Transforming from paramagnetism to room temperature ferromagnetism in CuO by ball milling

In this work, we experimentally demonstrate that it is possible to induce ferromagnetism in CuO by ball milling without any ferromagnetic dopant. The magnetic measurements indicate that paramagnetic CuO is driven to the ferromagnetic state at room temperature by ball milling gradually. The saturatio...

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Main Authors: Daqiang Gao, Zhaolong Yang, Jing Zhang, Guijin Yang, Zhonghua Zhu, Jing Qi, Mingsu Si, Desheng Xue
Format: Article
Language:English
Published: AIP Publishing LLC 2011-12-01
Series:AIP Advances
Online Access:http://dx.doi.org/10.1063/1.3670360
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author Daqiang Gao
Zhaolong Yang
Jing Zhang
Guijin Yang
Zhonghua Zhu
Jing Qi
Mingsu Si
Desheng Xue
author_facet Daqiang Gao
Zhaolong Yang
Jing Zhang
Guijin Yang
Zhonghua Zhu
Jing Qi
Mingsu Si
Desheng Xue
author_sort Daqiang Gao
collection DOAJ
description In this work, we experimentally demonstrate that it is possible to induce ferromagnetism in CuO by ball milling without any ferromagnetic dopant. The magnetic measurements indicate that paramagnetic CuO is driven to the ferromagnetic state at room temperature by ball milling gradually. The saturation magnetization of the milled powders is found to increase with expanding the milling time and then decrease by annealing under atmosphere. The fitted X-ray photoelectron spectroscopy results indicate that the observed induction and weaken of the ferromagnetism shows close relationship with the valence charged oxygen vacancies (Cu1+-VO) in CuO.
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spelling doaj.art-0ddf56c32b9e40329a4216e8cd459ab72022-12-22T00:53:56ZengAIP Publishing LLCAIP Advances2158-32262011-12-0114042168042168-610.1063/1.3670360074104ADVTransforming from paramagnetism to room temperature ferromagnetism in CuO by ball millingDaqiang Gao0Zhaolong Yang1Jing Zhang2Guijin Yang3Zhonghua Zhu4Jing Qi5Mingsu Si6Desheng Xue7Key Laboratory for Magnetism and Magnetic Materials of MOE, Lanzhou University, Lanzhou 730000, P. R. ChinaKey Laboratory for Magnetism and Magnetic Materials of MOE, Lanzhou University, Lanzhou 730000, P. R. ChinaKey Laboratory for Magnetism and Magnetic Materials of MOE, Lanzhou University, Lanzhou 730000, P. R. ChinaKey Laboratory for Magnetism and Magnetic Materials of MOE, Lanzhou University, Lanzhou 730000, P. R. ChinaKey Laboratory for Magnetism and Magnetic Materials of MOE, Lanzhou University, Lanzhou 730000, P. R. ChinaKey Laboratory for Magnetism and Magnetic Materials of MOE, Lanzhou University, Lanzhou 730000, P. R. ChinaKey Laboratory for Magnetism and Magnetic Materials of MOE, Lanzhou University, Lanzhou 730000, P. R. ChinaKey Laboratory for Magnetism and Magnetic Materials of MOE, Lanzhou University, Lanzhou 730000, P. R. ChinaIn this work, we experimentally demonstrate that it is possible to induce ferromagnetism in CuO by ball milling without any ferromagnetic dopant. The magnetic measurements indicate that paramagnetic CuO is driven to the ferromagnetic state at room temperature by ball milling gradually. The saturation magnetization of the milled powders is found to increase with expanding the milling time and then decrease by annealing under atmosphere. The fitted X-ray photoelectron spectroscopy results indicate that the observed induction and weaken of the ferromagnetism shows close relationship with the valence charged oxygen vacancies (Cu1+-VO) in CuO.http://dx.doi.org/10.1063/1.3670360
spellingShingle Daqiang Gao
Zhaolong Yang
Jing Zhang
Guijin Yang
Zhonghua Zhu
Jing Qi
Mingsu Si
Desheng Xue
Transforming from paramagnetism to room temperature ferromagnetism in CuO by ball milling
AIP Advances
title Transforming from paramagnetism to room temperature ferromagnetism in CuO by ball milling
title_full Transforming from paramagnetism to room temperature ferromagnetism in CuO by ball milling
title_fullStr Transforming from paramagnetism to room temperature ferromagnetism in CuO by ball milling
title_full_unstemmed Transforming from paramagnetism to room temperature ferromagnetism in CuO by ball milling
title_short Transforming from paramagnetism to room temperature ferromagnetism in CuO by ball milling
title_sort transforming from paramagnetism to room temperature ferromagnetism in cuo by ball milling
url http://dx.doi.org/10.1063/1.3670360
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