Di-μ-chromato-κ4O:O′-bis[bis(phenanthroline-κ2N,N′)cadmium(II)] dihydrate
In the title compound, [Cd2Cr2O8(C12H8N2)4]·2H2O, which was obtained by hydrothermal reaction of CdCO3 and phenanthroline with K2CrO4 at 393 K, two distorted Cd(N4O2) octahedra are linked through μ2-bridging chromate anions, forming a centrosymmetric tetranucl...
| Main Authors: | , , |
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2009-04-01
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| Series: | Acta Crystallographica Section E |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S160053680900823X |
| _version_ | 1818776228707958784 |
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| author | Hai-Xing Liu Fang-Fang Jian Jing Wang |
| author_facet | Hai-Xing Liu Fang-Fang Jian Jing Wang |
| author_sort | Hai-Xing Liu |
| collection | DOAJ |
| description | In the title compound, [Cd2Cr2O8(C12H8N2)4]·2H2O, which was obtained by hydrothermal reaction of CdCO3 and phenanthroline with K2CrO4 at 393 K, two distorted Cd(N4O2) octahedra are linked through μ2-bridging chromate anions, forming a centrosymmetric tetranuclear eight-membered ring complex. The water molecules link the chromate O atoms via intermolecular O—H...O hydrogen bonds. These aggregates pack to a three-dimensional network through weak intermolecular C—H...O and C—H...π hydrogen-bonding contacts. |
| first_indexed | 2024-12-18T11:09:36Z |
| format | Article |
| id | doaj.art-0dcfe21b4e65448380c2f095f9fed3cc |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-18T11:09:36Z |
| publishDate | 2009-04-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-0dcfe21b4e65448380c2f095f9fed3cc2022-12-21T21:10:01ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682009-04-01654m392m39310.1107/S160053680900823XDi-μ-chromato-κ4O:O′-bis[bis(phenanthroline-κ2N,N′)cadmium(II)] dihydrateHai-Xing LiuFang-Fang JianJing WangIn the title compound, [Cd2Cr2O8(C12H8N2)4]·2H2O, which was obtained by hydrothermal reaction of CdCO3 and phenanthroline with K2CrO4 at 393 K, two distorted Cd(N4O2) octahedra are linked through μ2-bridging chromate anions, forming a centrosymmetric tetranuclear eight-membered ring complex. The water molecules link the chromate O atoms via intermolecular O—H...O hydrogen bonds. These aggregates pack to a three-dimensional network through weak intermolecular C—H...O and C—H...π hydrogen-bonding contacts.http://scripts.iucr.org/cgi-bin/paper?S160053680900823X |
| spellingShingle | Hai-Xing Liu Fang-Fang Jian Jing Wang Di-μ-chromato-κ4O:O′-bis[bis(phenanthroline-κ2N,N′)cadmium(II)] dihydrate Acta Crystallographica Section E |
| title | Di-μ-chromato-κ4O:O′-bis[bis(phenanthroline-κ2N,N′)cadmium(II)] dihydrate |
| title_full | Di-μ-chromato-κ4O:O′-bis[bis(phenanthroline-κ2N,N′)cadmium(II)] dihydrate |
| title_fullStr | Di-μ-chromato-κ4O:O′-bis[bis(phenanthroline-κ2N,N′)cadmium(II)] dihydrate |
| title_full_unstemmed | Di-μ-chromato-κ4O:O′-bis[bis(phenanthroline-κ2N,N′)cadmium(II)] dihydrate |
| title_short | Di-μ-chromato-κ4O:O′-bis[bis(phenanthroline-κ2N,N′)cadmium(II)] dihydrate |
| title_sort | di amp 956 chromato amp 954 4o o amp 8242 bis bis phenanthroline amp 954 2n n amp 8242 cadmium ii dihydrate |
| url | http://scripts.iucr.org/cgi-bin/paper?S160053680900823X |
| work_keys_str_mv | AT haixingliu diamp956chromatoamp9544ooamp8242bisbisphenanthrolineamp9542nnamp8242cadmiumiidihydrate AT fangfangjian diamp956chromatoamp9544ooamp8242bisbisphenanthrolineamp9542nnamp8242cadmiumiidihydrate AT jingwang diamp956chromatoamp9544ooamp8242bisbisphenanthrolineamp9542nnamp8242cadmiumiidihydrate |