Synthesis and characterization of the cyanobenzene-ethylenedithio-TTF donor
A dissymmetric TTF-type electron donor, cyanobenzene-ethylenedithio-tetrathiafulvalene (CNB-EDT-TTF), was obtained in high yield, by a cross-coupling reaction with triethyl phosphite between 2-thioxobenzo[d][1,3]dithiole-5-carbonitrile and 5,6-dihydro-[1,3]dithiolo[4,5-b][1,4]dithiin-2-one. This new...
| Main Authors: | , , , , |
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| Format: | Article |
| Language: | English |
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Beilstein-Institut
2015-06-01
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| Series: | Beilstein Journal of Organic Chemistry |
| Subjects: | |
| Online Access: | https://doi.org/10.3762/bjoc.11.106 |
| _version_ | 1818343820978290688 |
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| author | Sandrina Oliveira Dulce Belo Isabel C. Santos Sandra Rabaça Manuel Almeida |
| author_facet | Sandrina Oliveira Dulce Belo Isabel C. Santos Sandra Rabaça Manuel Almeida |
| author_sort | Sandrina Oliveira |
| collection | DOAJ |
| description | A dissymmetric TTF-type electron donor, cyanobenzene-ethylenedithio-tetrathiafulvalene (CNB-EDT-TTF), was obtained in high yield, by a cross-coupling reaction with triethyl phosphite between 2-thioxobenzo[d][1,3]dithiole-5-carbonitrile and 5,6-dihydro-[1,3]dithiolo[4,5-b][1,4]dithiin-2-one. This new donor was characterized namely by single crystal X-ray diffraction, cyclic voltammetry, NMR, UV-visible and IR spectroscopy. |
| first_indexed | 2024-12-13T16:36:40Z |
| format | Article |
| id | doaj.art-0c14ae5a9db14515a9295b757ef8fb6c |
| institution | Directory Open Access Journal |
| issn | 1860-5397 |
| language | English |
| last_indexed | 2024-12-13T16:36:40Z |
| publishDate | 2015-06-01 |
| publisher | Beilstein-Institut |
| record_format | Article |
| series | Beilstein Journal of Organic Chemistry |
| spelling | doaj.art-0c14ae5a9db14515a9295b757ef8fb6c2022-12-21T23:38:22ZengBeilstein-InstitutBeilstein Journal of Organic Chemistry1860-53972015-06-0111195195610.3762/bjoc.11.1061860-5397-11-106Synthesis and characterization of the cyanobenzene-ethylenedithio-TTF donorSandrina Oliveira0Dulce Belo1Isabel C. Santos2Sandra Rabaça3Manuel Almeida4C²TN, Instituto Superior Técnico, Universidade de Lisboa, Estrada Nacional 10, P-2695-066 Bobadela LRS, PortugalC²TN, Instituto Superior Técnico, Universidade de Lisboa, Estrada Nacional 10, P-2695-066 Bobadela LRS, PortugalC²TN, Instituto Superior Técnico, Universidade de Lisboa, Estrada Nacional 10, P-2695-066 Bobadela LRS, PortugalC²TN, Instituto Superior Técnico, Universidade de Lisboa, Estrada Nacional 10, P-2695-066 Bobadela LRS, PortugalC²TN, Instituto Superior Técnico, Universidade de Lisboa, Estrada Nacional 10, P-2695-066 Bobadela LRS, PortugalA dissymmetric TTF-type electron donor, cyanobenzene-ethylenedithio-tetrathiafulvalene (CNB-EDT-TTF), was obtained in high yield, by a cross-coupling reaction with triethyl phosphite between 2-thioxobenzo[d][1,3]dithiole-5-carbonitrile and 5,6-dihydro-[1,3]dithiolo[4,5-b][1,4]dithiin-2-one. This new donor was characterized namely by single crystal X-ray diffraction, cyclic voltammetry, NMR, UV-visible and IR spectroscopy.https://doi.org/10.3762/bjoc.11.106cross-couplingcyanobenzenecyclic voltammetrydissymmetric tetrathiafulvaleneelectro-active donors |
| spellingShingle | Sandrina Oliveira Dulce Belo Isabel C. Santos Sandra Rabaça Manuel Almeida Synthesis and characterization of the cyanobenzene-ethylenedithio-TTF donor Beilstein Journal of Organic Chemistry cross-coupling cyanobenzene cyclic voltammetry dissymmetric tetrathiafulvalene electro-active donors |
| title | Synthesis and characterization of the cyanobenzene-ethylenedithio-TTF donor |
| title_full | Synthesis and characterization of the cyanobenzene-ethylenedithio-TTF donor |
| title_fullStr | Synthesis and characterization of the cyanobenzene-ethylenedithio-TTF donor |
| title_full_unstemmed | Synthesis and characterization of the cyanobenzene-ethylenedithio-TTF donor |
| title_short | Synthesis and characterization of the cyanobenzene-ethylenedithio-TTF donor |
| title_sort | synthesis and characterization of the cyanobenzene ethylenedithio ttf donor |
| topic | cross-coupling cyanobenzene cyclic voltammetry dissymmetric tetrathiafulvalene electro-active donors |
| url | https://doi.org/10.3762/bjoc.11.106 |
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