Synthesis of Ammonium Dinitramide by Nitration of Potassium and Ammonium Sulfamate. The Effect of Sulfamate Conterion on ADN Purity
Nitration of potassium sulphamate was carried out using a mixture of sulphuric and nitric acid at -30 °C. The reaction time was optimized at the mole ratio of sulphuric to nitric acid of (1:3.5). The difference in product yield by changing the potassium to ammonium sulphamate was studied throughly....
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| Format: | Article |
| Language: | English |
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Iranian Institute of Research and Development in Chemical Industries (IRDCI)-ACECR
2008-03-01
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| Series: | Iranian Journal of Chemistry & Chemical Engineering |
| Subjects: | |
| Online Access: | http://www.ijcce.ac.ir/article_7128_95472a7cb423c8056ae145c7e55316c9.pdf |
| _version_ | 1811265545096396800 |
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| author | Gholam Hossein Nazeri Ramin Mastour Mohammad Fayaznia Parviz Keyghobadi |
| author_facet | Gholam Hossein Nazeri Ramin Mastour Mohammad Fayaznia Parviz Keyghobadi |
| author_sort | Gholam Hossein Nazeri |
| collection | DOAJ |
| description | Nitration of potassium sulphamate was carried out using a mixture of sulphuric and nitric acid at -30 °C. The reaction time was optimized at the mole ratio of sulphuric to nitric acid of (1:3.5). The difference in product yield by changing the potassium to ammonium sulphamate was studied throughly. It was found that both the yield and purity of the product is better starting with potassium sulphamate. |
| first_indexed | 2024-04-12T20:25:42Z |
| format | Article |
| id | doaj.art-0cbfe48e9be640aab6f9648b179cae4d |
| institution | Directory Open Access Journal |
| issn | 1021-9986 1021-9986 |
| language | English |
| last_indexed | 2024-04-12T20:25:42Z |
| publishDate | 2008-03-01 |
| publisher | Iranian Institute of Research and Development in Chemical Industries (IRDCI)-ACECR |
| record_format | Article |
| series | Iranian Journal of Chemistry & Chemical Engineering |
| spelling | doaj.art-0cbfe48e9be640aab6f9648b179cae4d2022-12-22T03:17:52ZengIranian Institute of Research and Development in Chemical Industries (IRDCI)-ACECRIranian Journal of Chemistry & Chemical Engineering1021-99861021-99862008-03-0127185897128Synthesis of Ammonium Dinitramide by Nitration of Potassium and Ammonium Sulfamate. The Effect of Sulfamate Conterion on ADN PurityGholam Hossein Nazeri0Ramin Mastour1Mohammad Fayaznia2Parviz Keyghobadi3Advanced Material’s Research Center, P.O. Box 16765-3574 Tehran, I.R. IRANAdvanced Material’s Research Center, P.O. Box 16765-3574 Tehran, I.R. IRANAdvanced Material’s Research Center, P.O. Box 16765-3574 Tehran, I.R. IRANAdvanced Material’s Research Center, P.O. Box 16765-3574 Tehran, I.R. IRANNitration of potassium sulphamate was carried out using a mixture of sulphuric and nitric acid at -30 °C. The reaction time was optimized at the mole ratio of sulphuric to nitric acid of (1:3.5). The difference in product yield by changing the potassium to ammonium sulphamate was studied throughly. It was found that both the yield and purity of the product is better starting with potassium sulphamate.http://www.ijcce.ac.ir/article_7128_95472a7cb423c8056ae145c7e55316c9.pdfpotassium sulphamatedinitramidic acidnitrationammonium dinitramidepotassium dinitramide |
| spellingShingle | Gholam Hossein Nazeri Ramin Mastour Mohammad Fayaznia Parviz Keyghobadi Synthesis of Ammonium Dinitramide by Nitration of Potassium and Ammonium Sulfamate. The Effect of Sulfamate Conterion on ADN Purity Iranian Journal of Chemistry & Chemical Engineering potassium sulphamate dinitramidic acid nitration ammonium dinitramide potassium dinitramide |
| title | Synthesis of Ammonium Dinitramide by Nitration of Potassium and Ammonium Sulfamate. The Effect of Sulfamate Conterion on ADN Purity |
| title_full | Synthesis of Ammonium Dinitramide by Nitration of Potassium and Ammonium Sulfamate. The Effect of Sulfamate Conterion on ADN Purity |
| title_fullStr | Synthesis of Ammonium Dinitramide by Nitration of Potassium and Ammonium Sulfamate. The Effect of Sulfamate Conterion on ADN Purity |
| title_full_unstemmed | Synthesis of Ammonium Dinitramide by Nitration of Potassium and Ammonium Sulfamate. The Effect of Sulfamate Conterion on ADN Purity |
| title_short | Synthesis of Ammonium Dinitramide by Nitration of Potassium and Ammonium Sulfamate. The Effect of Sulfamate Conterion on ADN Purity |
| title_sort | synthesis of ammonium dinitramide by nitration of potassium and ammonium sulfamate the effect of sulfamate conterion on adn purity |
| topic | potassium sulphamate dinitramidic acid nitration ammonium dinitramide potassium dinitramide |
| url | http://www.ijcce.ac.ir/article_7128_95472a7cb423c8056ae145c7e55316c9.pdf |
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