Atomic layer deposition-induced integration of N-doped carbon particles on carbon foam for flexible supercapacitor

Flexible devices have attracted abundant attention in energy storage systems. In this paper, we presented a novel approach for fabricating flexible supercapacitor based on metal organic frameworks-derived material. In this approach, a uniform zeolitic imidazolate frameworks-8 layer with a high mass...

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Main Authors: Zhe Zhao, Ye Kong, Chang Liu, Jinrun Liu, Zhijie Wang, Gengfeng Zheng, Gaoshan Huang, Yongfeng Mei
Format: Article
Language:English
Published: Elsevier 2020-03-01
Series:Journal of Materiomics
Online Access:http://www.sciencedirect.com/science/article/pii/S2352847819301558
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author Zhe Zhao
Ye Kong
Chang Liu
Jinrun Liu
Zhijie Wang
Gengfeng Zheng
Gaoshan Huang
Yongfeng Mei
author_facet Zhe Zhao
Ye Kong
Chang Liu
Jinrun Liu
Zhijie Wang
Gengfeng Zheng
Gaoshan Huang
Yongfeng Mei
author_sort Zhe Zhao
collection DOAJ
description Flexible devices have attracted abundant attention in energy storage systems. In this paper, we presented a novel approach for fabricating flexible supercapacitor based on metal organic frameworks-derived material. In this approach, a uniform zeolitic imidazolate frameworks-8 layer with a high mass loading was deposited on a flexible carbon foam (CF) skeleton efficiently by the induction of a uniform ZnO nanomembrane prepared via an atomic layer deposition technique. A flexible N-doped carbon particle-carbon foam (N-CP-CF) composite with a hierarchically porous structure and a large specific surface area (i.e., 538 m2 g−1) was obtained in a subsequent pyrolysis process. The resultant materials have the excellent electrochemical performance (i.e., a high specific capacitance of 300 F g−1 and a high energy density of 20.8 W h kg−1). The N-CP-CF composite can provide a stable capacitance (i.e., 250 F g−1) and an energy density (i.e., 17.36 W h kg−1) under large deformation (25% of original thickness). This work could propose a promising strategy in fabrication of flexible electrode with a large potential towards energy storage applications in the future. Keywords: Atomic layer deposition, Zeolitic imidazolate framework-8, Flexible device, Supercapacitor
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spelling doaj.art-0d2eb791a60140f38bf870c1c9ef384c2023-09-02T23:37:28ZengElsevierJournal of Materiomics2352-84782020-03-0161209215Atomic layer deposition-induced integration of N-doped carbon particles on carbon foam for flexible supercapacitorZhe Zhao0Ye Kong1Chang Liu2Jinrun Liu3Zhijie Wang4Gengfeng Zheng5Gaoshan Huang6Yongfeng Mei7Department of Materials Science, Fudan University, Shanghai, 200433, ChinaDepartment of Materials Science, Fudan University, Shanghai, 200433, ChinaDepartment of Materials Science, Fudan University, Shanghai, 200433, ChinaDepartment of Materials Science, Fudan University, Shanghai, 200433, ChinaLaboratory of Advanced Materials, Fudan University, Shanghai, 200438, ChinaLaboratory of Advanced Materials, Fudan University, Shanghai, 200438, ChinaDepartment of Materials Science, Fudan University, Shanghai, 200433, China; Corresponding author.Department of Materials Science, Fudan University, Shanghai, 200433, China; Corresponding author.Flexible devices have attracted abundant attention in energy storage systems. In this paper, we presented a novel approach for fabricating flexible supercapacitor based on metal organic frameworks-derived material. In this approach, a uniform zeolitic imidazolate frameworks-8 layer with a high mass loading was deposited on a flexible carbon foam (CF) skeleton efficiently by the induction of a uniform ZnO nanomembrane prepared via an atomic layer deposition technique. A flexible N-doped carbon particle-carbon foam (N-CP-CF) composite with a hierarchically porous structure and a large specific surface area (i.e., 538 m2 g−1) was obtained in a subsequent pyrolysis process. The resultant materials have the excellent electrochemical performance (i.e., a high specific capacitance of 300 F g−1 and a high energy density of 20.8 W h kg−1). The N-CP-CF composite can provide a stable capacitance (i.e., 250 F g−1) and an energy density (i.e., 17.36 W h kg−1) under large deformation (25% of original thickness). This work could propose a promising strategy in fabrication of flexible electrode with a large potential towards energy storage applications in the future. Keywords: Atomic layer deposition, Zeolitic imidazolate framework-8, Flexible device, Supercapacitorhttp://www.sciencedirect.com/science/article/pii/S2352847819301558
spellingShingle Zhe Zhao
Ye Kong
Chang Liu
Jinrun Liu
Zhijie Wang
Gengfeng Zheng
Gaoshan Huang
Yongfeng Mei
Atomic layer deposition-induced integration of N-doped carbon particles on carbon foam for flexible supercapacitor
Journal of Materiomics
title Atomic layer deposition-induced integration of N-doped carbon particles on carbon foam for flexible supercapacitor
title_full Atomic layer deposition-induced integration of N-doped carbon particles on carbon foam for flexible supercapacitor
title_fullStr Atomic layer deposition-induced integration of N-doped carbon particles on carbon foam for flexible supercapacitor
title_full_unstemmed Atomic layer deposition-induced integration of N-doped carbon particles on carbon foam for flexible supercapacitor
title_short Atomic layer deposition-induced integration of N-doped carbon particles on carbon foam for flexible supercapacitor
title_sort atomic layer deposition induced integration of n doped carbon particles on carbon foam for flexible supercapacitor
url http://www.sciencedirect.com/science/article/pii/S2352847819301558
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