Evaluation of Low Cost-Activated Carbon Produced from Waste Tyres Pyrolysis for Removal of 2-Chlorophenol

A low cost Activated Carbon (AC) was prepared by using waste tyres as raw material for the removal of 2-chlorophenol (2-CP). The AC adsorbent was prepared and activated by pyrolysis process at 900 ºC under constant nitrogen flow. The physical properties of the AC produced was characterized using X-r...

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Main Authors: Kanchana Manirajah, Sheela V. Sukumaran, Nor Nasuha Abdullah, Hazirah A. Razak, Nurul Ainirazali
Format: Article
Language:English
Published: Masyarakat Katalis Indonesia - Indonesian Catalyst Society (MKICS) 2019-08-01
Series:Bulletin of Chemical Reaction Engineering & Catalysis
Subjects:
Online Access:https://journal.bcrec.id/index.php/bcrec/article/view/3617
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author Kanchana Manirajah
Sheela V. Sukumaran
Nor Nasuha Abdullah
Hazirah A. Razak
Nurul Ainirazali
author_facet Kanchana Manirajah
Sheela V. Sukumaran
Nor Nasuha Abdullah
Hazirah A. Razak
Nurul Ainirazali
author_sort Kanchana Manirajah
collection DOAJ
description A low cost Activated Carbon (AC) was prepared by using waste tyres as raw material for the removal of 2-chlorophenol (2-CP). The AC adsorbent was prepared and activated by pyrolysis process at 900 ºC under constant nitrogen flow. The physical properties of the AC produced was characterized using X-ray Diffraction (XRD), Brunauer-Emmett-Teller (BET), Field Emission Scanning Electron Microscopy (FESEM), and Fourier Transform Infra Red (FTIR). The influence of initial adsorbate concentration, pH and adsorbent dosage on the removal of 2-CP in the batch-operational mode at ambient temperature were also investigated. The results obtained showed the AC presence of an amorphous carbon with high BET surface area and a total pore volume of 208 m2.g-1 and 0.5817 cm3, respectively. The highest adsorption capacity of 2-CP by the AC absorbent was achieved at an initial concentration of 10 mg.L-1, pH 5, and adsorbent dosage of 0.5 g in the first 10 min of contact time. This finding proves that the low cost-AC produced from waste tyres can be utilized for an effective removal of chemical plant wastewater containing toxic chlorine substances. Copyright © 2019 BCREC Group. All rights reserved
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spelling doaj.art-0d30c9791d5d44efa1a3f95c76dfd7d02023-09-22T03:42:21ZengMasyarakat Katalis Indonesia - Indonesian Catalyst Society (MKICS)Bulletin of Chemical Reaction Engineering & Catalysis1978-29932019-08-0114244344910.9767/bcrec.14.2.3617.443-4492242Evaluation of Low Cost-Activated Carbon Produced from Waste Tyres Pyrolysis for Removal of 2-ChlorophenolKanchana Manirajah0Sheela V. Sukumaran1Nor Nasuha Abdullah2Hazirah A. Razak3Nurul Ainirazali4Faculty of Chemical & Natural Resources Engineering, Universiti Malaysia Pahang, MalaysiaFaculty of Chemical & Natural Resources Engineering, Universiti Malaysia Pahang, MalaysiaFaculty of Chemical & Natural Resources Engineering, Universiti Malaysia Pahang, MalaysiaFaculty of Chemical & Natural Resources Engineering, Universiti Malaysia Pahang, MalaysiaFaculty of Chemical & Natural Resources Engineering, Universiti Malaysia Pahang, MalaysiaA low cost Activated Carbon (AC) was prepared by using waste tyres as raw material for the removal of 2-chlorophenol (2-CP). The AC adsorbent was prepared and activated by pyrolysis process at 900 ºC under constant nitrogen flow. The physical properties of the AC produced was characterized using X-ray Diffraction (XRD), Brunauer-Emmett-Teller (BET), Field Emission Scanning Electron Microscopy (FESEM), and Fourier Transform Infra Red (FTIR). The influence of initial adsorbate concentration, pH and adsorbent dosage on the removal of 2-CP in the batch-operational mode at ambient temperature were also investigated. The results obtained showed the AC presence of an amorphous carbon with high BET surface area and a total pore volume of 208 m2.g-1 and 0.5817 cm3, respectively. The highest adsorption capacity of 2-CP by the AC absorbent was achieved at an initial concentration of 10 mg.L-1, pH 5, and adsorbent dosage of 0.5 g in the first 10 min of contact time. This finding proves that the low cost-AC produced from waste tyres can be utilized for an effective removal of chemical plant wastewater containing toxic chlorine substances. Copyright © 2019 BCREC Group. All rights reservedhttps://journal.bcrec.id/index.php/bcrec/article/view/3617waste tyreactivated carbonadsorption2-chlorophenolpyrolysis
spellingShingle Kanchana Manirajah
Sheela V. Sukumaran
Nor Nasuha Abdullah
Hazirah A. Razak
Nurul Ainirazali
Evaluation of Low Cost-Activated Carbon Produced from Waste Tyres Pyrolysis for Removal of 2-Chlorophenol
Bulletin of Chemical Reaction Engineering & Catalysis
waste tyre
activated carbon
adsorption
2-chlorophenol
pyrolysis
title Evaluation of Low Cost-Activated Carbon Produced from Waste Tyres Pyrolysis for Removal of 2-Chlorophenol
title_full Evaluation of Low Cost-Activated Carbon Produced from Waste Tyres Pyrolysis for Removal of 2-Chlorophenol
title_fullStr Evaluation of Low Cost-Activated Carbon Produced from Waste Tyres Pyrolysis for Removal of 2-Chlorophenol
title_full_unstemmed Evaluation of Low Cost-Activated Carbon Produced from Waste Tyres Pyrolysis for Removal of 2-Chlorophenol
title_short Evaluation of Low Cost-Activated Carbon Produced from Waste Tyres Pyrolysis for Removal of 2-Chlorophenol
title_sort evaluation of low cost activated carbon produced from waste tyres pyrolysis for removal of 2 chlorophenol
topic waste tyre
activated carbon
adsorption
2-chlorophenol
pyrolysis
url https://journal.bcrec.id/index.php/bcrec/article/view/3617
work_keys_str_mv AT kanchanamanirajah evaluationoflowcostactivatedcarbonproducedfromwastetyrespyrolysisforremovalof2chlorophenol
AT sheelavsukumaran evaluationoflowcostactivatedcarbonproducedfromwastetyrespyrolysisforremovalof2chlorophenol
AT nornasuhaabdullah evaluationoflowcostactivatedcarbonproducedfromwastetyrespyrolysisforremovalof2chlorophenol
AT haziraharazak evaluationoflowcostactivatedcarbonproducedfromwastetyrespyrolysisforremovalof2chlorophenol
AT nurulainirazali evaluationoflowcostactivatedcarbonproducedfromwastetyrespyrolysisforremovalof2chlorophenol