Structure and Properties of High-Entropy Nitride Coatings
The interest in nitride coatings based on high-entropy alloys (HEAs) has increased rapidly in the last decade. According to a number of papers, such high-entropy nitride (HEN) coatings have a single-phase structure and properties that significantly exceed those of simpler nitride systems. These prop...
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MDPI AG
2022-05-01
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author | Vseslav Novikov Nikita Stepanov Sergey Zherebtsov Gennady Salishchev |
author_facet | Vseslav Novikov Nikita Stepanov Sergey Zherebtsov Gennady Salishchev |
author_sort | Vseslav Novikov |
collection | DOAJ |
description | The interest in nitride coatings based on high-entropy alloys (HEAs) has increased rapidly in the last decade. According to a number of papers, such high-entropy nitride (HEN) coatings have a single-phase structure and properties that significantly exceed those of simpler nitride systems. These properties include high hardness, wear resistance, oxidation resistance and thermal stability. It is believed that these distinctive properties are due to the high entropy of mixing, which increases with an increase in the number of elements in the composition. However, comparison with various binary and ternary systems shows that better properties are not typical of each HEA-based coating, and the effect of the number of elements competes with other factors that can make even more pronounced contributions to the structure and properties of the coating. Because of fragmentation of data on the structure and properties of high-entropy coatings, a unified concept of alloying is needed. This review compares the methods for obtaining HEN coatings, describes their structural features and analyzes the main properties, such as hardness, wear resistance and oxidation resistance, in order to establish an understanding of the influence of the number of elements and their role in the composition of coatings. |
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language | English |
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publisher | MDPI AG |
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spelling | doaj.art-0b5ced7e63044fc8848548c18aafe5132023-11-23T12:10:17ZengMDPI AGMetals2075-47012022-05-0112584710.3390/met12050847Structure and Properties of High-Entropy Nitride CoatingsVseslav Novikov0Nikita Stepanov1Sergey Zherebtsov2Gennady Salishchev3Joint Research Center “Technology and Materials”, Belgorod State University, 308015 Belgorod, RussiaLaboratory of Bulk Nanostructured Materials, Belgorod State University, 308015 Belgorod, RussiaLaboratory of Bulk Nanostructured Materials, Belgorod State University, 308015 Belgorod, RussiaLaboratory of Bulk Nanostructured Materials, Belgorod State University, 308015 Belgorod, RussiaThe interest in nitride coatings based on high-entropy alloys (HEAs) has increased rapidly in the last decade. According to a number of papers, such high-entropy nitride (HEN) coatings have a single-phase structure and properties that significantly exceed those of simpler nitride systems. These properties include high hardness, wear resistance, oxidation resistance and thermal stability. It is believed that these distinctive properties are due to the high entropy of mixing, which increases with an increase in the number of elements in the composition. However, comparison with various binary and ternary systems shows that better properties are not typical of each HEA-based coating, and the effect of the number of elements competes with other factors that can make even more pronounced contributions to the structure and properties of the coating. Because of fragmentation of data on the structure and properties of high-entropy coatings, a unified concept of alloying is needed. This review compares the methods for obtaining HEN coatings, describes their structural features and analyzes the main properties, such as hardness, wear resistance and oxidation resistance, in order to establish an understanding of the influence of the number of elements and their role in the composition of coatings.https://www.mdpi.com/2075-4701/12/5/847high-entropy alloyscoatingsthin filmsnitridesPVDstructure |
spellingShingle | Vseslav Novikov Nikita Stepanov Sergey Zherebtsov Gennady Salishchev Structure and Properties of High-Entropy Nitride Coatings Metals high-entropy alloys coatings thin films nitrides PVD structure |
title | Structure and Properties of High-Entropy Nitride Coatings |
title_full | Structure and Properties of High-Entropy Nitride Coatings |
title_fullStr | Structure and Properties of High-Entropy Nitride Coatings |
title_full_unstemmed | Structure and Properties of High-Entropy Nitride Coatings |
title_short | Structure and Properties of High-Entropy Nitride Coatings |
title_sort | structure and properties of high entropy nitride coatings |
topic | high-entropy alloys coatings thin films nitrides PVD structure |
url | https://www.mdpi.com/2075-4701/12/5/847 |
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