catena-Poly[diethyl(2-hydroxyethyl)ammonium [[tetra-μ-acetato-κ8O:O′-dicuprate(II)(Cu—Cu)]-μ-acetato-κ2O:O′] dichloromethane solvate]
The title compound, {(C6H16NO)[Cu2(CH3COO)5]·CH2Cl2}n, consists of acetate-bridged Cu2(CH3COO)4 units that are connected via another acetate anion at each terminus to form infinite anionic [{Cu2(CH3COO)4}(CH3COO)]n chains along [100]. The connecting acetate is hydrogen bonded to the diethyl...
| Main Authors: | , , , , |
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| Format: | Article |
| Language: | English |
| Published: |
International Union of Crystallography
2009-02-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536808044048 |
| _version_ | 1818997426974883840 |
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| author | James Raftery Mohammad Afzaal Paul O'Brien Muhammad Mazhar Muhammad Shahid |
| author_facet | James Raftery Mohammad Afzaal Paul O'Brien Muhammad Mazhar Muhammad Shahid |
| author_sort | James Raftery |
| collection | DOAJ |
| description | The title compound, {(C6H16NO)[Cu2(CH3COO)5]·CH2Cl2}n, consists of acetate-bridged Cu2(CH3COO)4 units that are connected via another acetate anion at each terminus to form infinite anionic [{Cu2(CH3COO)4}(CH3COO)]n chains along [100]. The connecting acetate is hydrogen bonded to the diethyl(2-hydroxyethyl)ammonium cation, and the dichloromethane solvent molecule fills the remaining voids in the structure. The O—Cu—Cu angles along the polymeric chain are nearly linear [175.49 (5)°], but individual O—Cu—Cu—O units along the chain are bent and rotated against each other at the bridging acetate ion. Translation of each Cu2(CH3COO)4 unit along the chain, represented by the least-squares plane of the two copper ions along with four of the acetate O atoms, rotated these units by 35.16 (3)°. |
| first_indexed | 2024-12-20T21:45:27Z |
| format | Article |
| id | doaj.art-0d9855ce34c44f8782959dc4b4e471b7 |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-20T21:45:27Z |
| publishDate | 2009-02-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-0d9855ce34c44f8782959dc4b4e471b72022-12-21T19:25:41ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682009-02-01652m163m16410.1107/S1600536808044048catena-Poly[diethyl(2-hydroxyethyl)ammonium [[tetra-μ-acetato-κ8O:O′-dicuprate(II)(Cu—Cu)]-μ-acetato-κ2O:O′] dichloromethane solvate]James RafteryMohammad AfzaalPaul O'BrienMuhammad MazharMuhammad ShahidThe title compound, {(C6H16NO)[Cu2(CH3COO)5]·CH2Cl2}n, consists of acetate-bridged Cu2(CH3COO)4 units that are connected via another acetate anion at each terminus to form infinite anionic [{Cu2(CH3COO)4}(CH3COO)]n chains along [100]. The connecting acetate is hydrogen bonded to the diethyl(2-hydroxyethyl)ammonium cation, and the dichloromethane solvent molecule fills the remaining voids in the structure. The O—Cu—Cu angles along the polymeric chain are nearly linear [175.49 (5)°], but individual O—Cu—Cu—O units along the chain are bent and rotated against each other at the bridging acetate ion. Translation of each Cu2(CH3COO)4 unit along the chain, represented by the least-squares plane of the two copper ions along with four of the acetate O atoms, rotated these units by 35.16 (3)°.http://scripts.iucr.org/cgi-bin/paper?S1600536808044048 |
| spellingShingle | James Raftery Mohammad Afzaal Paul O'Brien Muhammad Mazhar Muhammad Shahid catena-Poly[diethyl(2-hydroxyethyl)ammonium [[tetra-μ-acetato-κ8O:O′-dicuprate(II)(Cu—Cu)]-μ-acetato-κ2O:O′] dichloromethane solvate] Acta Crystallographica Section E |
| title | catena-Poly[diethyl(2-hydroxyethyl)ammonium [[tetra-μ-acetato-κ8O:O′-dicuprate(II)(Cu—Cu)]-μ-acetato-κ2O:O′] dichloromethane solvate] |
| title_full | catena-Poly[diethyl(2-hydroxyethyl)ammonium [[tetra-μ-acetato-κ8O:O′-dicuprate(II)(Cu—Cu)]-μ-acetato-κ2O:O′] dichloromethane solvate] |
| title_fullStr | catena-Poly[diethyl(2-hydroxyethyl)ammonium [[tetra-μ-acetato-κ8O:O′-dicuprate(II)(Cu—Cu)]-μ-acetato-κ2O:O′] dichloromethane solvate] |
| title_full_unstemmed | catena-Poly[diethyl(2-hydroxyethyl)ammonium [[tetra-μ-acetato-κ8O:O′-dicuprate(II)(Cu—Cu)]-μ-acetato-κ2O:O′] dichloromethane solvate] |
| title_short | catena-Poly[diethyl(2-hydroxyethyl)ammonium [[tetra-μ-acetato-κ8O:O′-dicuprate(II)(Cu—Cu)]-μ-acetato-κ2O:O′] dichloromethane solvate] |
| title_sort | catena poly diethyl 2 hydroxyethyl ammonium tetra 956 acetato 954 8o o 8242 dicuprate ii cu 8212 cu 956 acetato 954 2o o 8242 dichloromethane solvate |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536808044048 |
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