Biaxial Elongation Behavior in Partially Molted State of Two-Layer Sheets Containing Postconsumer Material

Due to the lack of raw material and forced by political demand, an increasing percentage of postconsumer materials (PCR) shall be used in all processing methods in polymer technology. Thermoforming, as one of the oldest polymer-processing methods, has special requirements regarding the melt stabilit...

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Main Authors: Lisa-Maria Wittmann, Joachim Kaschta, Dietmar Drummer
Format: Article
Language:English
Published: MDPI AG 2022-08-01
Series:Polymers
Subjects:
Online Access:https://www.mdpi.com/2073-4360/14/15/3172
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author Lisa-Maria Wittmann
Joachim Kaschta
Dietmar Drummer
author_facet Lisa-Maria Wittmann
Joachim Kaschta
Dietmar Drummer
author_sort Lisa-Maria Wittmann
collection DOAJ
description Due to the lack of raw material and forced by political demand, an increasing percentage of postconsumer materials (PCR) shall be used in all processing methods in polymer technology. Thermoforming, as one of the oldest polymer-processing methods, has special requirements regarding the melt stability at high temperatures. Low melt stability affects the thermoforming in a negative manner, as the low stiffness leads the sheet to sag during the heating phase. In this study, two-layer sheets are used in order to improve melt stability of PCR material. The focus is placed on the influence of rheological properties on the biaxial stretching behavior of mono- and two-layer sheets in partially molted state. In order to create a stabilizing layer, two different thermoformable virgin materials with a melt flow rate (MFR) of 3 g/10 min and 6 g/10 min were chosen. The second layer consists of instable PCR materials with a MFR of 16 g/10min and 50 g/10 min. Rheological investigations, molecular characterization and biaxial stretching tests are used to show the benefit of two-layer sheets for processing PCR material under elongational stress. The results show that the use of two-layer sheets can improve the biaxial stretching properties, so that two-layer sheets can offer a significant potential in the processing of PCR materials in thermoforming.
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spelling doaj.art-0cb4dd7e286742b3b7d8e19900756fc42023-12-01T23:07:27ZengMDPI AGPolymers2073-43602022-08-011415317210.3390/polym14153172Biaxial Elongation Behavior in Partially Molted State of Two-Layer Sheets Containing Postconsumer MaterialLisa-Maria Wittmann0Joachim Kaschta1Dietmar Drummer2Department of Mechanical Engineering, Institute of Polymer Technology, Friedrich-Alexander-Universität Erlangen-Nürnberg, Am Weichselgarten 10, 91058 Erlangen, GermanyDepartment of Material Science and Engineering, Institute of Polymer Materials, Friedrich-Alexander-Universität Erlangen-Nürnberg, Martenstraße 7, 91058 Erlangen, GermanyDepartment of Mechanical Engineering, Institute of Polymer Technology, Friedrich-Alexander-Universität Erlangen-Nürnberg, Am Weichselgarten 10, 91058 Erlangen, GermanyDue to the lack of raw material and forced by political demand, an increasing percentage of postconsumer materials (PCR) shall be used in all processing methods in polymer technology. Thermoforming, as one of the oldest polymer-processing methods, has special requirements regarding the melt stability at high temperatures. Low melt stability affects the thermoforming in a negative manner, as the low stiffness leads the sheet to sag during the heating phase. In this study, two-layer sheets are used in order to improve melt stability of PCR material. The focus is placed on the influence of rheological properties on the biaxial stretching behavior of mono- and two-layer sheets in partially molted state. In order to create a stabilizing layer, two different thermoformable virgin materials with a melt flow rate (MFR) of 3 g/10 min and 6 g/10 min were chosen. The second layer consists of instable PCR materials with a MFR of 16 g/10min and 50 g/10 min. Rheological investigations, molecular characterization and biaxial stretching tests are used to show the benefit of two-layer sheets for processing PCR material under elongational stress. The results show that the use of two-layer sheets can improve the biaxial stretching properties, so that two-layer sheets can offer a significant potential in the processing of PCR materials in thermoforming.https://www.mdpi.com/2073-4360/14/15/3172two-layer sheetbiaxial stretchingpostconsumer material
spellingShingle Lisa-Maria Wittmann
Joachim Kaschta
Dietmar Drummer
Biaxial Elongation Behavior in Partially Molted State of Two-Layer Sheets Containing Postconsumer Material
Polymers
two-layer sheet
biaxial stretching
postconsumer material
title Biaxial Elongation Behavior in Partially Molted State of Two-Layer Sheets Containing Postconsumer Material
title_full Biaxial Elongation Behavior in Partially Molted State of Two-Layer Sheets Containing Postconsumer Material
title_fullStr Biaxial Elongation Behavior in Partially Molted State of Two-Layer Sheets Containing Postconsumer Material
title_full_unstemmed Biaxial Elongation Behavior in Partially Molted State of Two-Layer Sheets Containing Postconsumer Material
title_short Biaxial Elongation Behavior in Partially Molted State of Two-Layer Sheets Containing Postconsumer Material
title_sort biaxial elongation behavior in partially molted state of two layer sheets containing postconsumer material
topic two-layer sheet
biaxial stretching
postconsumer material
url https://www.mdpi.com/2073-4360/14/15/3172
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AT dietmardrummer biaxialelongationbehaviorinpartiallymoltedstateoftwolayersheetscontainingpostconsumermaterial