Methyl 2-(5-bromo-3-methylsulfinyl-1-benzofuran-2-yl)acetate
The title compound, C12H11BrO4S, was synthesized by the oxidation of methyl 2-(5-bromo-3-methylsulfanyl-1-benzofuran-2-yl)acetate with 3-chloroperoxybenzoic acid. The O atom and the methyl group of the methylsulfinyl substituent lie on opposite sides of the plane of the benzofuran ring system. The c...
| Main Authors: | , , , |
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| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2008-12-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536808037768 |
| _version_ | 1818083237824561152 |
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| author | Uk Lee Byeng Wha Son Pil Ja Seo Hong Dae Choi |
| author_facet | Uk Lee Byeng Wha Son Pil Ja Seo Hong Dae Choi |
| author_sort | Uk Lee |
| collection | DOAJ |
| description | The title compound, C12H11BrO4S, was synthesized by the oxidation of methyl 2-(5-bromo-3-methylsulfanyl-1-benzofuran-2-yl)acetate with 3-chloroperoxybenzoic acid. The O atom and the methyl group of the methylsulfinyl substituent lie on opposite sides of the plane of the benzofuran ring system. The crystal structure is stabilized by C—H...π interactions, involving a methyl H atom and the benzene ring of a neighbouring molecule, and by weak intermolecular C—H...O hydrogen bonds. |
| first_indexed | 2024-12-10T19:34:48Z |
| format | Article |
| id | doaj.art-0d6106a33b0947d0bc28f3085e110e45 |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-10T19:34:48Z |
| publishDate | 2008-12-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-0d6106a33b0947d0bc28f3085e110e452022-12-22T01:36:10ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682008-12-016412o2397o239710.1107/S1600536808037768Methyl 2-(5-bromo-3-methylsulfinyl-1-benzofuran-2-yl)acetateUk LeeByeng Wha SonPil Ja SeoHong Dae ChoiThe title compound, C12H11BrO4S, was synthesized by the oxidation of methyl 2-(5-bromo-3-methylsulfanyl-1-benzofuran-2-yl)acetate with 3-chloroperoxybenzoic acid. The O atom and the methyl group of the methylsulfinyl substituent lie on opposite sides of the plane of the benzofuran ring system. The crystal structure is stabilized by C—H...π interactions, involving a methyl H atom and the benzene ring of a neighbouring molecule, and by weak intermolecular C—H...O hydrogen bonds.http://scripts.iucr.org/cgi-bin/paper?S1600536808037768 |
| spellingShingle | Uk Lee Byeng Wha Son Pil Ja Seo Hong Dae Choi Methyl 2-(5-bromo-3-methylsulfinyl-1-benzofuran-2-yl)acetate Acta Crystallographica Section E |
| title | Methyl 2-(5-bromo-3-methylsulfinyl-1-benzofuran-2-yl)acetate |
| title_full | Methyl 2-(5-bromo-3-methylsulfinyl-1-benzofuran-2-yl)acetate |
| title_fullStr | Methyl 2-(5-bromo-3-methylsulfinyl-1-benzofuran-2-yl)acetate |
| title_full_unstemmed | Methyl 2-(5-bromo-3-methylsulfinyl-1-benzofuran-2-yl)acetate |
| title_short | Methyl 2-(5-bromo-3-methylsulfinyl-1-benzofuran-2-yl)acetate |
| title_sort | methyl 2 5 bromo 3 methylsulfinyl 1 benzofuran 2 yl acetate |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536808037768 |
| work_keys_str_mv | AT uklee methyl25bromo3methylsulfinyl1benzofuran2ylacetate AT byengwhason methyl25bromo3methylsulfinyl1benzofuran2ylacetate AT piljaseo methyl25bromo3methylsulfinyl1benzofuran2ylacetate AT hongdaechoi methyl25bromo3methylsulfinyl1benzofuran2ylacetate |