<i>In-situ</i> synthesis and electrochemical properties of flower-like cobalt hydroxide
The cobalt hydroxides were <i>in situ</i> synthesized <i>via</i> hydrothermal method with carbon fiber derived from cotton as substrate using cobalt nitrate as cobalt precursor and hexamethylenetetramine as precipitation agent. The morphology and structure of the materials we...
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| Format: | Article |
| Language: | zho |
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Journal of Materials Engineering
2019-03-01
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| Series: | Cailiao gongcheng |
| Subjects: | |
| Online Access: | http://html.rhhz.net/CHXB/html/2020-3-121.htm |
| _version_ | 1797966159663857664 |
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| author | FENG Yan-yan LI Yan-jie YANG Wen ZHONG Kai-ying |
| author_facet | FENG Yan-yan LI Yan-jie YANG Wen ZHONG Kai-ying |
| author_sort | FENG Yan-yan |
| collection | DOAJ |
| description | The cobalt hydroxides were <i>in situ</i> synthesized <i>via</i> hydrothermal method with carbon fiber derived from cotton as substrate using cobalt nitrate as cobalt precursor and hexamethylenetetramine as precipitation agent. The morphology and structure of the materials were characterized by scanning electron microscope(SEM), X-ray diffraction(XRD) and IR spectra, respectively. The electroch-emical performance of the samples was analyzed by electrochemical tests such as cyclic voltammetry, galvanostatic charge and discharge and AC impedance. The XRD and SEM results show that, the obtained cobalt hydroxide grown <i>in situ</i> on the carbon fiber substrate is flower-like and α-phase. The electrochemical performance tests display that the specific capacitance of the flower-like cobalt hydroxide is 650 F/g at the current density of 1 A/g, and the retention rate of 67% can be kept with the current density of 10 A/g. The above results illustrate that the flower-like cobalt hydroxide has excellent electrochemical performance, mainly due to its unique structure and morphology, which significantly improves the stability of the electrode material, the diffusion rate of ions and the transport efficiency of electrons. |
| first_indexed | 2024-04-11T02:11:20Z |
| format | Article |
| id | doaj.art-0c991a5513e44072af729f0bf0e38c76 |
| institution | Directory Open Access Journal |
| issn | 1001-4381 1001-4381 |
| language | zho |
| last_indexed | 2024-04-11T02:11:20Z |
| publishDate | 2019-03-01 |
| publisher | Journal of Materials Engineering |
| record_format | Article |
| series | Cailiao gongcheng |
| spelling | doaj.art-0c991a5513e44072af729f0bf0e38c762023-01-03T01:57:56ZzhoJournal of Materials EngineeringCailiao gongcheng1001-43811001-43812019-03-0148312112620200316<i>In-situ</i> synthesis and electrochemical properties of flower-like cobalt hydroxideFENG Yan-yan0LI Yan-jie1YANG Wen2ZHONG Kai-ying3Guangxi Key Laboratory of Electrochemical and Magnetochemical Functional Materials, College of Chemistry and Bioengineering, Guilin University of Technology, Guilin 541004, Guangxi, ChinaGuangxi Key Laboratory of Electrochemical and Magnetochemical Functional Materials, College of Chemistry and Bioengineering, Guilin University of Technology, Guilin 541004, Guangxi, ChinaGuangxi Key Laboratory of Electrochemical and Magnetochemical Functional Materials, College of Chemistry and Bioengineering, Guilin University of Technology, Guilin 541004, Guangxi, ChinaGuangxi Key Laboratory of Electrochemical and Magnetochemical Functional Materials, College of Chemistry and Bioengineering, Guilin University of Technology, Guilin 541004, Guangxi, ChinaThe cobalt hydroxides were <i>in situ</i> synthesized <i>via</i> hydrothermal method with carbon fiber derived from cotton as substrate using cobalt nitrate as cobalt precursor and hexamethylenetetramine as precipitation agent. The morphology and structure of the materials were characterized by scanning electron microscope(SEM), X-ray diffraction(XRD) and IR spectra, respectively. The electroch-emical performance of the samples was analyzed by electrochemical tests such as cyclic voltammetry, galvanostatic charge and discharge and AC impedance. The XRD and SEM results show that, the obtained cobalt hydroxide grown <i>in situ</i> on the carbon fiber substrate is flower-like and α-phase. The electrochemical performance tests display that the specific capacitance of the flower-like cobalt hydroxide is 650 F/g at the current density of 1 A/g, and the retention rate of 67% can be kept with the current density of 10 A/g. The above results illustrate that the flower-like cobalt hydroxide has excellent electrochemical performance, mainly due to its unique structure and morphology, which significantly improves the stability of the electrode material, the diffusion rate of ions and the transport efficiency of electrons.http://html.rhhz.net/CHXB/html/2020-3-121.htmsupercapacitorflower-like cobalt hydroxidecarbon fiberhexamethylenetetramine |
| spellingShingle | FENG Yan-yan LI Yan-jie YANG Wen ZHONG Kai-ying <i>In-situ</i> synthesis and electrochemical properties of flower-like cobalt hydroxide Cailiao gongcheng supercapacitor flower-like cobalt hydroxide carbon fiber hexamethylenetetramine |
| title | <i>In-situ</i> synthesis and electrochemical properties of flower-like cobalt hydroxide |
| title_full | <i>In-situ</i> synthesis and electrochemical properties of flower-like cobalt hydroxide |
| title_fullStr | <i>In-situ</i> synthesis and electrochemical properties of flower-like cobalt hydroxide |
| title_full_unstemmed | <i>In-situ</i> synthesis and electrochemical properties of flower-like cobalt hydroxide |
| title_short | <i>In-situ</i> synthesis and electrochemical properties of flower-like cobalt hydroxide |
| title_sort | i in situ i synthesis and electrochemical properties of flower like cobalt hydroxide |
| topic | supercapacitor flower-like cobalt hydroxide carbon fiber hexamethylenetetramine |
| url | http://html.rhhz.net/CHXB/html/2020-3-121.htm |
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