Effect of preparation methods on morphology of active manganese dioxide and 2,4-dinitrophenol adsorption performance

Herein active manganese dioxide was prepared by different methods using KMnO 4 and MnSO 4 ·H 2 O as inorganic precursors. The impact of preparation methods on morphology and adsorption performance of the synthesized products was investigated. The experimental results show that the reaction temperatu...

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Main Authors: Hua-jun Chen, Wenjie Tian, Wuxiu Ding
Format: Article
Language:English
Published: SAGE Publications 2018-05-01
Series:Adsorption Science & Technology
Online Access:https://doi.org/10.1177/0263617417752578
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author Hua-jun Chen
Wenjie Tian
Wuxiu Ding
author_facet Hua-jun Chen
Wenjie Tian
Wuxiu Ding
author_sort Hua-jun Chen
collection DOAJ
description Herein active manganese dioxide was prepared by different methods using KMnO 4 and MnSO 4 ·H 2 O as inorganic precursors. The impact of preparation methods on morphology and adsorption performance of the synthesized products was investigated. The experimental results show that the reaction temperature and pressure had a great effect on the morphology and adsorption performance of active manganese dioxide. The shape of active manganese dioxide prepared at room temperature and pressure was short rod-like while active manganese dioxide synthesized by hydrothermal method was mesoporous fibers and had better adsorption performance. The adsorption behavior of 2,4-dinitrophenol on mesoporous manganese dioxide was well described by Langmuir and Freundlich isotherm equation ( R 2 >0.99) and pseudo-second-order kinetic equation ( R 2 >0.99), so the adsorption process maybe a chemical and monolayer adsorption. The pH of solution had significant effect on the adsorption performance of 2,4-dinitrophenol on mesoporous manganese dioxide. The adsorption capacity was 2.539 mg/g in the condition of pH = 7.
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spelling doaj.art-0c59661a0c7e45cb9aebf895cb62f6862024-03-02T00:33:34ZengSAGE PublicationsAdsorption Science & Technology0263-61742048-40382018-05-013610.1177/0263617417752578Effect of preparation methods on morphology of active manganese dioxide and 2,4-dinitrophenol adsorption performanceHua-jun ChenWenjie TianWuxiu DingHerein active manganese dioxide was prepared by different methods using KMnO 4 and MnSO 4 ·H 2 O as inorganic precursors. The impact of preparation methods on morphology and adsorption performance of the synthesized products was investigated. The experimental results show that the reaction temperature and pressure had a great effect on the morphology and adsorption performance of active manganese dioxide. The shape of active manganese dioxide prepared at room temperature and pressure was short rod-like while active manganese dioxide synthesized by hydrothermal method was mesoporous fibers and had better adsorption performance. The adsorption behavior of 2,4-dinitrophenol on mesoporous manganese dioxide was well described by Langmuir and Freundlich isotherm equation ( R 2 >0.99) and pseudo-second-order kinetic equation ( R 2 >0.99), so the adsorption process maybe a chemical and monolayer adsorption. The pH of solution had significant effect on the adsorption performance of 2,4-dinitrophenol on mesoporous manganese dioxide. The adsorption capacity was 2.539 mg/g in the condition of pH = 7.https://doi.org/10.1177/0263617417752578
spellingShingle Hua-jun Chen
Wenjie Tian
Wuxiu Ding
Effect of preparation methods on morphology of active manganese dioxide and 2,4-dinitrophenol adsorption performance
Adsorption Science & Technology
title Effect of preparation methods on morphology of active manganese dioxide and 2,4-dinitrophenol adsorption performance
title_full Effect of preparation methods on morphology of active manganese dioxide and 2,4-dinitrophenol adsorption performance
title_fullStr Effect of preparation methods on morphology of active manganese dioxide and 2,4-dinitrophenol adsorption performance
title_full_unstemmed Effect of preparation methods on morphology of active manganese dioxide and 2,4-dinitrophenol adsorption performance
title_short Effect of preparation methods on morphology of active manganese dioxide and 2,4-dinitrophenol adsorption performance
title_sort effect of preparation methods on morphology of active manganese dioxide and 2 4 dinitrophenol adsorption performance
url https://doi.org/10.1177/0263617417752578
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AT wuxiuding effectofpreparationmethodsonmorphologyofactivemanganesedioxideand24dinitrophenoladsorptionperformance