Engineering Spin States of Isolated Copper Species in a Metal–Organic Framework Improves Urea Electrosynthesis
Highlights The single-atom Cu species with S = 0 spin ground state in CuIII-HHTP have been fabricated. The CuIII-HHTP exhibits remarkable performance with a high urea yield of 7.780 mmol h−1 g−1 with the corresponding Faradaic efficiency of 23.09% at − 0.6 V (vs. RHE). Low spin state and empty ( $${...
| Main Authors: | , , , , , , |
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| Format: | Article |
| Language: | English |
| Published: |
SpringerOpen
2023-06-01
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| Series: | Nano-Micro Letters |
| Subjects: | |
| Online Access: | https://doi.org/10.1007/s40820-023-01127-0 |