Crystal structure of S,N-dibenzyl-d-penicillamine monohydrate
In the asymmetric unit of the title compound, C19H23NO2S·H2O, there are two independent organic molecules and two water molecules. Both organic molecules exist as the zwitterionic form. The dihedral angles between the planes of the rings in the organic molecules are 86.84 (10) and 88.77 (11)°. An in...
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2014-11-01
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| Series: | Acta Crystallographica Section E |
| Subjects: | |
| Online Access: | http://scripts.iucr.org/cgi-bin/paper?S1600536814023459 |
| _version_ | 1831691275345068032 |
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| author | Nobuto Yoshinari Takumi Konno |
| author_facet | Nobuto Yoshinari Takumi Konno |
| author_sort | Nobuto Yoshinari |
| collection | DOAJ |
| description | In the asymmetric unit of the title compound, C19H23NO2S·H2O, there are two independent organic molecules and two water molecules. Both organic molecules exist as the zwitterionic form. The dihedral angles between the planes of the rings in the organic molecules are 86.84 (10) and 88.77 (11)°. An intramolecular N—H...S hydrogen bond occurs. In the crystal, organic and water molecules are linked by N—H...O and O—H...O hydrogen bonds, generating a tape structure running along the b-axis direction. |
| first_indexed | 2024-12-20T11:26:13Z |
| format | Article |
| id | doaj.art-0e010786b38d42a684d02f0995778308 |
| institution | Directory Open Access Journal |
| issn | 1600-5368 |
| language | English |
| last_indexed | 2024-12-20T11:26:13Z |
| publishDate | 2014-11-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E |
| spelling | doaj.art-0e010786b38d42a684d02f09957783082022-12-21T19:42:21ZengInternational Union of CrystallographyActa Crystallographica Section E1600-53682014-11-017011o1209o120910.1107/S1600536814023459is5378Crystal structure of S,N-dibenzyl-d-penicillamine monohydrateNobuto Yoshinari0Takumi Konno1Department of Chemistry, Graduate School of Science, Osaka University, Toyonaka, Osaka 560-0043, JapanDepartment of Chemistry, Graduate School of Science, Osaka University, Toyonaka, Osaka 560-0043, JapanIn the asymmetric unit of the title compound, C19H23NO2S·H2O, there are two independent organic molecules and two water molecules. Both organic molecules exist as the zwitterionic form. The dihedral angles between the planes of the rings in the organic molecules are 86.84 (10) and 88.77 (11)°. An intramolecular N—H...S hydrogen bond occurs. In the crystal, organic and water molecules are linked by N—H...O and O—H...O hydrogen bonds, generating a tape structure running along the b-axis direction.http://scripts.iucr.org/cgi-bin/paper?S1600536814023459crystal structurehydrogen bondspenicillamine |
| spellingShingle | Nobuto Yoshinari Takumi Konno Crystal structure of S,N-dibenzyl-d-penicillamine monohydrate Acta Crystallographica Section E crystal structure hydrogen bonds penicillamine |
| title | Crystal structure of S,N-dibenzyl-d-penicillamine monohydrate |
| title_full | Crystal structure of S,N-dibenzyl-d-penicillamine monohydrate |
| title_fullStr | Crystal structure of S,N-dibenzyl-d-penicillamine monohydrate |
| title_full_unstemmed | Crystal structure of S,N-dibenzyl-d-penicillamine monohydrate |
| title_short | Crystal structure of S,N-dibenzyl-d-penicillamine monohydrate |
| title_sort | crystal structure of s n dibenzyl d penicillamine monohydrate |
| topic | crystal structure hydrogen bonds penicillamine |
| url | http://scripts.iucr.org/cgi-bin/paper?S1600536814023459 |
| work_keys_str_mv | AT nobutoyoshinari crystalstructureofsndibenzyldpenicillaminemonohydrate AT takumikonno crystalstructureofsndibenzyldpenicillaminemonohydrate |