Facile synthesis of reusable graphene oxide composite magnetic beads for removal of arsenic (III)

Abstract Consumption of As(III) in drinking water is a severe problem, and more than 180 million people are suffering worldwide. Therefore, developing an affordable technique to remove As(III) from drinking water is essential to protect human health. In this work, we report chitosan‐iron oxide‐graph...

Full description

Bibliographic Details
Main Authors: Savan K. Raj, Jeet Sharma, Vaibhav Kulshrestha
Format: Article
Language:English
Published: Wiley 2021-02-01
Series:SPE Polymers
Subjects:
Online Access:https://doi.org/10.1002/pls2.10031
_version_ 1811180839631847424
author Savan K. Raj
Jeet Sharma
Vaibhav Kulshrestha
author_facet Savan K. Raj
Jeet Sharma
Vaibhav Kulshrestha
author_sort Savan K. Raj
collection DOAJ
description Abstract Consumption of As(III) in drinking water is a severe problem, and more than 180 million people are suffering worldwide. Therefore, developing an affordable technique to remove As(III) from drinking water is essential to protect human health. In this work, we report chitosan‐iron oxide‐graphene oxide composite beads (GO‐BDs) for the removal of As(III) from the drinking water. The incorporation of chitosan and graphene oxide (GO) provides better physical strength and stability to the GO‐BDs. Prepared GO‐BDs were characterized using different characterization techniques. X‐Ray diffraction (XRD) spectra show the iron oxide nanoparticles were successfully linked with graphene oxide. The size of the beads confirmed by scanning electron microscopy (SEM) and found to be ~1 mm. Elemental mapping of beads show the uniform dispersion of GO/iron oxide on the surface of the beads. The adsorption of As(III) occurs rapidly and attain equilibrium condition in <6 h after removing As(III) from the water within the permissible limit. Effect of water pH, time, temperature, adsorbent dosage, and concentration of the dose have been studied in detail for arsenic removal. Coexisting ions show negligible influence on As(III) removal. Langmuir and Freundlich isotherms were also examined. This study provides the application of GO‐BDs for As(III) removal from contaminated drinking water.
first_indexed 2024-04-11T09:10:04Z
format Article
id doaj.art-0ca532596ab543c19a291cfbb959b35d
institution Directory Open Access Journal
issn 2690-3857
language English
last_indexed 2024-04-11T09:10:04Z
publishDate 2021-02-01
publisher Wiley
record_format Article
series SPE Polymers
spelling doaj.art-0ca532596ab543c19a291cfbb959b35d2022-12-22T04:32:32ZengWileySPE Polymers2690-38572021-02-0121748510.1002/pls2.10031Facile synthesis of reusable graphene oxide composite magnetic beads for removal of arsenic (III)Savan K. Raj0Jeet Sharma1Vaibhav Kulshrestha2CSIR‐Central Salt and Marine Chemicals Research Institute Bhavnagar IndiaCSIR‐Central Salt and Marine Chemicals Research Institute Bhavnagar IndiaCSIR‐Central Salt and Marine Chemicals Research Institute Bhavnagar IndiaAbstract Consumption of As(III) in drinking water is a severe problem, and more than 180 million people are suffering worldwide. Therefore, developing an affordable technique to remove As(III) from drinking water is essential to protect human health. In this work, we report chitosan‐iron oxide‐graphene oxide composite beads (GO‐BDs) for the removal of As(III) from the drinking water. The incorporation of chitosan and graphene oxide (GO) provides better physical strength and stability to the GO‐BDs. Prepared GO‐BDs were characterized using different characterization techniques. X‐Ray diffraction (XRD) spectra show the iron oxide nanoparticles were successfully linked with graphene oxide. The size of the beads confirmed by scanning electron microscopy (SEM) and found to be ~1 mm. Elemental mapping of beads show the uniform dispersion of GO/iron oxide on the surface of the beads. The adsorption of As(III) occurs rapidly and attain equilibrium condition in <6 h after removing As(III) from the water within the permissible limit. Effect of water pH, time, temperature, adsorbent dosage, and concentration of the dose have been studied in detail for arsenic removal. Coexisting ions show negligible influence on As(III) removal. Langmuir and Freundlich isotherms were also examined. This study provides the application of GO‐BDs for As(III) removal from contaminated drinking water.https://doi.org/10.1002/pls2.10031As(III) removalgraphene oxideiron oxidereusable beads
spellingShingle Savan K. Raj
Jeet Sharma
Vaibhav Kulshrestha
Facile synthesis of reusable graphene oxide composite magnetic beads for removal of arsenic (III)
SPE Polymers
As(III) removal
graphene oxide
iron oxide
reusable beads
title Facile synthesis of reusable graphene oxide composite magnetic beads for removal of arsenic (III)
title_full Facile synthesis of reusable graphene oxide composite magnetic beads for removal of arsenic (III)
title_fullStr Facile synthesis of reusable graphene oxide composite magnetic beads for removal of arsenic (III)
title_full_unstemmed Facile synthesis of reusable graphene oxide composite magnetic beads for removal of arsenic (III)
title_short Facile synthesis of reusable graphene oxide composite magnetic beads for removal of arsenic (III)
title_sort facile synthesis of reusable graphene oxide composite magnetic beads for removal of arsenic iii
topic As(III) removal
graphene oxide
iron oxide
reusable beads
url https://doi.org/10.1002/pls2.10031
work_keys_str_mv AT savankraj facilesynthesisofreusablegrapheneoxidecompositemagneticbeadsforremovalofarseniciii
AT jeetsharma facilesynthesisofreusablegrapheneoxidecompositemagneticbeadsforremovalofarseniciii
AT vaibhavkulshrestha facilesynthesisofreusablegrapheneoxidecompositemagneticbeadsforremovalofarseniciii