Recent Advances in Ball-Milling-Based Silicon Anodes for Lithium-Ion Batteries
Having a high theoretical capacity density of 4200 mAh g<sup>−1</sup>, silicon has been highlighted as one of the most promising anode materials for lithium-ion batteries. Countless silicon-based materials have been proposed and reported in research articles, mostly synthesized using bot...
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MDPI AG
2023-03-01
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Online Access: | https://www.mdpi.com/1996-1073/16/7/3099 |
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author | Han Yang Shiyu Lin Alex Cheng Fangbo He Zhoulu Wang Yutong Wu Yi Zhang Xiang Liu |
author_facet | Han Yang Shiyu Lin Alex Cheng Fangbo He Zhoulu Wang Yutong Wu Yi Zhang Xiang Liu |
author_sort | Han Yang |
collection | DOAJ |
description | Having a high theoretical capacity density of 4200 mAh g<sup>−1</sup>, silicon has been highlighted as one of the most promising anode materials for lithium-ion batteries. Countless silicon-based materials have been proposed and reported in research articles, mostly synthesized using bottom-up methods. While the infamous volume expansion issue can be settled with the bottom-up processes, the complicated protocols and high cost leave a non-neglectable gap between laboratory-scale and mass production. The top-down ball-milling method is still favored by industrial suppliers because of its simplicity and cost-effectiveness, even with compromised electrochemical performances. This paper reviews the latest development of ball-milling-based silicon anode materials. Although the ball-milling process seems straightforward, the procedures and parameters influencing the product have hardly been discussed in research papers compared to the bottom-up ones. This paper reviews recent advances in ball-milling-based silicon anode materials, provides a material comparison, and discusses how ball milling can provide lithium-ion batteries with greater possibilities at a larger scale. |
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issn | 1996-1073 |
language | English |
last_indexed | 2024-03-11T05:38:24Z |
publishDate | 2023-03-01 |
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series | Energies |
spelling | doaj.art-0bb91f248cd74a5496ac81fae60ef8272023-11-17T16:37:25ZengMDPI AGEnergies1996-10732023-03-01167309910.3390/en16073099Recent Advances in Ball-Milling-Based Silicon Anodes for Lithium-Ion BatteriesHan Yang0Shiyu Lin1Alex Cheng2Fangbo He3Zhoulu Wang4Yutong Wu5Yi Zhang6Xiang Liu7School of Energy Sciences and Engineering, Nanjing Tech University, Nanjing 211816, ChinaSchool of Energy Sciences and Engineering, Nanjing Tech University, Nanjing 211816, ChinaShanghai Energy New Materials Technology Co., Ltd., Shanghai 201399, ChinaZhuhai Energy New Materials Technology Co., Ltd., Zhuhai 519600, ChinaSchool of Energy Sciences and Engineering, Nanjing Tech University, Nanjing 211816, ChinaSchool of Energy Sciences and Engineering, Nanjing Tech University, Nanjing 211816, ChinaSchool of Energy Sciences and Engineering, Nanjing Tech University, Nanjing 211816, ChinaSchool of Energy Sciences and Engineering, Nanjing Tech University, Nanjing 211816, ChinaHaving a high theoretical capacity density of 4200 mAh g<sup>−1</sup>, silicon has been highlighted as one of the most promising anode materials for lithium-ion batteries. Countless silicon-based materials have been proposed and reported in research articles, mostly synthesized using bottom-up methods. While the infamous volume expansion issue can be settled with the bottom-up processes, the complicated protocols and high cost leave a non-neglectable gap between laboratory-scale and mass production. The top-down ball-milling method is still favored by industrial suppliers because of its simplicity and cost-effectiveness, even with compromised electrochemical performances. This paper reviews the latest development of ball-milling-based silicon anode materials. Although the ball-milling process seems straightforward, the procedures and parameters influencing the product have hardly been discussed in research papers compared to the bottom-up ones. This paper reviews recent advances in ball-milling-based silicon anode materials, provides a material comparison, and discusses how ball milling can provide lithium-ion batteries with greater possibilities at a larger scale.https://www.mdpi.com/1996-1073/16/7/3099ball millSi anodelithium-ion batteryelectric vehicleelectrochemistry |
spellingShingle | Han Yang Shiyu Lin Alex Cheng Fangbo He Zhoulu Wang Yutong Wu Yi Zhang Xiang Liu Recent Advances in Ball-Milling-Based Silicon Anodes for Lithium-Ion Batteries Energies ball mill Si anode lithium-ion battery electric vehicle electrochemistry |
title | Recent Advances in Ball-Milling-Based Silicon Anodes for Lithium-Ion Batteries |
title_full | Recent Advances in Ball-Milling-Based Silicon Anodes for Lithium-Ion Batteries |
title_fullStr | Recent Advances in Ball-Milling-Based Silicon Anodes for Lithium-Ion Batteries |
title_full_unstemmed | Recent Advances in Ball-Milling-Based Silicon Anodes for Lithium-Ion Batteries |
title_short | Recent Advances in Ball-Milling-Based Silicon Anodes for Lithium-Ion Batteries |
title_sort | recent advances in ball milling based silicon anodes for lithium ion batteries |
topic | ball mill Si anode lithium-ion battery electric vehicle electrochemistry |
url | https://www.mdpi.com/1996-1073/16/7/3099 |
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