(Z)-2-(4-{[(E)-2-Hydroxybenzylidene]amino}phenyl)-3-[4-(1,4,7,10-tetraoxa-13-azacyclopentadecan-13-yl)phenyl]acrylonitrile
The title compound, C32H35N3O5, is an important fluorescence probe. It is composed of a 1,4,7,10-tetraoxa-13λ2-azacyclopentadecane unit linked to a twisted (Z)-2-(4-{[(E)-2-hydroxybenzylidene]amino}phenyl)-3-phenylacrylonitrile chain. In the molecule, an O—H...N hydrogen bond forms an S(6) ring moti...
| Main Authors: | , |
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2016-10-01
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| Series: | IUCrData |
| Subjects: | |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S2414314616015984 |
| _version_ | 1818142145842774016 |
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| author | Xin Zhang Zhi-Chao Wu |
| author_facet | Xin Zhang Zhi-Chao Wu |
| author_sort | Xin Zhang |
| collection | DOAJ |
| description | The title compound, C32H35N3O5, is an important fluorescence probe. It is composed of a 1,4,7,10-tetraoxa-13λ2-azacyclopentadecane unit linked to a twisted (Z)-2-(4-{[(E)-2-hydroxybenzylidene]amino}phenyl)-3-phenylacrylonitrile chain. In the molecule, an O—H...N hydrogen bond forms an S(6) ring motif. There is also in intramolecular C—H...N hydrogen bond in the azacrown ether moiety, which also forms an S(6) ring motif. In the crystal, molecules are linked via pairs of C—H...O hydrogen bonds, forming inversion dimers. |
| first_indexed | 2024-12-11T11:11:08Z |
| format | Article |
| id | doaj.art-0deaa364bc5648bd846fc9dbe1fb2fb5 |
| institution | Directory Open Access Journal |
| issn | 2414-3146 |
| language | English |
| last_indexed | 2024-12-11T11:11:08Z |
| publishDate | 2016-10-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | IUCrData |
| spelling | doaj.art-0deaa364bc5648bd846fc9dbe1fb2fb52022-12-22T01:09:32ZengInternational Union of CrystallographyIUCrData2414-31462016-10-01110x16159810.1107/S2414314616015984su4074(Z)-2-(4-{[(E)-2-Hydroxybenzylidene]amino}phenyl)-3-[4-(1,4,7,10-tetraoxa-13-azacyclopentadecan-13-yl)phenyl]acrylonitrileXin Zhang0Zhi-Chao Wu1Department of Chemistry, Anhui University, Hefei 230601, People's Republic of ChinaDepartment of Chemistry, Anhui University, Hefei 230601, People's Republic of ChinaThe title compound, C32H35N3O5, is an important fluorescence probe. It is composed of a 1,4,7,10-tetraoxa-13λ2-azacyclopentadecane unit linked to a twisted (Z)-2-(4-{[(E)-2-hydroxybenzylidene]amino}phenyl)-3-phenylacrylonitrile chain. In the molecule, an O—H...N hydrogen bond forms an S(6) ring motif. There is also in intramolecular C—H...N hydrogen bond in the azacrown ether moiety, which also forms an S(6) ring motif. In the crystal, molecules are linked via pairs of C—H...O hydrogen bonds, forming inversion dimers.http://scripts.iucr.org/cgi-bin/paper?S2414314616015984crystal structureazacrown etheracrylonitrilefluorescence probehydrogen bonding |
| spellingShingle | Xin Zhang Zhi-Chao Wu (Z)-2-(4-{[(E)-2-Hydroxybenzylidene]amino}phenyl)-3-[4-(1,4,7,10-tetraoxa-13-azacyclopentadecan-13-yl)phenyl]acrylonitrile IUCrData crystal structure azacrown ether acrylonitrile fluorescence probe hydrogen bonding |
| title | (Z)-2-(4-{[(E)-2-Hydroxybenzylidene]amino}phenyl)-3-[4-(1,4,7,10-tetraoxa-13-azacyclopentadecan-13-yl)phenyl]acrylonitrile |
| title_full | (Z)-2-(4-{[(E)-2-Hydroxybenzylidene]amino}phenyl)-3-[4-(1,4,7,10-tetraoxa-13-azacyclopentadecan-13-yl)phenyl]acrylonitrile |
| title_fullStr | (Z)-2-(4-{[(E)-2-Hydroxybenzylidene]amino}phenyl)-3-[4-(1,4,7,10-tetraoxa-13-azacyclopentadecan-13-yl)phenyl]acrylonitrile |
| title_full_unstemmed | (Z)-2-(4-{[(E)-2-Hydroxybenzylidene]amino}phenyl)-3-[4-(1,4,7,10-tetraoxa-13-azacyclopentadecan-13-yl)phenyl]acrylonitrile |
| title_short | (Z)-2-(4-{[(E)-2-Hydroxybenzylidene]amino}phenyl)-3-[4-(1,4,7,10-tetraoxa-13-azacyclopentadecan-13-yl)phenyl]acrylonitrile |
| title_sort | z 2 4 e 2 hydroxybenzylidene amino phenyl 3 4 1 4 7 10 tetraoxa 13 azacyclopentadecan 13 yl phenyl acrylonitrile |
| topic | crystal structure azacrown ether acrylonitrile fluorescence probe hydrogen bonding |
| url | http://scripts.iucr.org/cgi-bin/paper?S2414314616015984 |
| work_keys_str_mv | AT xinzhang z24e2hydroxybenzylideneaminophenyl3414710tetraoxa13azacyclopentadecan13ylphenylacrylonitrile AT zhichaowu z24e2hydroxybenzylideneaminophenyl3414710tetraoxa13azacyclopentadecan13ylphenylacrylonitrile |