(Acetato-κO){2-[(2-aminoethyl-κN)disulfanyl]ethanaminium}dichloridozinc(II)
In the title compound, [Zn(C4H13N2S2)(CH3COO)Cl2], the ZnII ion is in a tetrahedral coordination geometry, coordinated by one acetate, two chloride and one 2-[(2-aminoethyl)disulfanyl]ethanaminium ligand, with a Zn—O distance of 1.977 (3) Å, a Zn—N distance of 2.015 (3) Å and Zn—Cl distances of 2.26...
| Main Authors: | , , |
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| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2016-01-01
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| Series: | IUCrData |
| Subjects: | |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S241431461600105X |
| _version_ | 1819095172862967808 |
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| author | Naoto Kuwamura Payel Laskar Takumi Konno |
| author_facet | Naoto Kuwamura Payel Laskar Takumi Konno |
| author_sort | Naoto Kuwamura |
| collection | DOAJ |
| description | In the title compound, [Zn(C4H13N2S2)(CH3COO)Cl2], the ZnII ion is in a tetrahedral coordination geometry, coordinated by one acetate, two chloride and one 2-[(2-aminoethyl)disulfanyl]ethanaminium ligand, with a Zn—O distance of 1.977 (3) Å, a Zn—N distance of 2.015 (3) Å and Zn—Cl distances of 2.2673 (18) and 2.2688 (15) Å. In the crystal, molecules are self-assembled by N—H...Cl hydrogen bonds, leading to a one-dimensional chain structure. The chains interact with each other through N—H...O, N—H...S, C—H...Cl and C—H...S hydrogen bonding, completing a three-dimensional hydrogen-bonding network structure. |
| first_indexed | 2024-12-21T23:39:05Z |
| format | Article |
| id | doaj.art-0bd3543b784140289ee814ef9ce45b84 |
| institution | Directory Open Access Journal |
| issn | 2414-3146 |
| language | English |
| last_indexed | 2024-12-21T23:39:05Z |
| publishDate | 2016-01-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | IUCrData |
| spelling | doaj.art-0bd3543b784140289ee814ef9ce45b842022-12-21T18:46:16ZengInternational Union of CrystallographyIUCrData2414-31462016-01-0111x16010510.1107/S241431461600105Xgw2155(Acetato-κO){2-[(2-aminoethyl-κN)disulfanyl]ethanaminium}dichloridozinc(II)Naoto Kuwamura0Payel Laskar1Takumi Konno2Department of Chemistry, Graduate School of Science, Osaka University, Toyonaka, Osaka 560-0043, JapanDepartment of Chemistry, Graduate School of Science, Osaka University, Toyonaka, Osaka 560-0043, JapanDepartment of Chemistry, Graduate School of Science, Osaka University, Toyonaka, Osaka 560-0043, JapanIn the title compound, [Zn(C4H13N2S2)(CH3COO)Cl2], the ZnII ion is in a tetrahedral coordination geometry, coordinated by one acetate, two chloride and one 2-[(2-aminoethyl)disulfanyl]ethanaminium ligand, with a Zn—O distance of 1.977 (3) Å, a Zn—N distance of 2.015 (3) Å and Zn—Cl distances of 2.2673 (18) and 2.2688 (15) Å. In the crystal, molecules are self-assembled by N—H...Cl hydrogen bonds, leading to a one-dimensional chain structure. The chains interact with each other through N—H...O, N—H...S, C—H...Cl and C—H...S hydrogen bonding, completing a three-dimensional hydrogen-bonding network structure.http://scripts.iucr.org/cgi-bin/paper?S241431461600105Xcrystal structurezinc(II) complex2,2′-dithiobis(ethylamine) |
| spellingShingle | Naoto Kuwamura Payel Laskar Takumi Konno (Acetato-κO){2-[(2-aminoethyl-κN)disulfanyl]ethanaminium}dichloridozinc(II) IUCrData crystal structure zinc(II) complex 2,2′-dithiobis(ethylamine) |
| title | (Acetato-κO){2-[(2-aminoethyl-κN)disulfanyl]ethanaminium}dichloridozinc(II) |
| title_full | (Acetato-κO){2-[(2-aminoethyl-κN)disulfanyl]ethanaminium}dichloridozinc(II) |
| title_fullStr | (Acetato-κO){2-[(2-aminoethyl-κN)disulfanyl]ethanaminium}dichloridozinc(II) |
| title_full_unstemmed | (Acetato-κO){2-[(2-aminoethyl-κN)disulfanyl]ethanaminium}dichloridozinc(II) |
| title_short | (Acetato-κO){2-[(2-aminoethyl-κN)disulfanyl]ethanaminium}dichloridozinc(II) |
| title_sort | acetato κo 2 2 aminoethyl κn disulfanyl ethanaminium dichloridozinc ii |
| topic | crystal structure zinc(II) complex 2,2′-dithiobis(ethylamine) |
| url | http://scripts.iucr.org/cgi-bin/paper?S241431461600105X |
| work_keys_str_mv | AT naotokuwamura acetatoko22aminoethylkndisulfanylethanaminiumdichloridozincii AT payellaskar acetatoko22aminoethylkndisulfanylethanaminiumdichloridozincii AT takumikonno acetatoko22aminoethylkndisulfanylethanaminiumdichloridozincii |