Design, synthesis, structure, and gas (CO2, CH4, and H2) storage properties of porous imine-linkage organic compounds

The high quantity of carbon dioxide in the atmosphere, which has been steadily increasing year after year, has had a significant influence, particularly on the environment, resulting in climate change and global warming. As a result, numerous approaches, like the Schiff bases, have reported extensiv...

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Main Authors: Taiseer Saleh, Emad Yousif, Emaad Al‐Tikrity, Dina Ahmed, Muna Bufaroosha, Mohammed Al-Mashhadani, Anaheed Yaseen
Format: Article
Language:English
Published: KeAi Communications Co., Ltd. 2022-01-01
Series:Materials Science for Energy Technologies
Subjects:
Online Access:http://www.sciencedirect.com/science/article/pii/S2589299122000209
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author Taiseer Saleh
Emad Yousif
Emaad Al‐Tikrity
Dina Ahmed
Muna Bufaroosha
Mohammed Al-Mashhadani
Anaheed Yaseen
author_facet Taiseer Saleh
Emad Yousif
Emaad Al‐Tikrity
Dina Ahmed
Muna Bufaroosha
Mohammed Al-Mashhadani
Anaheed Yaseen
author_sort Taiseer Saleh
collection DOAJ
description The high quantity of carbon dioxide in the atmosphere, which has been steadily increasing year after year, has had a significant influence, particularly on the environment, resulting in climate change and global warming. As a result, numerous approaches, like the Schiff bases, have reported extensive investigation into storing this gas. We synthesized four new Schiff bases containing the amlodipine medication and tested them as CO2, CH4 and H2 storage. In boiling methanol as a solvent, amlodipine reacts with (p-Chlorobenzaldehyde, p-hydroxy benzaldehyde, vanillin, terphthaldehyde) to generate COFs. Scanning electron microscopy (SEM), and atomic force microscopy (AFM) were utilized to study the features of the surface for synthesized compounds. Schiff bases have surface areas, pore volumes cm3/g, and pore widths, according to the Brunauer-Emmett-Teller (BET) test. At temperature (313 K) and pressure (40 bars), the produced Schiff bases obtained reasonable CO2 (26.3 cm3/g) CH4 (30.1 cm3/g) and H2 (2.5 cm3/g) absorption values.
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spelling doaj.art-0dad98beadc8463fbe6e49beeaebda3c2023-01-26T04:47:19ZengKeAi Communications Co., Ltd.Materials Science for Energy Technologies2589-29912022-01-015344352Design, synthesis, structure, and gas (CO2, CH4, and H2) storage properties of porous imine-linkage organic compoundsTaiseer Saleh0Emad Yousif1Emaad Al‐Tikrity2Dina Ahmed3Muna Bufaroosha4Mohammed Al-Mashhadani5Anaheed Yaseen6Department of Chemistry, College of Science, Tikrit University, Tikrit 34001, IraqDepartment of Chemistry, College of Science, Al-Nahrain University, 64021 Baghdad, IraqDepartment of Chemistry, College of Science, Tikrit University, Tikrit 34001, IraqDepartment of Medical Instrumentation Engineering, Al-Mansour University College, Baghdad 64021, IraqDepartment of Chemistry, College of Science, UAE University, Al-Ain, United Arab Emirates; Corresponding author.Department of Chemistry, College of Science, Al-Nahrain University, 64021 Baghdad, IraqDepartment of Chemistry, College of Science, Tikrit University, Tikrit 34001, IraqThe high quantity of carbon dioxide in the atmosphere, which has been steadily increasing year after year, has had a significant influence, particularly on the environment, resulting in climate change and global warming. As a result, numerous approaches, like the Schiff bases, have reported extensive investigation into storing this gas. We synthesized four new Schiff bases containing the amlodipine medication and tested them as CO2, CH4 and H2 storage. In boiling methanol as a solvent, amlodipine reacts with (p-Chlorobenzaldehyde, p-hydroxy benzaldehyde, vanillin, terphthaldehyde) to generate COFs. Scanning electron microscopy (SEM), and atomic force microscopy (AFM) were utilized to study the features of the surface for synthesized compounds. Schiff bases have surface areas, pore volumes cm3/g, and pore widths, according to the Brunauer-Emmett-Teller (BET) test. At temperature (313 K) and pressure (40 bars), the produced Schiff bases obtained reasonable CO2 (26.3 cm3/g) CH4 (30.1 cm3/g) and H2 (2.5 cm3/g) absorption values.http://www.sciencedirect.com/science/article/pii/S2589299122000209Amlodipine, gas storageSchiff basesGlobal warmingCarbon dioxide uptake
spellingShingle Taiseer Saleh
Emad Yousif
Emaad Al‐Tikrity
Dina Ahmed
Muna Bufaroosha
Mohammed Al-Mashhadani
Anaheed Yaseen
Design, synthesis, structure, and gas (CO2, CH4, and H2) storage properties of porous imine-linkage organic compounds
Materials Science for Energy Technologies
Amlodipine, gas storage
Schiff bases
Global warming
Carbon dioxide uptake
title Design, synthesis, structure, and gas (CO2, CH4, and H2) storage properties of porous imine-linkage organic compounds
title_full Design, synthesis, structure, and gas (CO2, CH4, and H2) storage properties of porous imine-linkage organic compounds
title_fullStr Design, synthesis, structure, and gas (CO2, CH4, and H2) storage properties of porous imine-linkage organic compounds
title_full_unstemmed Design, synthesis, structure, and gas (CO2, CH4, and H2) storage properties of porous imine-linkage organic compounds
title_short Design, synthesis, structure, and gas (CO2, CH4, and H2) storage properties of porous imine-linkage organic compounds
title_sort design synthesis structure and gas co2 ch4 and h2 storage properties of porous imine linkage organic compounds
topic Amlodipine, gas storage
Schiff bases
Global warming
Carbon dioxide uptake
url http://www.sciencedirect.com/science/article/pii/S2589299122000209
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