Evolution Analysis of Free Fatty Acids and Aroma-Active Compounds during Tallow Oxidation

To explore the role of fatty acids as flavor precursors in the flavor of oxidized tallow, the volatile flavor compounds and free fatty acid (FFAs) in the four oxidization stages of tallow were analyzed via gas chromatography (GC)–mass spectrometry (MS), the aroma characteristics of them were analyze...

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Main Authors: Shiqing Song, Feiting Zheng, Xiaoyan Tian, Tao Feng, Lingyun Yao, Min Sun, Lei Shi
Format: Article
Language:English
Published: MDPI AG 2022-01-01
Series:Molecules
Subjects:
Online Access:https://www.mdpi.com/1420-3049/27/2/352
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author Shiqing Song
Feiting Zheng
Xiaoyan Tian
Tao Feng
Lingyun Yao
Min Sun
Lei Shi
author_facet Shiqing Song
Feiting Zheng
Xiaoyan Tian
Tao Feng
Lingyun Yao
Min Sun
Lei Shi
author_sort Shiqing Song
collection DOAJ
description To explore the role of fatty acids as flavor precursors in the flavor of oxidized tallow, the volatile flavor compounds and free fatty acid (FFAs) in the four oxidization stages of tallow were analyzed via gas chromatography (GC)–mass spectrometry (MS), the aroma characteristics of them were analyzed by GC–olfactory (GC-O) method combined with sensory analysis and partial least-squares regression (PLSR) analysis. 12 common FFAs and 35 key aroma-active compounds were obtained. Combined with the results of odor activity value (OAV) and FD factor, benzaldehyde was found to be an important component in unoxidized tallow. (<i>E</i>,<i>E</i>)-2,4-Heptadienal, (<i>E</i>,<i>E</i>)-2,4-decadienal, (<i>E</i>)-2-nonenal, octanal, hexanoic acid, hexanal and (<i>E</i>)-2-heptenal were the key compounds involved in the tallow flavor oxidation. The changes in FFAs and volatile flavor compounds during oxidation and the metabolic evolution of key aroma-active compounds are systematically summarized in this study. The paper also provides considerable guidance in oxidation control and meat flavor product development.
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spelling doaj.art-0de0abcc6b384be2931ceb1d9025eb2c2023-11-23T14:50:40ZengMDPI AGMolecules1420-30492022-01-0127235210.3390/molecules27020352Evolution Analysis of Free Fatty Acids and Aroma-Active Compounds during Tallow OxidationShiqing Song0Feiting Zheng1Xiaoyan Tian2Tao Feng3Lingyun Yao4Min Sun5Lei Shi6School of Perfume and Aroma Technology, Shanghai Institute of Technology, Shanghai 201418, ChinaSchool of Perfume and Aroma Technology, Shanghai Institute of Technology, Shanghai 201418, ChinaSchool of Perfume and Aroma Technology, Shanghai Institute of Technology, Shanghai 201418, ChinaSchool of Perfume and Aroma Technology, Shanghai Institute of Technology, Shanghai 201418, ChinaSchool of Perfume and Aroma Technology, Shanghai Institute of Technology, Shanghai 201418, ChinaSchool of Perfume and Aroma Technology, Shanghai Institute of Technology, Shanghai 201418, ChinaPudong New Area Agro-Technology Extension Center, Shanghai 201201, ChinaTo explore the role of fatty acids as flavor precursors in the flavor of oxidized tallow, the volatile flavor compounds and free fatty acid (FFAs) in the four oxidization stages of tallow were analyzed via gas chromatography (GC)–mass spectrometry (MS), the aroma characteristics of them were analyzed by GC–olfactory (GC-O) method combined with sensory analysis and partial least-squares regression (PLSR) analysis. 12 common FFAs and 35 key aroma-active compounds were obtained. Combined with the results of odor activity value (OAV) and FD factor, benzaldehyde was found to be an important component in unoxidized tallow. (<i>E</i>,<i>E</i>)-2,4-Heptadienal, (<i>E</i>,<i>E</i>)-2,4-decadienal, (<i>E</i>)-2-nonenal, octanal, hexanoic acid, hexanal and (<i>E</i>)-2-heptenal were the key compounds involved in the tallow flavor oxidation. The changes in FFAs and volatile flavor compounds during oxidation and the metabolic evolution of key aroma-active compounds are systematically summarized in this study. The paper also provides considerable guidance in oxidation control and meat flavor product development.https://www.mdpi.com/1420-3049/27/2/352oxidized tallowaroma-active compoundssolvent-assisted flavor evaporationgas chromatography-olfactometrypartial least-squares regression
spellingShingle Shiqing Song
Feiting Zheng
Xiaoyan Tian
Tao Feng
Lingyun Yao
Min Sun
Lei Shi
Evolution Analysis of Free Fatty Acids and Aroma-Active Compounds during Tallow Oxidation
Molecules
oxidized tallow
aroma-active compounds
solvent-assisted flavor evaporation
gas chromatography-olfactometry
partial least-squares regression
title Evolution Analysis of Free Fatty Acids and Aroma-Active Compounds during Tallow Oxidation
title_full Evolution Analysis of Free Fatty Acids and Aroma-Active Compounds during Tallow Oxidation
title_fullStr Evolution Analysis of Free Fatty Acids and Aroma-Active Compounds during Tallow Oxidation
title_full_unstemmed Evolution Analysis of Free Fatty Acids and Aroma-Active Compounds during Tallow Oxidation
title_short Evolution Analysis of Free Fatty Acids and Aroma-Active Compounds during Tallow Oxidation
title_sort evolution analysis of free fatty acids and aroma active compounds during tallow oxidation
topic oxidized tallow
aroma-active compounds
solvent-assisted flavor evaporation
gas chromatography-olfactometry
partial least-squares regression
url https://www.mdpi.com/1420-3049/27/2/352
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