Methyl 3-(4-bromophenyl)-1-methyl-1,2,3,3a,4,9b-hexahydrobenzo[f]chromeno[4,3-b]pyrrole-3a-carboxylate
In the title compound, C24H22BrNO3, the dihydropyran ring adopts a half-chair conformation, whereas the pyrrolidine ring is in an envelope conformation. The bromophenyl group is oriented at an angle of 66.44 (4)° with respect to the naphthalene ring system. In the crystal...
| Main Authors: | , , , , |
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2009-08-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536809029389 |
| _version_ | 1819279928153079808 |
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| author | S. Nirmala E. Theboral Sugi Kamala L. Sudha S. Kathiravan R. Raghunathan |
| author_facet | S. Nirmala E. Theboral Sugi Kamala L. Sudha S. Kathiravan R. Raghunathan |
| author_sort | S. Nirmala |
| collection | DOAJ |
| description | In the title compound, C24H22BrNO3, the dihydropyran ring adopts a half-chair conformation, whereas the pyrrolidine ring is in an envelope conformation. The bromophenyl group is oriented at an angle of 66.44 (4)° with respect to the naphthalene ring system. In the crystal structure, molecules are linked into centrosymmetric dimers by C—H...π interactions and the dimers are connected via C—H...Br hydrogen bonds. The crystal structure is further stabilized by π–π interactions [centroid–centroid distance = 3.453 (1) Å]. |
| first_indexed | 2024-12-24T00:35:41Z |
| format | Article |
| id | doaj.art-0cca2c0004bc417fbd5c71e4a8f471f8 |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-24T00:35:41Z |
| publishDate | 2009-08-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-0cca2c0004bc417fbd5c71e4a8f471f82022-12-21T17:24:05ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682009-08-01658o2028o202910.1107/S1600536809029389Methyl 3-(4-bromophenyl)-1-methyl-1,2,3,3a,4,9b-hexahydrobenzo[f]chromeno[4,3-b]pyrrole-3a-carboxylateS. NirmalaE. Theboral Sugi KamalaL. SudhaS. KathiravanR. RaghunathanIn the title compound, C24H22BrNO3, the dihydropyran ring adopts a half-chair conformation, whereas the pyrrolidine ring is in an envelope conformation. The bromophenyl group is oriented at an angle of 66.44 (4)° with respect to the naphthalene ring system. In the crystal structure, molecules are linked into centrosymmetric dimers by C—H...π interactions and the dimers are connected via C—H...Br hydrogen bonds. The crystal structure is further stabilized by π–π interactions [centroid–centroid distance = 3.453 (1) Å].http://scripts.iucr.org/cgi-bin/paper?S1600536809029389 |
| spellingShingle | S. Nirmala E. Theboral Sugi Kamala L. Sudha S. Kathiravan R. Raghunathan Methyl 3-(4-bromophenyl)-1-methyl-1,2,3,3a,4,9b-hexahydrobenzo[f]chromeno[4,3-b]pyrrole-3a-carboxylate Acta Crystallographica Section E |
| title | Methyl 3-(4-bromophenyl)-1-methyl-1,2,3,3a,4,9b-hexahydrobenzo[f]chromeno[4,3-b]pyrrole-3a-carboxylate |
| title_full | Methyl 3-(4-bromophenyl)-1-methyl-1,2,3,3a,4,9b-hexahydrobenzo[f]chromeno[4,3-b]pyrrole-3a-carboxylate |
| title_fullStr | Methyl 3-(4-bromophenyl)-1-methyl-1,2,3,3a,4,9b-hexahydrobenzo[f]chromeno[4,3-b]pyrrole-3a-carboxylate |
| title_full_unstemmed | Methyl 3-(4-bromophenyl)-1-methyl-1,2,3,3a,4,9b-hexahydrobenzo[f]chromeno[4,3-b]pyrrole-3a-carboxylate |
| title_short | Methyl 3-(4-bromophenyl)-1-methyl-1,2,3,3a,4,9b-hexahydrobenzo[f]chromeno[4,3-b]pyrrole-3a-carboxylate |
| title_sort | methyl 3 4 bromophenyl 1 methyl 1 2 3 3a 4 9b hexahydrobenzo f chromeno 4 3 b pyrrole 3a carboxylate |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536809029389 |
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