort structure and properties of high entropy nitride coatings
topic high-entropy alloys
coatings
thin films
nitrides
PVD
structure
url https://www.mdpi.com/2075-4701/12/5/847
work_keys_str_mv AT vseslavnovikov structureandpropertiesofhighentropynitridecoatings
AT nikitastepanov structureandpropertiesofhighentropynitridecoatings
AT sergeyzherebtsov structureandpropertiesofhighentropynitridecoatings
AT gennadysalishchev structureandpropertiesofhighentropynitridecoatings