Crystal structure of triaqua(1,10-phenanthroline-κ2N,N′)(2,4,5-trifluoro-3-methoxybenzoato-κO1)cobalt(II) 2,4,5-trifluoro-3-methoxybenzoate
The title salt, [Co(C8H4F3O3)(C12H8N2)(H2O)3](C8H4F3O3), was obtained under solvothermal conditions by the reaction of 2,4,5-trifluoro-3-methoxybenzoic acid with CoCl2 in the presence of 1,10-phenanthroline (phen). The CoII ion is octahedrally coordinated by two N atoms [Co—N = 2.165 (2) and 2.129 (...
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2014-11-01
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| Series: | Acta Crystallographica Section E |
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| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536814022077 |
| _version_ | 1819290586103939072 |
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| author | Junshan Sun |
| author_facet | Junshan Sun |
| author_sort | Junshan Sun |
| collection | DOAJ |
| description | The title salt, [Co(C8H4F3O3)(C12H8N2)(H2O)3](C8H4F3O3), was obtained under solvothermal conditions by the reaction of 2,4,5-trifluoro-3-methoxybenzoic acid with CoCl2 in the presence of 1,10-phenanthroline (phen). The CoII ion is octahedrally coordinated by two N atoms [Co—N = 2.165 (2) and 2.129 (2) Å] from the phen ligand, by one carboxylate O atom [Co—O = 2.107 (1) Å] and by three O atoms from water molecules [Co—O = 2.093 (1), 2.102 (1) and 2.114 (1) Å]. The equatorial positions of the slightly distorted octahedron are occupied by the N atoms, the carboxylate O and one water O atom. An intra- and intermolecular O—H...O hydrogen-bonding network between the water-containing complex cation and the organic anion leads to the formation of ribbons parallel to [010]. |
| first_indexed | 2024-12-24T03:25:06Z |
| format | Article |
| id | doaj.art-0c4f7eed24084bd386f1f54dc8019364 |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-24T03:25:06Z |
| publishDate | 2014-11-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-0c4f7eed24084bd386f1f54dc80193642022-12-21T17:17:22ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682014-11-017011m367m36810.1107/S1600536814022077wm5067Crystal structure of triaqua(1,10-phenanthroline-κ2N,N′)(2,4,5-trifluoro-3-methoxybenzoato-κO1)cobalt(II) 2,4,5-trifluoro-3-methoxybenzoateJunshan Sun0Beijing Key Laboratory for Science and Application of Functional Molecular and Crystalline Materials, Department of Chemistry, University of Science and Technology Beijing, Beijing,100083, People's Republic of ChinaThe title salt, [Co(C8H4F3O3)(C12H8N2)(H2O)3](C8H4F3O3), was obtained under solvothermal conditions by the reaction of 2,4,5-trifluoro-3-methoxybenzoic acid with CoCl2 in the presence of 1,10-phenanthroline (phen). The CoII ion is octahedrally coordinated by two N atoms [Co—N = 2.165 (2) and 2.129 (2) Å] from the phen ligand, by one carboxylate O atom [Co—O = 2.107 (1) Å] and by three O atoms from water molecules [Co—O = 2.093 (1), 2.102 (1) and 2.114 (1) Å]. The equatorial positions of the slightly distorted octahedron are occupied by the N atoms, the carboxylate O and one water O atom. An intra- and intermolecular O—H...O hydrogen-bonding network between the water-containing complex cation and the organic anion leads to the formation of ribbons parallel to [010].http://scripts.iucr.org/cgi-bin/paper?S1600536814022077crystal structurecobalt(II) complexphenanthroline ligands2,4,5-trifluoro-3-methoxybenzoate ligandshydrogen bonding |
| spellingShingle | Junshan Sun Crystal structure of triaqua(1,10-phenanthroline-κ2N,N′)(2,4,5-trifluoro-3-methoxybenzoato-κO1)cobalt(II) 2,4,5-trifluoro-3-methoxybenzoate Acta Crystallographica Section E crystal structure cobalt(II) complex phenanthroline ligands 2,4,5-trifluoro-3-methoxybenzoate ligands hydrogen bonding |
| title | Crystal structure of triaqua(1,10-phenanthroline-κ2N,N′)(2,4,5-trifluoro-3-methoxybenzoato-κO1)cobalt(II) 2,4,5-trifluoro-3-methoxybenzoate |
| title_full | Crystal structure of triaqua(1,10-phenanthroline-κ2N,N′)(2,4,5-trifluoro-3-methoxybenzoato-κO1)cobalt(II) 2,4,5-trifluoro-3-methoxybenzoate |
| title_fullStr | Crystal structure of triaqua(1,10-phenanthroline-κ2N,N′)(2,4,5-trifluoro-3-methoxybenzoato-κO1)cobalt(II) 2,4,5-trifluoro-3-methoxybenzoate |
| title_full_unstemmed | Crystal structure of triaqua(1,10-phenanthroline-κ2N,N′)(2,4,5-trifluoro-3-methoxybenzoato-κO1)cobalt(II) 2,4,5-trifluoro-3-methoxybenzoate |
| title_short | Crystal structure of triaqua(1,10-phenanthroline-κ2N,N′)(2,4,5-trifluoro-3-methoxybenzoato-κO1)cobalt(II) 2,4,5-trifluoro-3-methoxybenzoate |
| title_sort | crystal structure of triaqua 1 10 phenanthroline κ2n n 2 4 5 trifluoro 3 methoxybenzoato κo1 cobalt ii 2 4 5 trifluoro 3 methoxybenzoate |
| topic | crystal structure cobalt(II) complex phenanthroline ligands 2,4,5-trifluoro-3-methoxybenzoate ligands hydrogen bonding |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536814022077 |
| work_keys_str_mv | AT junshansun crystalstructureoftriaqua110phenanthrolinek2nn245trifluoro3methoxybenzoatoko1cobaltii245trifluoro3methoxybenzoate |