Textural properties of VO/TiO catalysts obtained from VOCl
V 2 O 5 /TiO 2 systems have been obtained by reacting TiO 2 (P-25 from Degussa, ca 55% anatase, or a rutilised modification, ca 3% anatase) with gaseous VOCl 3 . The samples have been characterised by X-ray diffraction, UV–Vis spectrophotometry and nitrogen adsorption at 77 K. For the anatase carrie...
| Main Authors: | , |
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| Format: | Article |
| Language: | English |
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SAGE Publications
1985-12-01
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| Series: | Adsorption Science & Technology |
| Online Access: | https://doi.org/10.1177/026361748500200404 |
| _version_ | 1797283840818937856 |
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| author | C. Martin V. Rives |
| author_facet | C. Martin V. Rives |
| author_sort | C. Martin |
| collection | DOAJ |
| description | V 2 O 5 /TiO 2 systems have been obtained by reacting TiO 2 (P-25 from Degussa, ca 55% anatase, or a rutilised modification, ca 3% anatase) with gaseous VOCl 3 . The samples have been characterised by X-ray diffraction, UV–Vis spectrophotometry and nitrogen adsorption at 77 K. For the anatase carrier, a monolayer coverage of V 2 O 5 is achieved, but only 0·46 monolayers are formed with the rutilised support. The specific surface areas decrease upon incorporation of V 2 O 5 , and that seems to be well dispersed without forming crystallites. |
| first_indexed | 2024-03-07T17:37:38Z |
| format | Article |
| id | doaj.art-0c7fd45c6d084f1dba9fa9aaa2409df0 |
| institution | Directory Open Access Journal |
| issn | 0263-6174 2048-4038 |
| language | English |
| last_indexed | 2024-03-07T17:37:38Z |
| publishDate | 1985-12-01 |
| publisher | SAGE Publications |
| record_format | Article |
| series | Adsorption Science & Technology |
| spelling | doaj.art-0c7fd45c6d084f1dba9fa9aaa2409df02024-03-02T16:21:30ZengSAGE PublicationsAdsorption Science & Technology0263-61742048-40381985-12-01210.1177/026361748500200404Textural properties of VO/TiO catalysts obtained from VOClC. Martin0V. Rives1Departamento de Química Inorgánica, Facultad de Farmacia, Universidad de Salamanca, Apdo. 449, 37071-Salamanca, SpainDepartamento de Química Inorgánica, Facultad de Farmacia, Universidad de Salamanca, Apdo. 449, 37071-Salamanca, SpainV 2 O 5 /TiO 2 systems have been obtained by reacting TiO 2 (P-25 from Degussa, ca 55% anatase, or a rutilised modification, ca 3% anatase) with gaseous VOCl 3 . The samples have been characterised by X-ray diffraction, UV–Vis spectrophotometry and nitrogen adsorption at 77 K. For the anatase carrier, a monolayer coverage of V 2 O 5 is achieved, but only 0·46 monolayers are formed with the rutilised support. The specific surface areas decrease upon incorporation of V 2 O 5 , and that seems to be well dispersed without forming crystallites.https://doi.org/10.1177/026361748500200404 |
| spellingShingle | C. Martin V. Rives Textural properties of VO/TiO catalysts obtained from VOCl Adsorption Science & Technology |
| title | Textural properties of VO/TiO catalysts obtained from VOCl |
| title_full | Textural properties of VO/TiO catalysts obtained from VOCl |
| title_fullStr | Textural properties of VO/TiO catalysts obtained from VOCl |
| title_full_unstemmed | Textural properties of VO/TiO catalysts obtained from VOCl |
| title_short | Textural properties of VO/TiO catalysts obtained from VOCl |
| title_sort | textural properties of vo tio catalysts obtained from vocl |
| url | https://doi.org/10.1177/026361748500200404 |
| work_keys_str_mv | AT cmartin texturalpropertiesofvotiocatalystsobtainedfromvocl AT vrives texturalpropertiesofvotiocatalystsobtainedfromvocl |