Visible light induced alkene aminopyridylation using N-aminopyridinium salts as bifunctional reagents
A key difficulty to overcome in pyridinium salts functionalization is the regioselectivity at the two competing C2 and C4 sites. Here, the authors show bifunctional N-aminopyridinium salts reagents delivering both the aminyl radical and the pyridyl group to an olefin with C4-pyridyl regioselectivity...
Main Authors: | Yonghoon Moon, Bohyun Park, Inwon Kim, Gyumin Kang, Sanghoon Shin, Dahye Kang, Mu-Hyun Baik, Sungwoo Hong |
---|---|
Format: | Article |
Language: | English |
Published: |
Nature Portfolio
2019-09-01
|
Series: | Nature Communications |
Online Access: | https://doi.org/10.1038/s41467-019-12216-3 |
Similar Items
-
N-Aminopyridinium reagents as traceless activating groups in the synthesis of N-Aryl aziridines
by: Hao Tan, et al.
Published: (2022-06-01) -
New osmium-based reagent for the dihydroxylation of alkenes.
by: Donohoe, T, et al.
Published: (2006) -
3-Aminopyridinium picrate
by: Yan-jun Li
Published: (2010-10-01) -
2-Aminopyridinium trifluoroacetate
by: Hoong-Kun Fun, et al.
Published: (2010-03-01) -
Alkene synthesis using phosphonium ylides as umpolung reagents
by: Vu, Minh Duy, et al.
Published: (2020)