Pillarization of Sumatera Bentonite by Sodium-assisted As Effective Adsorbent of Anionic Surfactants Sodium Lauryl Sulphate (SLS) Waste
In this work, the Sumatera bentonite was sodium-pillarized in a new low-temperature and restricted time preparation route and then applied in anionic surfactant sodium lauryl sulphate removal. Structure characterization used Fourier Transform Infra Red (FT-IR), Scanning Electron Microscope - Energy...
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| Format: | Article |
| Language: | English |
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Masyarakat Katalis Indonesia - Indonesian Catalyst Society (MKICS)
2023-03-01
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| Series: | Bulletin of Chemical Reaction Engineering & Catalysis |
| Subjects: | |
| Online Access: | https://journal.bcrec.id/index.php/bcrec/article/view/16500 |
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| author | Risfidian Mohadi Yusuf Mathiinul Hakim Rahma Dinta Astuti Idha Royani Mardiyanto Mardiyanto |
| author_facet | Risfidian Mohadi Yusuf Mathiinul Hakim Rahma Dinta Astuti Idha Royani Mardiyanto Mardiyanto |
| author_sort | Risfidian Mohadi |
| collection | DOAJ |
| description | In this work, the Sumatera bentonite was sodium-pillarized in a new low-temperature and restricted time preparation route and then applied in anionic surfactant sodium lauryl sulphate removal. Structure characterization used Fourier Transform Infra Red (FT-IR), Scanning Electron Microscope - Energy Dispersive X-ray (SEM-EDX), X-ray Diffraction (XRD), and Brunauer–Emmett–Teller (BET) analysis. A strong peak at 22° and 35.66° in XRD analysis was detected as Sodium-pillar that increased crystallinity, then the functional changes of dehydration in lattice structure were detected in 1013 cm−1 by FTIR analysis. The morphology and compositional transformation were analyzed by SEM-EDX and BET analysis, denoted by increasing particle shape and sodium intercalant composition homogeneity. Moreover, the surface area increased from 61.791 to 66.086 m2/g. The sodium lauryl sulphate adsorption by bentonite-Na reached maximum capacity at 8.403 mg/g, which is higher than the pristine bentonite (5.747 mg/g) under the optimum condition. The adsorption mechanism is feasible, endothermic, and conformed to the pseudo-second-order and Freundlich adsorption model. The new route proposed for sodium intercalation effectively improves the Sumatera bentonite adsorption ability to remove sodium lauryl sulphate waste. Copyright © 2023 by Authors, Published by BCREC Group. This is an open access article under the CC BY-SA License (https://creativecommons.org/licenses/by-sa/4.0). |
| first_indexed | 2024-03-11T22:51:20Z |
| format | Article |
| id | doaj.art-0c2af9cd9a3a467ba24cc8375de8f9d4 |
| institution | Directory Open Access Journal |
| issn | 1978-2993 |
| language | English |
| last_indexed | 2024-03-11T22:51:20Z |
| publishDate | 2023-03-01 |
| publisher | Masyarakat Katalis Indonesia - Indonesian Catalyst Society (MKICS) |
| record_format | Article |
| series | Bulletin of Chemical Reaction Engineering & Catalysis |
| spelling | doaj.art-0c2af9cd9a3a467ba24cc8375de8f9d42023-09-22T03:21:15ZengMasyarakat Katalis Indonesia - Indonesian Catalyst Society (MKICS)Bulletin of Chemical Reaction Engineering & Catalysis1978-29932023-03-01181485810.9767/bcrec.165007454Pillarization of Sumatera Bentonite by Sodium-assisted As Effective Adsorbent of Anionic Surfactants Sodium Lauryl Sulphate (SLS) WasteRisfidian Mohadi0https://orcid.org/0000-0003-4974-4329Yusuf Mathiinul Hakim1https://orcid.org/0000-0003-3350-8129Rahma Dinta Astuti2Idha Royani3https://orcid.org/0000-0002-2068-9517Mardiyanto Mardiyanto4https://orcid.org/0000-0002-2951-4123Graduate School, Faculty of Mathematics and Natural Sciences, Sriwijaya University, Palembang, 30139, South Sumatera, IndonesiaGraduate School, Faculty of Mathematics and Natural Sciences, Sriwijaya University, Palembang, 30139, South Sumatera, IndonesiaDepartment of Chemistry, Faculty of Mathematics and Natural Sciences, Sriwijaya University, Palembang, 30139, South Sumatera, IndonesiaDepartment of Physics, Faculty of Mathematics and Natural Sciences, Sriwijaya University, Palembang, 30139, South Sumatera, IndonesiaPharmaceutical Department, Faculty of Mathematics and Natural Sciences, Sriwijaya University, Palembang, 30139, South Sumatera, IndonesiaIn this work, the Sumatera bentonite was sodium-pillarized in a new low-temperature and restricted time preparation route and then applied in anionic surfactant sodium lauryl sulphate removal. Structure characterization used Fourier Transform Infra Red (FT-IR), Scanning Electron Microscope - Energy Dispersive X-ray (SEM-EDX), X-ray Diffraction (XRD), and Brunauer–Emmett–Teller (BET) analysis. A strong peak at 22° and 35.66° in XRD analysis was detected as Sodium-pillar that increased crystallinity, then the functional changes of dehydration in lattice structure were detected in 1013 cm−1 by FTIR analysis. The morphology and compositional transformation were analyzed by SEM-EDX and BET analysis, denoted by increasing particle shape and sodium intercalant composition homogeneity. Moreover, the surface area increased from 61.791 to 66.086 m2/g. The sodium lauryl sulphate adsorption by bentonite-Na reached maximum capacity at 8.403 mg/g, which is higher than the pristine bentonite (5.747 mg/g) under the optimum condition. The adsorption mechanism is feasible, endothermic, and conformed to the pseudo-second-order and Freundlich adsorption model. The new route proposed for sodium intercalation effectively improves the Sumatera bentonite adsorption ability to remove sodium lauryl sulphate waste. Copyright © 2023 by Authors, Published by BCREC Group. This is an open access article under the CC BY-SA License (https://creativecommons.org/licenses/by-sa/4.0).https://journal.bcrec.id/index.php/bcrec/article/view/16500pillarizationsumatera bentonitebentonite-naadsorptionsodium lauryl sulphate. |
| spellingShingle | Risfidian Mohadi Yusuf Mathiinul Hakim Rahma Dinta Astuti Idha Royani Mardiyanto Mardiyanto Pillarization of Sumatera Bentonite by Sodium-assisted As Effective Adsorbent of Anionic Surfactants Sodium Lauryl Sulphate (SLS) Waste Bulletin of Chemical Reaction Engineering & Catalysis pillarization sumatera bentonite bentonite-na adsorption sodium lauryl sulphate. |
| title | Pillarization of Sumatera Bentonite by Sodium-assisted As Effective Adsorbent of Anionic Surfactants Sodium Lauryl Sulphate (SLS) Waste |
| title_full | Pillarization of Sumatera Bentonite by Sodium-assisted As Effective Adsorbent of Anionic Surfactants Sodium Lauryl Sulphate (SLS) Waste |
| title_fullStr | Pillarization of Sumatera Bentonite by Sodium-assisted As Effective Adsorbent of Anionic Surfactants Sodium Lauryl Sulphate (SLS) Waste |
| title_full_unstemmed | Pillarization of Sumatera Bentonite by Sodium-assisted As Effective Adsorbent of Anionic Surfactants Sodium Lauryl Sulphate (SLS) Waste |
| title_short | Pillarization of Sumatera Bentonite by Sodium-assisted As Effective Adsorbent of Anionic Surfactants Sodium Lauryl Sulphate (SLS) Waste |
| title_sort | pillarization of sumatera bentonite by sodium assisted as effective adsorbent of anionic surfactants sodium lauryl sulphate sls waste |
| topic | pillarization sumatera bentonite bentonite-na adsorption sodium lauryl sulphate. |
| url | https://journal.bcrec.id/index.php/bcrec/article/view/16500 |
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