Study of the Sorption Properties of Natural Zeolite in Relation to Indium(III) and Gallium(III) Cations on the Model Systems

This paper presents the systematic studies of the sorption capacity of natural zeolite with respect to In<sup>3+</sup> and Ga<sup>3+</sup> cations in the model systems “natural zeolite–In<sup>3+</sup>–H<sub>2</sub>O” and “natural zeolite–In<sup>3...

Full description

Bibliographic Details
Main Authors: Gita Sultanbayeva, Aktolkyn Agatayeva, Raushan Kaiynbayeva, Nazym Kozhabekova, Raisa Chernyakova, Umirzak Jussipbekov
Format: Article
Language:English
Published: MDPI AG 2022-08-01
Series:Crystals
Subjects:
Online Access:https://www.mdpi.com/2073-4352/12/9/1220
_version_ 1797489638953189376
author Gita Sultanbayeva
Aktolkyn Agatayeva
Raushan Kaiynbayeva
Nazym Kozhabekova
Raisa Chernyakova
Umirzak Jussipbekov
author_facet Gita Sultanbayeva
Aktolkyn Agatayeva
Raushan Kaiynbayeva
Nazym Kozhabekova
Raisa Chernyakova
Umirzak Jussipbekov
author_sort Gita Sultanbayeva
collection DOAJ
description This paper presents the systematic studies of the sorption capacity of natural zeolite with respect to In<sup>3+</sup> and Ga<sup>3+</sup> cations in the model systems “natural zeolite–In<sup>3+</sup>–H<sub>2</sub>O” and “natural zeolite–In<sup>3+</sup>–Ga<sup>3+</sup>–H<sub>2</sub>O”, while varying a number of the main process factors. The patterns of sorption of In<sup>3+</sup> and Ga<sup>3+</sup> cations by the natural zeolite of the Shankanai deposit are revealed, depending on the zeolite vs. solution ratio, temperature, and time. It is shown that the sorption of In<sup>3+</sup> cations by natural zeolite can be controlled by the process duration. The longer the process, the less the sorption by natural zeolite. It has been found that the sorption of In<sup>3+</sup> cations in the “natural zeolite–In<sup>3+</sup>–Ga<sup>3+</sup>–H<sub>2</sub>O” model system depends on the amount of zeolite and temperature, and the sorption of Ga<sup>3+</sup> cations depends on the temperature and time. The physicochemical characteristics of the spent sorbents confirm the sorption of the cations, present in the systems under study.
first_indexed 2024-03-10T00:20:28Z
format Article
id doaj.art-0bb10a472c0a4009a0c4030f55aca44d
institution Directory Open Access Journal
issn 2073-4352
language English
last_indexed 2024-03-10T00:20:28Z
publishDate 2022-08-01
publisher MDPI AG
record_format Article
series Crystals
spelling doaj.art-0bb10a472c0a4009a0c4030f55aca44d2023-11-23T15:43:25ZengMDPI AGCrystals2073-43522022-08-01129122010.3390/cryst12091220Study of the Sorption Properties of Natural Zeolite in Relation to Indium(III) and Gallium(III) Cations on the Model SystemsGita Sultanbayeva0Aktolkyn Agatayeva1Raushan Kaiynbayeva2Nazym Kozhabekova3Raisa Chernyakova4Umirzak Jussipbekov5A.B. Bekturov Institute of Chemical Sciences JSC, 106 Sh. Ualikhanovstr., Almaty 050010, KazakhstanA.B. Bekturov Institute of Chemical Sciences JSC, 106 Sh. Ualikhanovstr., Almaty 050010, KazakhstanA.B. Bekturov Institute of Chemical Sciences JSC, 106 Sh. Ualikhanovstr., Almaty 050010, KazakhstanA.B. Bekturov Institute of Chemical Sciences JSC, 106 Sh. Ualikhanovstr., Almaty 050010, KazakhstanA.B. Bekturov Institute of Chemical Sciences JSC, 106 Sh. Ualikhanovstr., Almaty 050010, KazakhstanA.B. Bekturov Institute of Chemical Sciences JSC, 106 Sh. Ualikhanovstr., Almaty 050010, KazakhstanThis paper presents the systematic studies of the sorption capacity of natural zeolite with respect to In<sup>3+</sup> and Ga<sup>3+</sup> cations in the model systems “natural zeolite–In<sup>3+</sup>–H<sub>2</sub>O” and “natural zeolite–In<sup>3+</sup>–Ga<sup>3+</sup>–H<sub>2</sub>O”, while varying a number of the main process factors. The patterns of sorption of In<sup>3+</sup> and Ga<sup>3+</sup> cations by the natural zeolite of the Shankanai deposit are revealed, depending on the zeolite vs. solution ratio, temperature, and time. It is shown that the sorption of In<sup>3+</sup> cations by natural zeolite can be controlled by the process duration. The longer the process, the less the sorption by natural zeolite. It has been found that the sorption of In<sup>3+</sup> cations in the “natural zeolite–In<sup>3+</sup>–Ga<sup>3+</sup>–H<sub>2</sub>O” model system depends on the amount of zeolite and temperature, and the sorption of Ga<sup>3+</sup> cations depends on the temperature and time. The physicochemical characteristics of the spent sorbents confirm the sorption of the cations, present in the systems under study.https://www.mdpi.com/2073-4352/12/9/1220sorptionnatural zeoliteindium cationsgallium cationsdegree of sorptionsorption capacity
spellingShingle Gita Sultanbayeva
Aktolkyn Agatayeva
Raushan Kaiynbayeva
Nazym Kozhabekova
Raisa Chernyakova
Umirzak Jussipbekov
Study of the Sorption Properties of Natural Zeolite in Relation to Indium(III) and Gallium(III) Cations on the Model Systems
Crystals
sorption
natural zeolite
indium cations
gallium cations
degree of sorption
sorption capacity
title Study of the Sorption Properties of Natural Zeolite in Relation to Indium(III) and Gallium(III) Cations on the Model Systems
title_full Study of the Sorption Properties of Natural Zeolite in Relation to Indium(III) and Gallium(III) Cations on the Model Systems
title_fullStr Study of the Sorption Properties of Natural Zeolite in Relation to Indium(III) and Gallium(III) Cations on the Model Systems
title_full_unstemmed Study of the Sorption Properties of Natural Zeolite in Relation to Indium(III) and Gallium(III) Cations on the Model Systems
title_short Study of the Sorption Properties of Natural Zeolite in Relation to Indium(III) and Gallium(III) Cations on the Model Systems
title_sort study of the sorption properties of natural zeolite in relation to indium iii and gallium iii cations on the model systems
topic sorption
natural zeolite
indium cations
gallium cations
degree of sorption
sorption capacity
url https://www.mdpi.com/2073-4352/12/9/1220
work_keys_str_mv AT gitasultanbayeva studyofthesorptionpropertiesofnaturalzeoliteinrelationtoindiumiiiandgalliumiiicationsonthemodelsystems
AT aktolkynagatayeva studyofthesorptionpropertiesofnaturalzeoliteinrelationtoindiumiiiandgalliumiiicationsonthemodelsystems
AT raushankaiynbayeva studyofthesorptionpropertiesofnaturalzeoliteinrelationtoindiumiiiandgalliumiiicationsonthemodelsystems
AT nazymkozhabekova studyofthesorptionpropertiesofnaturalzeoliteinrelationtoindiumiiiandgalliumiiicationsonthemodelsystems
AT raisachernyakova studyofthesorptionpropertiesofnaturalzeoliteinrelationtoindiumiiiandgalliumiiicationsonthemodelsystems
AT umirzakjussipbekov studyofthesorptionpropertiesofnaturalzeoliteinrelationtoindiumiiiandgalliumiiicationsonthemodelsystems